Abstract
Since zeolites were first successfully crystallized in the laboratory over 30 years ago, researchers have been trying to understand how these micropor-ous materials form from complex mixtures. Based on (1) the large number of variables that affect the crystallization process, (2) the complex chemistry of basic solutions of the amphoteric oxides of silicon and aluminum, and (3) the inhomogeneity of the crystallizing system, identification of the precursors formed on a “molecular” level—from the time of mixing of all the components until the point at which rapid crystallization (characteristic of these systems) is observable on a macroscopic scale—becomes a horrendous task. The ultimate goal is the same on both the macroscopic scale (as discussed in the previous chapter) and the microscopic scale (which will be presented here): to be able to custom-synthesize catalysts and adsorbents with structural features desirable for a given process. In considering the mechanism(s) of zeolite formation, it is essential to understand that the synthesis of zeolites is a crystallization process governed by a set of rules that differ from those applied to chemical reactions.
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Szostak, R. (1989). Process of Zeolite Formation on a Molecular Level. In: Molecular Sieves. Van Nostrand Reinhold Catalysis Series. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-9529-7_3
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