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Dimerization of Acrylic Compounds

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Aspects of Homogeneous Catalysis

Part of the book series: Aspects of Homogeneous Catalysis ((AHCA,volume 2))

Abstract

The chemistry of oligomerization reactions is currently receiving considerable attention from the industrial point of view. Dimerization and co-dimerization of olefins, dienes, alkynes, and acrylic monomers which can be produced in large quantities and at low cost by the petrochemical industry afford valuable intermediates. In particular the dimerization of acrylic compounds opens a new field for the synthesis of bifunctional materials. There is, for example, the reductive dimerization of acrylonitrile to adiponitrile which is an important process since the latter compound is a raw material for 6,6-nylon. Several methods for the dimerization reaction have been discovered, but the dimerization catalyzed by transition metal complexes has attracted much interest since the reaction proceeds rather selectively under mild conditions.

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  1. Department of Industrial Chemistry, The University of Tokyo, Hongo, Tokyo, Japan

    Masanobu Hidai & Akira Misono

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  1. Masanobu Hidai
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  1. Istituto Di Chimica Generale Ed Inorganica, Milan University, Italy

    Renato Ugo

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© 1974 D. Reidel Publishing Company, Dordrecht, Holland

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Hidai, M., Misono, A. (1974). Dimerization of Acrylic Compounds. In: Ugo, R. (eds) Aspects of Homogeneous Catalysis. Aspects of Homogeneous Catalysis, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-2285-9_4

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  • DOI: https://doi.org/10.1007/978-94-010-2285-9_4

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