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A Comparison of Proton Transfer Rates in Aqueous and Non-Aqueous Solutions

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Book cover Chemical and Biological Applications of Relaxation Spectrometry

Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 18))

Abstract

Proton transfer mechanisms are described in either water or anhydrous dimethylsulphoxide as solvents, using the same acidic substrates in each case: ammonium salts, acetylenic compounds, thiols or alcohols. Rate measurements were performed as a function of the pH by means of dynamic NMR of proton or carbon -13 nuclei at 25°C. From these experiments, it seems that the presence of water is not necessary to obtain fast proton transfers.

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Author information

Authors and Affiliations

  1. Equipe de Recherche Associée au C.N.R.S., Laboratoire de Chimie Physique Organique, Université de Nancy I, base officielle no 140, 54037, Nancy Cedex, France

    B. Bianchin, J. Chrisment, J. J. Delpuech, M. N. Deschamps, D. Nicole & G. Serratrice

Authors
  1. B. Bianchin
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  2. J. Chrisment
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  3. J. J. Delpuech
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  4. M. N. Deschamps
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  5. D. Nicole
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  6. G. Serratrice
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Editor information

Editors and Affiliations

  1. Department of Chemistry and Applied Chemistry, University of Salford, Salford, England

    E. Wyn-Jones

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© 1975 D. Reidel Publishing Company, Dordrecht-Holland

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Bianchin, B., Chrisment, J., Delpuech, J.J., Deschamps, M.N., Nicole, D., Serratrice, G. (1975). A Comparison of Proton Transfer Rates in Aqueous and Non-Aqueous Solutions. In: Wyn-Jones, E. (eds) Chemical and Biological Applications of Relaxation Spectrometry. NATO Advanced Study Institutes Series, vol 18. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1855-5_40

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  • DOI: https://doi.org/10.1007/978-94-010-1855-5_40

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-1857-9

  • Online ISBN: 978-94-010-1855-5

  • eBook Packages: Springer Book Archive

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