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Kinetic Studies of the Rapid Reactions in n-Alkyl Sulfate Solution

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Chemical and Biological Applications of Relaxation Spectrometry

Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 18))

Abstract

The kinetics of micellization have been studied using the various relaxation techniques on several detergent micelles1–16. Synthetically speaking, the relaxation times obtained by means of the ultrasonic absorption techniques1–7 are above two order of magnitude faster than those by means of the temperature-jump or the pressure-jump techniques8–15. In the latter case, all of the published papers containing ours12,13 have reported that the reciprocal relaxation times increase with the total detergent concentration in the concentration range larger than the critical micellar concentration (c.m.c.) except two papers14,15 which also indicate the apparent concentration dependences of the relaxation times in the lower concentration range. More recently, however, we have obtained the relaxation times independent of the total detergent concentration on sodium dodecyl sulfate (SDS) by means of the pressure-jump technique.

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References

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Hiroshima, Japan

    Tatsuya Yasunaga, Kunio Takeda, Nobuhide Tatsumoto & Hiromoto Uehara

Authors
  1. Tatsuya Yasunaga
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  2. Kunio Takeda
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  3. Nobuhide Tatsumoto
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  4. Hiromoto Uehara
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Editor information

Editors and Affiliations

  1. Department of Chemistry and Applied Chemistry, University of Salford, Salford, England

    E. Wyn-Jones

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© 1975 D. Reidel Publishing Company, Dordrecht-Holland

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Yasunaga, T., Takeda, K., Tatsumoto, N., Uehara, H. (1975). Kinetic Studies of the Rapid Reactions in n-Alkyl Sulfate Solution. In: Wyn-Jones, E. (eds) Chemical and Biological Applications of Relaxation Spectrometry. NATO Advanced Study Institutes Series, vol 18. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1855-5_16

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  • DOI: https://doi.org/10.1007/978-94-010-1855-5_16

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-1857-9

  • Online ISBN: 978-94-010-1855-5

  • eBook Packages: Springer Book Archive

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