Measurement of Circular Dichroism in the Vacuum Ultraviolet. A New Challenge for Theoreticians

Pysh, E. S.

doi:10.1007/978-94-010-1273-7_36

Measurement of Circular Dichroism in the Vacuum Ultraviolet. A New Challenge for Theoreticians

E. S. Pysh³

Conference paper

23 Accesses
4 Citations

Part of the book series: The Jerusalem Symposia on Quantum Chemistry and Biochemistry ((JSQC,volume 10))

Abstract

Measurements of vacuum ultraviolet circular dichroism (VUCD) ¹have been made only in recent years. Several prototype instruments have been described^2–20 and reviews have begun to appear in the literature. ^20–22 The new results reported here are described from the point of view of illustrating how these and similar data may influence the development of the theories of optical activity and conformational analysis.

This is a preview of subscription content, log in via an institution.

Chapter: USD 29.95; Price excludes VAT (USA)

eBook: USD 169.00; Price excludes VAT (USA)

Softcover Book: USD 219.99; Price excludes VAT (USA)

Hardcover Book: USD 219.99; Price excludes VAT (USA)

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

References

The following abbreviations are used: CD(circular dichroism), VUCD (vacuum ultraviolet circular dichroism), HFIP (hexafluoroisopropanol), TFE (trifluoroethanol), BOC (tert-butyloxycarbonyl), OMe (methoxy), Ala (alanine), Cha (cyclohexylalanine), Leu (leucine), Nva (norvaline), Val (valine).
Google Scholar
O. Schnepp, E. F. Pearson, and E. Sharman, J. Chem. Phys., 52, 6424 (1970); Chem. Commun., 1970, 45 (1970).
Article CAS Google Scholar
O. Schnepp, S. Allen, and E. F. Pearson, Rev. Sci. Instrum., 41, 1136 (1970).
Article CAS Google Scholar
O. Schnepp, in Chemical Spectroscopy and Photochemistry in the Vacuum Ultraviolet, Eds. C. Sandorfy, P. J. Ausloos, and M. B. Robin, Reidel Publ. Co. ( NATO ASI Series ), 1974, p. 211.
Chapter Google Scholar
W. C. Johnson, Jr., Rev. Sci. Instrum., 42, 1283 (1971).
Article CAS Google Scholar
H. J. Li, I. Isenberg, and W. C. Johnson, Jr., Biochemistry, 10, 2587 (1971).
Google Scholar
R. G. Nelson and W. C. Johnson, Jr., J. Am. Chem. Soc., 94, 3343 (1972)
Article CAS Google Scholar
W. C. Johnson, Jr. and I. Tinoco, Jr., J. Am. Chem. Soc., 94, 4389 (1972).
Article CAS Google Scholar
P. A. Snyder, P. M. Vipond, and W. C. Johnson, Jr., Biopolymers, 12, 975 (1973).
Google Scholar
W. C. Johnson, Jr., J. Chem. Phys., 59, 2618 (1973).
Article Google Scholar
D. G. Lewis and W. C. Johnson, Jr., J. Mol. Biol. 86, 91 (1974).
Article CAS Google Scholar
R. G. Nelson and W. C. Johnson, Jr., J. Am. Chem. Soc., 98, 4290 (1976).
Article CAS Google Scholar
R. G. Nelson and W. C. Johnson, Jr., J. Am. Chem. Soc., 98, 4296 (1976).
Article CAS Google Scholar
M. A. Young and E. S. Pysh, Macromolecules, 6, 790 (1973).
Article CAS Google Scholar
M. A. Young and E. S. Pysh, J. Am. Chem. Soc., 97, 5100 (1975).
Article CAS Google Scholar
J. S. Balcerski, E. S. Pysh, G. C. Chen, and J. T. Yang, J. Am. Chem. Soc., 97, 6274 (1975).
Article CAS Google Scholar
J. S. Balcerski, E. S. Pysh, G. M. Bonora, and C. Toniolo, J. Am. Chem. Soc., 98, 3470 (1976).
Article Google Scholar
M. M. Kelly, E. S. Pysh, G. M. Bonora, and C. Toniolo, J. Am. Chem. Soc., 99, xxxx (1977).
Google Scholar
L. A. Buffington, E. S. Pysh, B. Chakrabarti, and E. A. Balazs, J. Am. Chem. Soc., 99, xxxx (1977).
Article Google Scholar
E. S. Pysh, Ann. Rev. Biophys. Bioeng., 5, 63 (1976).
Article CAS Google Scholar
E. S. Pysh, Adv. Enzymology, in press.
Google Scholar
W. C. Johnson, Jr., Adv. Phys. Chem., in preparation.
Google Scholar
J. C. Kemp, J. Opt. Soc., Am., 59, 950 (1969).
Google Scholar
T. H. Morton, L. A. Buffington, and E. S. Pysh, in preparation.
Google Scholar
J. C. Craig and W. E. Pereira, Tetrahedron Lett., 18, 1563 (1970); Tetrahedron, 26, 3457 (1970).
Article Google Scholar
E. R. Morris, D. A. Rees, G. R. Sanderson, and D. Thorn, J. Chem. Soc., Perkin Trans., 2, 1418 (1975).
Article Google Scholar
I. Listowsky, G. Avigad, and S. Englard, J. Org. Chem., 35, 1080 (1970); Trans. N. Y. Acad. Sci., 34, 218 (1972).
Google Scholar
E. Peggion, M. Palumbo, G. M. Bonora, C. Toniolo, and E. S. Pysh, Proc. Fifth Amer. Peptide Symposium, San Diego, 1977.
Google Scholar
S. Kubota and G. D. Fasman, Biopolymers, 14, 605 (1975).
Article Google Scholar
J. Liang, E. R. Morris, and E. S. Pysh, in preparation.
Google Scholar
L. A. Buffington, E. R. Morris, and E. S. Pysh, in preparation.
Google Scholar

Download references

Author information

Authors and Affiliations

Department of Chemistry, Brown University, Providence, R. I., 02912, USA
E. S. Pysh

Authors

E. S. Pysh
View author publications
You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

Institut de Biologie Physico-Chimique (Fondation Edmond de Rothschild), Université Pierre et Marie Curie (Paris VI), 13 rue P. et M. Curie, Paris 5e, France
Bernard Pullman
Hadassah Medical School, The Hebrew University, Jerusalem, Israel
Natan Goldblum

Rights and permissions

Reprints and permissions

Copyright information

About this paper

Cite this paper

Pysh, E.S. (1977). Measurement of Circular Dichroism in the Vacuum Ultraviolet. A New Challenge for Theoreticians. In: Pullman, B., Goldblum, N. (eds) Excited States in Organic Chemistry and Biochemistry. The Jerusalem Symposia on Quantum Chemistry and Biochemistry, vol 10. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1273-7_36

Download citation

DOI: https://doi.org/10.1007/978-94-010-1273-7_36
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-1275-1
Online ISBN: 978-94-010-1273-7
eBook Packages: Springer Book Archive

Publish with us

Policies and ethics