Abstract
Depending on their structural dimensionality, bismuth-based oxide ion conductors can be classified in three groups : Bi2O3 itself is the prototype of the three- dimensional oxide ion conductors ; the BIMEVOX family, which particularly generated an increasing interest during the last ten years, belongs to the two-dimensional oxide ion conductors while Bi26Mo10O69 and its related phases, with a structure based on [Bi12O14]∞ columns, can be considered as the first example of mono-dimensional bismuth-based oxide ion conductors. The common feature between these three classes of materials is that oxygen diffusion takes place in a very disordered network, exhibiting a liquid-like structure. The mono and two-dimensional oxide ion conductors have a larger stability range in temperature, since their structure is reinforced by a covalent skeleton. The main feature of the different structural characteristics of these groups of materials are presented and discussed.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
Abraham, F., Boivin, J.C., Mairesse, G. and Nowogrocki, G. (1990) The BIMEVOX series: a new family of high performances oxide ion conductors, Solid State Ionics 40/41, 934–937
Boivin, J.C., Pirovano, C., Nowogrocki, G., Mairesse, G., Labrune, P., Lagrange, G. (1998) Electrode-electrolyte BIMEVOX system for moderate temperature oxygen separation, Solid State Ionics 113-115, 639–651
Vannier, R.N., Mairesse, G., Abraham, F. and Nowogrocki, G. (1996) Bi26Mo10Od solid solution type in the Bi2O3-MoO3-V2O5 ternary diagram, Journal of Solid State Chemistry 122, 394–406
Vannier, R.N., Abraham, F., Nowogrocki, G. and Mairesse, G. (1999) New structural and electrical data on Bi-Mo mixed oxides with a structure based on [Bi12O14]8 columns, Journal of solid State Chemistry 142, 294–304
Pernot E. (1994) Relation entre synthèse, structure et conductivité dans Bi4V2O11 et ses substitués (Cu, Ni), Thesis, University of Grenoble
Mairesse, G. (1993) Bismuth-based oxide conductors, novel structural and electrical features, Fast Ion Transport in Solids, 271–290, Kluwer Academic Publishers, the Netherlands
Pernot, E., Anne, M., Bacmann, M., Strobel, P., Fouletier, J., Vannier, R.N., Mairese, G., Abraham, F., Nowogrocki G. (1994) Structure and conductivity of Cu and Ni-substituted Bi4V2O11 compounds, Solid State Ionics 70/71, 259–263
Muller, C., Anne, M., Bacmann, M. (1998) Lattice vibrations and order-disorder transition in the oxide anion conductor BICOVOX.15: a neutron thermodiffractometry study, Solid State Ionics 111, 27–36
Muller, C., Anne, M., Bacmann, M. and Bonnet, M. (1998) Structural studies of the fast oxygen ion conductor BICOVOX.15 by single-crystal neutron diffraction at room temperature, Journal of Solid state Chemistry 141, 241–247
Baux, N., Vannier R.N., Mairesse, G., Nowogrocki G. (1996) Oxide ion conductivity in Bi2W1-xMExO6-x/2 (ME=Nb, Ta), Solid State Ionics 91, 243–248
Islam, M.S., Lazure, S., Vannier, R.N., Nowogrocki, G. and Mairesse, G. (1998) Structural and computational studies of Bi2WO6 based oxygen ion conductors, Journal of Materials Chemistry 8(3), 655–660
Vannier, R.N., Danzé, S., Nowogrocki, G., Huvé, M. and Mairesse, G., A new class of mono-dimensional bismuth-based oxide anion conductors with a structure based on [Bil2O14]8 columns, Solid State Ionics, to be published
Takahashi, T., Iwahara, H., Nagai, Y. (1970), J. Electrochem. Soc. 117, 244
Boivin, J.C., Mairesse, G. (1998) Recent materials developpements in fast oxide ion conductors, Chemistry of Materials 10, 2870–2888 and references therein
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2000 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Vannier, R.N., Boivin, J.C., Mairesse, G. (2000). High Performances Oxide Ion Conductors with Covalent Framework and Liquid-Like Ionic Network. In: Cloots, R., Ausloos, M., Pekala, M., Hurd, A.J., Vacquier, G. (eds) Supermaterials. NATO Science Series, vol 8. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0912-6_13
Download citation
DOI: https://doi.org/10.1007/978-94-010-0912-6_13
Publisher Name: Springer, Dordrecht
Print ISBN: 978-0-7923-6809-0
Online ISBN: 978-94-010-0912-6
eBook Packages: Springer Book Archive