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Calibration and Field Validation of SPME Fibres as Passive Air Samplers for Chlorinated Semivolatile Organic Compounds

  • A. Paschke
  • P. Popp
  • B. Vrana

Abstract

Chlorinated semi volatile organic compounds (SVOCs), for example the pesticides hexachlorobenzene, lindane (and its isomers) or DDT (and its metabolites) which have been used worldwide very extensively in the past, now occur as ubiquitous air pollutants. They are relatively stable in the atmosphere and can undergo medium to long range transport. In contrast to many other pesticides, the abovementioned chlorinated substances have high bioaccumulation potential and can cause direct or indirect effects on non-target plants, terrestrial and aquatic organisms and even on local human populations [Unsworth et al., 1999]. Because prediction of transport and fate of these substances (and thus of their actual or time–integrated atmospheric concentrations) is not exact enough, an extensive monitoring of persistent chlorinated SVOCs is necessary.

Keywords

Passive Sampling SPME Fibre Coated Fibre Field Validation Diffusion Path Length 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. Fuller, E.N.; Schettler, P.D.; Giddings, J.C. (1966): Ind. Eng. Chem. 58: 18–27.CrossRefGoogle Scholar
  2. Huckins, J.N.; Tubergen, M.W.; Manuweera, G.K. (1990): Chemosphere 20: 533–552.CrossRefGoogle Scholar
  3. Huckins, J.N.; Petty, J.D.; Orazio, C.E.; Zajicek, J.L.; Gibson, V.L.; Clark, R.C.; Echols, K.R. (1994): Proceedings of the 15th Annual SETAC Meeting, 30 Oct. - 3 Nov.1994. Denver/CO/USA, Abstract MBoi, p. 106.Google Scholar
  4. Khaled, A. & Pawliszyn, J. (2000): J. Chromatogr. A 892: 455–467.CrossRefGoogle Scholar
  5. Lord, H.; Pawliszyn, J. (2000): J Chromatogr. A 885: 153–193.CrossRefGoogle Scholar
  6. Martos, P. A. & Pawliszyn, J. (1999): Anal. Chem. 71:1513–1520.CrossRefGoogle Scholar
  7. Ockenden, W.A.; Prest, H.F.; Thomas, G.O.; Sweetman, A.; JonesK.C. (1998): Environ. Sci. Technol. 32: 1538–1543.CrossRefGoogle Scholar
  8. Popp, P; Brüggemann, L.; Keil, P.; Thuβ, U.; WEIβ, H. (2000): Chemospere 41: 849–855.CrossRefGoogle Scholar
  9. Prest, H.F.; Jacobson, L.A.; Huckins, J.N. (1995): Chemosphere 30: 1351–1361.CrossRefGoogle Scholar
  10. Unsworth, J.B.; Wauchope, R.D.; Klein, A.W.; Dorn, E.; Zeeh, B.; Yeh, S.M.; Akerblom, M.; Racke, K.D. & Rubin, B. (1999): Pure Appl. Chem. 71: 1359–1383Google Scholar
  11. Vrana, B.; Paschke, A.; Popp, P.; Schourmann, G. (2001): Environ. Sci. Pollut. Res., in press.Google Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2002

Authors and Affiliations

  • A. Paschke
    • 1
  • P. Popp
    • 2
  • B. Vrana
    • 1
  1. 1.Department of Chemical EcotoxicologyUFZ Centre for Environmental ResearchLeipzigGermany
  2. 2.Department of Analytical ChemistryUFZ Centre for Environmental ResearchLeipzigGermany

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