Abstract
New ternary hydride has been synthesised in the reaction of hydrogen with intermetallic Mg2Eu compound of MgZn2 structure type with hydrogen content of 5.0–5.5 g-at/mol MC. Mg2EuH5.5 (a = 5.344(3) Å; c = 8.014(4) Å; P4/nmm space group, Z=2) conceivably has Cu2Sb structure type, so the parameters of heavy atoms were determined and the model of hydrogen atoms arrangement was proposed.
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References
V.N. Verbetsky and S.N. Klyamkin. Izvestija. AN SSSR, Neorganicheskie.materialy. 23, (1987), p.1303.
M.E. Kost, N.G. Kuznetsova and A.L. Shilov. Dokiady AN SSSR. 292, (1987) p.632.
A.N. Sytnikov PhD. Thesis, Moscow, MGU. 1985. pp.174
S.N. Klyamkin, N.V. Kandalova, V.N. Verbetsky and K.N. Semememko. Zh.neorganicheskoi khimii,32,(1991)p..418.
F.W. Oliver, K.W. West, R.X. Cohen and K.H.J. Bushow. J. Phys.F: Metal Phys. 8, (1978), p.701.
K.N. Semenenko and V.V. Burnasheva. Vestnik. MGU. Serija 2 Khimija, 18, (1977), p.618.
W. Klemm, H. Kock and W. Muhlpfordt. Angew.Chem. 76, (1964), p.862.
K.N. Semenenko, S.V. Mitrokhin, V.N. Verbetsky and V.V. Burnasheva. Zh. neorganicheskoi khimii,25,(1980),p.1731.
J.-J. Didisheim, P. Zolliker, K. Yvon, P. Fisher, J. Shefer, M. Gubelmann and A.F. Williams. Inorg. Chem. 23, (1984). p.1953.
M. Kritikos. Chem. Commun. (1991), No.2.
M. Erlander, G. Hagg, A. Westgren. Ark.Kemi. Min.Geol. 12B, No. 1,p. 1936.
R. Wang and H. Steinfmk. Inorg.Chem., 6, (1967). p. 1985.
W.H. Zachariasen and C.E. Holley. Acta Crystallogr. 16, (1963). p.352.
F.H. Ellinger. J. Amer. Chem. Soc, 77, (1955). p.2647.
P. Zolliker, K. Yvon, P. Fischer and J. Schefer. Inorg. Chem. 24, (1985), p.4177.
D. Fruchart, A. Micou, M. Pezat and B. Darriet. Mat. Res. Bull, 19, (1984). p.1119.
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Kandalova, N.V., Sirotinkin, S.P., Verbetsky, V.N. (2002). Synthesis and Properties of Mg2EuH5.5 . In: Hampton, M.D., Schur, D.V., Zaginaichenko, S.Y., Trefilov, V.I. (eds) Hydrogen Materials Science and Chemistry of Metal Hydrides. NATO Science Series, vol 71. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0558-6_14
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DOI: https://doi.org/10.1007/978-94-010-0558-6_14
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