Abstract
For the majority of metal halides the solid state is the natural state; they are involatile ionic crystals, with high coordination number of the metal, and no discernible “molecules.” There are only a few covalent metal halides for which molecules can be distinguished in their crystals. Thus, when we talk about the molecular structure of metal halides, we usually refer to their vapors; it is there, where molecules of metal halide are present.
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Hargittai, M. (2002). Metal Halide Molecular Structures. In: Domenicano, A., Hargittai, I. (eds) Strength from Weakness: Structural Consequences of Weak Interactions in Molecules, Supermolecules, and Crystals. NATO Science Series, vol 68. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0546-3_10
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DOI: https://doi.org/10.1007/978-94-010-0546-3_10
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