Abstract
Acyclic Diene Metathesis (ADMET) Polymerization of dialkenylsubstituted silicon compounds (except divinylsubstituted derivatives) catalyzed by Mo, W, Ru and Re metallacarbene is a universal route for synthesis of linear well defined organosilicon polymers. Divinyldiorganosilicon compounds in the presence of Ru, Rh and Co complexes containing or initiating M-H and M-Si bond undergo competitive Silylative Coupling Polycondensation (SCP) to give linear poly(silylene,siloxylene, silazanylenevinylene)s (also poly(silylene-arylene-vinylene)s and poly(silylene-alkylene-vinylene)s) and/or the ring closure to synthesize organosilicon compounds containing cyclodienes, cyclotrienes or cycloalkenes with exo-cyclic methylidenes. Heterocoupling of di- and tri-vinylsilicon compounds with organic dienes allows a synthesis of dendrimeric polysilylene-arylene-vinylenes. Diallylsubstituted silanes undergo polycondensation via preliminary catalytic isomerization to vinylsilanes followed by their poly-cocondensation to yield silylene-propenylene-polymers.
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Marciniec, B. (2002). Silylative Coupling Polycondensation (SCP) vs. ADMET Polymerization of Divinylsubstituted Silicon Compounds. In: Khosravi, E., Szymanska-Buzar, T. (eds) Ring Opening Metathesis Polymerisation and Related Chemistry. NATO Science Series, vol 56. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0373-5_28
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DOI: https://doi.org/10.1007/978-94-010-0373-5_28
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