Abstract
Stereo-selectivity in catalytic reactions is a very important problem in organic synthesis. Evaluation of the factors determining the stereo-selectivity such as substrate and catalyst structures, reaction parameters, etc makes more clear reaction mechanisms particularly mechanisms of stereo-control. Eventually this allows the development of effective methods of stereo-regulation, which are important not only in the theoretical sense but also for practical use as well. In many cases commercially interesting properties of chemical compounds dramatically depend on their geometrical structure. All the factors mentioned above apply fully to olefin metathesis and cometathesis reactions, and offer an effective general approach for synthesis of linear long chain or macrocyclic compounds, having hydrocarbon skeleton.
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Bykov, V.I., Redkin, D.V., Finkelshtein, E.S. (2002). Stereo-Selectivity of Monocycloolefin Ring-Opening Metathesis. In: Khosravi, E., Szymanska-Buzar, T. (eds) Ring Opening Metathesis Polymerisation and Related Chemistry. NATO Science Series, vol 56. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0373-5_22
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DOI: https://doi.org/10.1007/978-94-010-0373-5_22
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