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High-Temperature NMR Studies of Ionic-Liquid Catalysts

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Green Industrial Applications of Ionic Liquids

Part of the book series: NATO Science Series ((NAII,volume 92))

Abstract

The number of “green” applications of ionic liquids (ILs) is progressively growing in recent years due to the chemical industry reorientation, including catalysis, towards environmentally friendly processes. Sulfuric acid production using silica-supported alkali metal pyrosulfate-vanadium oxide catalyst (M 2S 2O7-V2O5, hereinafter M = Na, K or Cs) was the first prominent application of an IL system in catalysis. SO2 oxidation to SO3 is carried out at high temperatures, where the active component of the catalyst is a melt [1]. Today, similar IL systems are used in the processes of flue gas purification [2], and the technological benefits are recognised worldwide. A recently discovered promising method for the catalytic epoxidation of olefins with supported alkali nitrate melts exemplifies another breakthrough application of catalysis by IL [3].

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Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    O. B. Lapina, V. V. Terskikh & B. S. Bal’Zhinimaev

  2. ICAT (Interdisciplinary Research Centre for Catalysis) and Department of Chemistry, Technical University of Denmark, DK-2800, Lyngby, Denmark

    K. M. Eriksen & R. Fehrmann

Authors
  1. O. B. Lapina
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  2. V. V. Terskikh
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  3. B. S. Bal’Zhinimaev
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  4. K. M. Eriksen
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  5. R. Fehrmann
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Editor information

Editors and Affiliations

  1. Center for Green Manufacturing, The University of Alabama, Tuscaloosa, AL, USA

    Robin D. Rogers

  2. The QUILL Research Centre, The Queen’s University of Belfast, Belfast, Northern Ireland, UK

    Kenneth R. Seddon

  3. V. Vernadsky Institute of General and Inorganic Chemistry, Ukrainian National Academy of Sciences, Kiev, Ukraine

    Sergei Volkov

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Lapina, O.B., Terskikh, V.V., Bal’Zhinimaev, B.S., Eriksen, K.M., Fehrmann, R. (2003). High-Temperature NMR Studies of Ionic-Liquid Catalysts. In: Rogers, R.D., Seddon, K.R., Volkov, S. (eds) Green Industrial Applications of Ionic Liquids. NATO Science Series, vol 92. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0127-4_5

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  • DOI: https://doi.org/10.1007/978-94-010-0127-4_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1137-5

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