Skip to main content

Potential to Apply Ionic Liquids in Industry

Exemplified for the Use as Solvents in Industrial Applications of Homogeneous Catalysis

  • Chapter
Green Industrial Applications of Ionic Liquids

Part of the book series: NATO Science Series ((NAII,volume 92))

Abstract

In general, an ionic liquid is a liquid that consists only of ions. However, the term “ionic liquid” includes an additional special definition to distinguish it from the classical definition of a molten salt. While a molten salt is generally thought to be a high-melting and highly viscous medium, ionic liquids are already liquid at low temperatures (< 80 °C) and have relatively low viscosity. The apparently somewhat arbitrary line draw between a molten salt and an ionic liquid at a melting point of 80 °C can be justified by the abrupt improvement of the applicability of the liquid salts below 80°C. Only a liquid range below this temperature can enable the substitution of conventional organic solvents by ionic liquids.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. Drießen-Hölscher, B., Wasserscheid, P., and Keim, W. (1998) Recycle of homogeneous transition metal catalysis in two liquid phases, CATTECH [June], 47–52.

    Google Scholar 

  2. Boon, J.A., Levisky, J.A., Pflug, J.L. and Wilkes, J.S. (1986) Friedel-Crafts reactions in ambient-temperature molten salts J. Org. Chem. 51, 480–486.

    Article  CAS  Google Scholar 

  3. Chauvin, Y., Gilbert, B., and Guibard, I. (1990) Catalytic dimerisation of alkenes by nickel complexes in organochloroaluminate molten salts, J. Chem. Soc., Chem. Commun. 1715–1716.

    Google Scholar 

  4. Burridge, E. (1999) Catalysis Creations, ECN Chemscope May, 27–28.

    Google Scholar 

  5. Welton, T. (1999) Room-temperature ionic liquids. Solvents for synthesis and catalysis, Chem. Rev. 99, 2071–2083.

    Article  CAS  Google Scholar 

  6. Holbrey, J.D. and Seddon, K.R. (1999) Ionic liquids, Clean Products and Processes, 1, 232–236.

    Google Scholar 

  7. Wilkes, J.S. and Zaworotko, M.J. (1992) Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids, J. Chem. Soc. Chem. Commun, 965–967.

    Google Scholar 

  8. Fuller, J., Carlin, R.T., de Long, H.C., and Haworth, D. (1994) Structure of 1-ethy1-3-methylimidazolium hexafluorophosphate: Model for room temperature molten salts, J. Chem. Soc. Chem. Commun. 299–300.

    Google Scholar 

  9. Brasse, C.C., Englert, U., Salzer, A., Waffenschmidt, H., and Wasserscheid, P. Organometallics, submitted for publication.

    Google Scholar 

  10. Cornils, B. and Herrmann, W. A. (1998) Aqueous-Phase Organometallic Catalysis, Wiley-VCH, Weinheim.

    Google Scholar 

  11. Cornils, B. and Herrmann, W. A. (1998) Aqueous-Phase Organometallic Catalysis, Wiley-VCH, Weinheim, p.12.

    Google Scholar 

  12. Keim, W., Vogt, D., Waffenschmidt, H., and Wasserscheid, P. (1999) New method to recycle homogeneous catalysts from monophasic reaction mixtures by using an ionic liquid examplified for the Rh-catalysed hydroformylation of methy1-3-pentenoate, J. Catal. 186, 481–484.

    Article  CAS  Google Scholar 

  13. Chauvin, Y., Einloft, S., and Olivier, H. (1995) Catalytic dimerization of propene by nickel-phosphine complexes in 1-buty1-3-methylimidazolium chloride/AlEtxCl3-x (x= 0.1) ionic liquids, Ind. Eng. Chem. Res. 34, 1149–1155.

    Article  CAS  Google Scholar 

  14. Chauvin, Y., Olivier, H., Wyrvalski, C.N., Simon, L.C., and de Souza, R.F. (1997) Oligomerisation of n-butenes catalyzed by nickel complexes dissolved in organochloroaluminate ionic liquids, J. Catal. 165, 275–278.

    Article  CAS  Google Scholar 

  15. Chauvin, Y., Einloft, S., and Olivier, H. (1996) US Patent 5, 550,304.

    Google Scholar 

  16. Keim, W., Hoffmann, B., Lodewick, R., Peukert, M., Schmitt, G., Fleischhauer, J., and Meier, U. (1979) Linear oligomerization of olefins via nickel chelate komplexes and mechanistic considerations based on semi-empiric calculations, J. Mol. Catal. 6, 79–97.

    Article  CAS  Google Scholar 

  17. Carlin, R.T. and Wilkes, J.S. (1994) Chemistry and speciation in room-temperature chloroaluminate molten salts, in G. Mamantov and A.I. Popov (eds.), Chemistry of Nonaqueous Solutions: Current Progress, VCH Publishers Inc., New York, pp. 277–306.

    Google Scholar 

  18. Ellis, B., Keim, W., and Wasserscheid P. (1999) Linear dimerisation of but-1-ene in biphasic mode using buffered chloroaluminate ionic liquid solvents, Chem. Commun. 337–338.

    Google Scholar 

  19. Melton T., Joyce, J., Maloy, J.T., Boon, J.A., and Wilkes, J.S. (1990) Electrochemical studies of sodium-chloride as a Lewis buffer for room-temperature chloroaluminate molten-salts, J. Electrochem. Soc 137, 3865–3869.

    Article  CAS  Google Scholar 

  20. http://www.solvent-innovation.com; March 2000.

    Google Scholar 

  21. http://www.acros.com

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Wasserscheid, P. (2003). Potential to Apply Ionic Liquids in Industry. In: Rogers, R.D., Seddon, K.R., Volkov, S. (eds) Green Industrial Applications of Ionic Liquids. NATO Science Series, vol 92. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0127-4_2

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-0127-4_2

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1137-5

  • Online ISBN: 978-94-010-0127-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics