Abstract
The results of third-order nonlinear susceptibility studies of Fe- and Zn-doped polyvinylpyrrolidone (PVP) in processes of third harmonic generation (THG) of Nd:YAG laser radiation are presented. Nonlinear susceptibilities (χ (3) (-3ω;ω,ω,ω)) of PVP:Fe and PVP:Zn were calculated to be 5×10-13 esu and 3×10-13 esu respectively. Third harmonic conversion efficiencies in these metalocomplexes were measured to be 8×10-7 and 5×10-7 respectively. The influence of high-frequency Kerr nonlinearities in PVP:Fe was negligible on the I 3ω(I ω) dependence. The optical limiting studies of cobalt-doped PVP have shown that this process was due to self-defocusing at the wavelength of 1064 nm and due to reverse saturable absorption and self-defocusing at the wavelength of 532 nm. The results of nonlinear optical characteristics (n2, χ (3) (-ω;ω,ω,ω), β) measurements of investigated media are discussed.
We also present the theoretical calculations of nonlinear susceptibilities, responsible for the frequency conversion and self-interaction effects, and of nonlinear refractive indices of organic dyes. The values of third- and fifth-order nonlinear susceptibilities responsible for the THG of Nd: YAG laser radiation are calculated on the basis of free electron model. In particular, the nonlinear susceptibilities χm (3) (-3ω;ω,ω,ω) of paraterphenyl and pentacene were calculated to be 2.4×10-30 esu and 1.7×10-30 esu respectively. The relation between the length of conjugated bonds of organic dyes and their third- and fifth-order nonlinear susceptibilities has been analysed. Calculations of third-order Kerr-induced nonlinear susceptibilities and nonlinear refractive indices of organic dyes are presented.
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Ganeev, R.A., Ryasnyansky, A.I., Tugushev, R.I., Usmanov, T. (2003). Characterization of Nonlinear Optical Parameters of Metal-Doped Polyvinylpyrrolidone Nanostructures and Organic Dye Molecules. In: Charra, F., Agranovich, V.M., Kajzar, F. (eds) Organic Nanophotonics. NATO Science Series, vol 100. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0103-8_31
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DOI: https://doi.org/10.1007/978-94-010-0103-8_31
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