Skip to main content

Part of the book series: NATO Science Series ((NAIV,volume 27))

  • 143 Accesses

Abstract

Laboratory studies of the mid and near infrared collision-induced absorption bands of O2 are reviewed, with an emphasis on the 6.4 μm and 1.27 μm bands and on Ar, O2, N2, and CO2 collision partners. These absorption bands are important in the radiative balance of the atmo- sphere and contribute to the background absorption in remote-sensing radiometers. Also discussed is the ripple structure observed on the 6.4 μm band, which is absent from the 1.27 μm band. This structure has been attributed to dimers or to line mixing involving the weakly allowed electric-quadrupole absorptions. Finally, the strong enhancement of the collision-induced absorption by CO2 collisions is shown.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Pfeilsticker, K., Erle, F., and Platt, U. (1997) Absorption of solar radiation by atmospheric O4, J. Atmos. Sci., 54, 933–939.

    Article  Google Scholar 

  2. Massie, S. T., Gille, J. C., Edwards, D.P., Bailey, P.L., Lyjak, L.V., Craig, C. A., Cavanaugh, C. P., Mergenthaler, J. L., Roche, A. E., Kumer, J.B., Lambert, A., Grainger, R. G., Rodgers, C. D., Taylor, F. W., Russell, J.M., III,  Park, J. H., Deshler, T., Hervig, M.E., Fishbein, E. F., Waters, J.W., and Lahoz, W.A. (1996) Validation studies using multiwavelength Cryogenic Limb Array Etalon Spectrometer (CLAES) observations of stratospheric aerosol, J. Geophys. Res., 101, 9757–9773.

    Article  Google Scholar 

  3. Edwards, D. P., Gille, J. C., Bailey, P. L., and Barnett, J.J. (1995) Selection of sounding channels for the High Resolution Dynamics Limb Sounder, Appl. Optics, 34, 7006–7018.

    Article  Google Scholar 

  4. Rinsland, C. P., Yue, G. K., Gunson, M. R., Zander, R., and Abrams, M. C. (1994) Mid-infrared extinction by sulfate aerosols from the Mt. Pinatubo eruption, J. Quant. Spectrosc. Radiat. Transfer, 52, 241–252.

    Article  Google Scholar 

  5. Goss-Custard, M., Remedios, J. J., Lambert, A., Taylor, F.W., Rogers, CD., Lopez-Puertos, M., Zaragoza, G., Gunson, M. R., Suttie, M.R., Harries, J. E., and Russell J.M., III, (1996) Measurements of water vapor distributions by the improved stratospheric and mesospheric sounder: Retrieval and validation, J. Geophys. Res. Atmos., 101, 9907–9928.

    Article  Google Scholar 

  6. Rinsland, C.P., Smith, M. A. H., Seals, Jr., R. K., Goldman, A., Murcray, F. J., Murcray, D. G., Larsen, J.C., and Rarig, P. L. (1982) Stratospheric measurements of collision-induced absorption by molecular oxygen, J. Geophys. Res., 87, 3119–3122.

    Article  Google Scholar 

  7. Rinsland, C. P., Zander, R., Namkung, J. S., Farmer, C.B., and Norton, R. H. (1989) Stratospheric infrared continuum absorptions observed by the ATMOS instrument, J. Geophys. Research, 94, 16303–16322.

    Article  Google Scholar 

  8. Dyke, T.R., Mack, K.M., and Muenter, J. S. (1977) Structure of water dimer from Molecular-Beam Electric Resonance Spectroscopy, J. Chem. Phys., 66, 498–510.

    Article  Google Scholar 

  9. Jucks, K.W., Huang, Z.S., Miller, R.E., Fraser, G. T., Pine, A. S., and Lafferty, W.J. (1988) Structure and vibrational dynamics of the CO2 dimer from the sub-Doppler infrared spectrum of the 2.7 μm Fermi dyad, J. Chem. Phys., 88, 2185–2195.

    Article  Google Scholar 

  10. Peterson, K. I. and Klemperer, W. (1984) Structure and internal rotation of H2O-CO2, HDO-CO2, and D2O-CO2 van der Waals complexes, J. Chem. Phys., 80, 2439–2445.

    Article  Google Scholar 

  11. Leung, H.O., Marshall, M. D., Suenram, R. D., and Lovas, F. J. (1989) Microwave spectrum and molecular structure of the N2-H2O complex, J. Chem. Phys., 90, 700–712.

    Article  Google Scholar 

  12. Maté, B., Lugez, CL., Fraser, G. T., and Lafferty, W. J. (1999) Absolute inten- sities for the O2 1.27 μm continuum absorption, J. Geophys. Research, 104, 30585–30590.

    Article  Google Scholar 

  13. Maté, B., Lugez, CL., Solodov, A. M., Fraser, G. T., and Lafferty, W. J. (2000) Investigation of the collision-induced absorption by O2 near 6.4 μm in pure O2 and O2/N2 mixtures, J. Geophys. Research, 105, 22225–22230.

    Article  Google Scholar 

  14. Fraser, G. T. and Lafferty, W. J. (2001) 1.27 μm O2 continuum absorption in O2/CO2 mixtures, J. Geophys. Research, 106, 31749–31753.

    Article  Google Scholar 

  15. McKellar, A. R. W. (1988) Infrared spectra of the (N2)2 and N2-Ar van der Waals molecules, J. Chem. Phys., 88, 4190–4196.

    Article  Google Scholar 

  16. Moreau, G., Boissoles, J., Le Doucen, R., Boulet, C, Tipping, R. H., and Ma, Q. (2001) Metastable dimer contributions to the collision-induced fundamental absorption spectra of N2 and O2 pairs, J. Quant. Spectrosc. Radiat. Transfer, 70, 99–113.

    Article  Google Scholar 

  17. Vigasin, A.A. (1996) On the nature of collision-induced absorption in gaseous homonuclear diatomics, J. Quant. Spectrosc. Radiat. Transfer, 56, 409–422.

    Article  Google Scholar 

  18. Vigasin, A. A. (2000) Collision- induced absorption in the region of the O2 fundamental: Bandshapes and dimeric features, J. Mol. Spectrosc, 202, 59–66.

    Article  Google Scholar 

  19. Shapiro, M. M. and Gush, H. P. (1966) The collision-induced fundamental and first overtone bands of oxygen and nitrogen, Can J. Phys., 44, 949–963.

    Article  Google Scholar 

  20. Orlando, J. J., Tyndall, G. S., Nickerson, K. E., and Calvert, J. G. (1991) Temperature dependence of collision-induced absorption by oxygen near 6 μm, J. Geophys. Research, 96, 20755–20760.

    Article  Google Scholar 

  21. Thibault, F., Menoux, V., Le Doucen, R., Rosenmann, L., Hartmann, J.-M., and Boulet, C. (1997) Infrared collision-induced absorption by O2 near 6.4 μm for atmospheric applications: Measurements and empirical modeling, Appl. Opt., 36, 562–567.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer Science+Business Media Dordrecht

About this paper

Cite this paper

Baranov, Y.I., Fraser, G.T., Lafferty, W.J., Maté, B., Vigasin, A.A. (2003). Laboratory Studies of Oxygen Continuum Absorption. In: Camy-Peyret, C., Vigasin, A.A. (eds) Weakly Interacting Molecular Pairs: Unconventional Absorbers of Radiation in the Atmosphere. NATO Science Series, vol 27. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0025-3_13

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-0025-3_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1596-0

  • Online ISBN: 978-94-010-0025-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics