Abstract
In molecular physics scientists are inclined to interpret interactions between atoms, ions or molecules by a set of “forces” which usually are grouped into different classes: weak and strong, specific and unspecific, etc. Quantum mechanics, on the other hand, tells us that there is no unique wav to split a given energy of interaction into “physically” meaningful contributions as long as the charge distributions of individual atoms, ions or molecules are spread over unlimited regions due to the exponential decay of their wave functions (see eg. Ahlrichs [1976]). The source of these ambiguities is the mutual penetration of electron density distributions of the interacting subunits which can be expressed quantitatively in terms of overlap integrals.
This contribution consists of parts of a review by Schuster 1977.
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Schuster, P. (1978). Hydrogen Bonding between Molecules or Ions and in Molecular Crystals. In: André, JM., Delhalle, J., Ladik, J. (eds) Quantum Theory of Polymers. NATO Advanced Study Institutes Series, vol 39. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9812-4_12
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DOI: https://doi.org/10.1007/978-94-009-9812-4_12
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