Abstract
Since 1966 the Wilkinson catalyst RhCl[P(C6H5)3]3 is used for the homogeneous hydrogenation of olefins mostly under conditions as mild as room temperature and hydrogen of atmospheric pressure (1). In 1968 the groups of Horner and Knowles used optically active phosphines instead of triphenylphosphine for the hydrogenation of prochiral olefins and
observed the formation of optically active hydrogenation products (2,3). In the past decade progress in the field of catalytic asymmetric hydrogenation of prochiral olefins was mainly associated with the development of new optically active chelate ligands, four examples of which are shown in scheme 1 (4–7).
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References
Osborn, J.A., Jardine, F.H., Young, J.F., and Wilkinson, G.: 1966, J. Chem. Soc. A, pp. 1711.
Horner, L., Siegel, H., and Büthe, H.: 1968, Angew.Chem. 80, pp. 1034;
Knowles, W.S. and Sabacky, M.J.: 1968, JCS Chem.Comm., pp. 1445.
Kagan, H.B. and Dang, T.P.: 1972, J.Amer.Chem.Soc. 94, pp. 6429.
Knowles, W.S., Sabacky, M.J., Vineyard, B.D., and Weinkauf, D.J.: 1975, J.Amer.Chem.Soc. 97, pp. 2567.
Fryzuk, M.D. and Bosnich, B.: 1977, J.Amer.Chem.Soc. 99, pp. 62 62.
Fryzuk, M.D. and Bosnich, B.: 1978, J.Amer.Chem.Soc. 100, pp. 5491.
Nesterova, N.P., Medved, T.Y., Polikarpov, Y.M., and Kabachnik, M.K.: 1974, Izv.Akad.Nauk SSSR Ser.Khim. 10, pp. 2210.
Naumann, K., Zon, G., and Mislow, K.: 1969, J. Amer. Chem. Soc. 91, pp. 7013.
Brunner, H. and Pieronczyk, W.: Angew.Chem., in press.
Brunner, H.: 1971, Angew.Chem. 83, pp. 274;
Brunner, H.: 1971, Angew. Chem. int. Ed. Engl. 10, pp. 249.
Brunner, H.: 1974, Ann. N.Y. Acad. Sci. 239, pp. 213.
Brunner, H.: 1975, Top. Curr. Chem. 56, pp. 67.
Brunner, H.: 1977, Chemie in unserer Zeit 11, pp. 157.
Brunner, H.: Acc. Chem. Res., in press.
Brunner, H.: Adv. Organometal. Chem., in press.
Brunner, H., in Koerner von Gustorf, E.A., Grevels, F.-W., and Fischler, I.: 1978, Organic Chemistry of Iron, Vol. 1, Academic Press, pp. 299.
Brunner, H., Herrmann, W.A., and Wachter, J.: 1976, J.Organometal.Chem. 107, pp. C11.
Brunner, H. and Wachter, J.: 1977, Chem. Ber. 110, pp. 721.
Brunner, H. and Lukas, R.: Chem. Ber., in press.
Brunner, H. and Rastogi, D.K.: Inorg. Chem., in press.
Brunner, H., Doppelberger, J., Dreischl, P., and Mol1enberg, T.: 1977, J.Organometal.Chem. 139, p. 223.
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Brunner, H. (1979). Asymmetric Homogeneous Hydrogenation of Prochiral Olefins and Control of the Metal Configuration in Labile Optically Active Organotransition Metal Complexes. In: Pullman, B. (eds) Catalysis in Chemistry and Biochemistry Theory and Experiment. The Jerusalem Symposia on Quantum Chemistry and Biochemistry, vol 12. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9513-0_20
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DOI: https://doi.org/10.1007/978-94-009-9513-0_20
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