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Lattice Mode Structure of Graphite Intercalation Compounds

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Intercalated Layered Materials

Part of the book series: Physics and Chemistry of Materials with Layered Structures ((PCMA,volume 6))

Abstract

At first sight, a discussion of the lattice, electronic and structural properties of graphite intercalation compounds would appear to be an exceedingly difficult task in view of the large number of intercalate species which form intercalation compounds. A great simplification of the discussion of the graphite intercalation compounds results from emphasis on the strong intralayer bonding in both the graphitic and intercalate layers and the relatively weak interlayer bonding between graphite-intercalate layers and graphite-graphite layers in the intercalation compounds. Thus many of the properties of the graphite intercalation compounds can be understood by identification of the graphite and intercalate layers with their respective parent materials. For this reason, knowledge of the structural, lattice and electronic properties of the parent materials is important for understanding the properties of the corresponding intercalation compounds. To be sure, differences in these properties are found for compounds formed by the various intercalate species but the similarities are more significant. The largest differences occur between classes of intercalation compounds, such as donor and acceptor compounds. For the donors, the intercalate species tends to be ionic and the interlayer interaction is greater than for pristine graphite, while acceptor intercalates tend to be molecular and have a weaker interlayer interaction than for pristine graphite. The similarities between various classes of intercalation compounds are great, and by emphasizing these similarities, a more coherent picture of this class of materials can be presented.

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References

  1. G. R. Hennig, in Prog. Inorg. Chem. 1 (Edited by F. A. Cotton ), Interscience Publishers, Inc., New York (1959), 125.

    Google Scholar 

  2. A. R. Ubbelohde and L. A. Lewis, in Graphite and its Crystal Compounds, (Oxford, 1960 ).

    Google Scholar 

  3. W. Rüdorff, in Adv. Inorg. Chem. Radiochem. (Edited by H. J. Emeleus and A. G. Sharpe, Academic Press, New York ) 1 (1959), 223.

    Google Scholar 

  4. W. Rüdorff, Z. Anorg. Allg. Chem. 254 (1947), 319.

    Google Scholar 

  5. D. Guérard and A. Hérold, C.R. Acad. Sci. 279 (1974), 455.

    Google Scholar 

  6. D. Guérard and A. Hérold, Carbon 13 (1975), 337.

    Google Scholar 

  7. W. Rüdorff and E. Schulze, Z. Anorg. Allg. Chem. 277 (1954), 156.

    Google Scholar 

  8. D. E. Nixon and G. S. Parry, Brit. J. Appl. Phys. 1 (1968), 291.

    CAS  Google Scholar 

  9. G. S. Parry and D. E. Nixon, Nature 216 (1967), 909.

    CAS  Google Scholar 

  10. G. S. Parry, D. E. Nixon, K. M. Lester and B. C. Levene, J. Phys. Chem. 2 (1969), 2156.

    CAS  Google Scholar 

  11. G. S. Parry, Mater. Sci. Eng. 31 (1977), 99.

    CAS  Google Scholar 

  12. D. D. L. Chung, G. Dresselhaus and M. S. Dresselhaus, Mater. Sci. Eng. 31 (1977), 107.

    CAS  Google Scholar 

  13. See Ref. 1, p. 157.

    Google Scholar 

  14. A. R. Ubbelohde, Proc. Roy. Soc. A327 (1972), 289.

    CAS  Google Scholar 

  15. G. M. T. Foley, C. Zeller, E. R. Falardeau, and F. L. Vogel, Solid State Commun. 24, (1977), 371.

    CAS  Google Scholar 

  16. A. S. Bender and D. A. Young, J. Phys. C. 5 (1972), 2163.

    CAS  Google Scholar 

  17. S. Tanuma, H. Suematsu, K. Higuchi, R. Inada and Y. Onuki, (to be published in the proceedings of the conference on The Application of High Magnetic Fields in Semiconductor Physics, Oxford, September, 1978.

    Google Scholar 

  18. D. D. L. Chung and M. S. Dresselhaus, Solid State Commun. 19 (1976), 227.

    CAS  Google Scholar 

  19. D. D. L. Chung and M. S. Dresselhaus, Physica 89B (1977), 131.

    Google Scholar 

  20. D. D. L. Chung, Ph.D. Thesis, Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA., U.S.A. (1977) (unpublished).

    Google Scholar 

  21. I. L. Spain, in Chemistry and Physics of Carbon (Edited by P. L. Walker and P. A. Thrower ), Dekker, New York, 8 (1973), 1.

    Google Scholar 

  22. J. W. McClure, in the Physics of Semimetals and Narrow-Gap Semiconductors Edited by D. L. Carter and R. T. Bate), Pergamon Press, New York (1971), pl27.

    Google Scholar 

  23. D. A. Platts, D. D. L. Chung and M. S. Dresselhaus, Phys. Rev. B15 (1977), 1087.

    CAS  Google Scholar 

  24. G. Dresselhaus and M. S. Dresselhaus, Mater. Sci. Eng. 31 (1977), 235.

    CAS  Google Scholar 

  25. M. S. Dresselhaus, G. Dresselhaus and J. E. Fischer, Phys. Rev. B15 (1977), 3180.

    CAS  Google Scholar 

  26. G. R. Hennig, J. Chem. Phys. 20, (1952), 1438; ibid. 20, (1952), 1443.

    CAS  Google Scholar 

  27. J. J. Murray and A. R. Ubbelohde, Proc. Roy. Soc. A312 (1969), 371.

    CAS  Google Scholar 

  28. A. R. Ubbelohde, Proc. Roy. Soc. A321 (1971) 445.

    CAS  Google Scholar 

  29. G. Guérard, G. M. T. Foley, M. Zanini and J. E. Fischer, Il Nuovo Cimento 38B (1977), 410.

    Google Scholar 

  30. J. E. Fischer, Mater. Sci. Eng. 31 (1977), 211.

    CAS  Google Scholar 

  31. I. L. Spain, and D. J. Nagel Mater. Sci. Eng. 31 (1977), 183.

    CAS  Google Scholar 

  32. A. R. Ubbelohde, Mater. Sci. Eng. 31 (1977), 341.

    CAS  Google Scholar 

  33. J. E. Fischer, Chapter this volume.

    Google Scholar 

  34. J. C. Slonczewski and P. R. Weiss, Phys. Rev. 109 (1958), 272.

    CAS  Google Scholar 

  35. J. W. McClure, Phys. Rev. 108 (1957), 612.

    CAS  Google Scholar 

  36. T. Inoshita, K. Nakao and H. Kamimura, J. Phys. Soc. Japan 43 (1977), 1237.

    CAS  Google Scholar 

  37. N. A. W. Holzwarth and S. Rabii, Mater. Sci. Eng. 31 (1977), 195.

    CAS  Google Scholar 

  38. P. C. Eklund, G. Dresselhaus, M. S. Dresselhaus and J. E. Fischer, Phys. Rev. B16 (1977), 3330.

    CAS  Google Scholar 

  39. M. S. Dresselhaus, G. Dresselhaus, P. C. Eklund and D. D. L. Chung, Mater. Sci. Eng. 31 (1977), 141.

    CAS  Google Scholar 

  40. A. W. Moore, in Chemistry and Physics of Carbon (Edited by P. L. Walker and P. A. Thrower ), Dekker, New York 11 (1973), 69.

    Google Scholar 

  41. J. W. Cowley and J. A. Ibers, Acta Cryst. 9 (1956), 421.

    CAS  Google Scholar 

  42. W. T. Eeles and J. A. Turnbull, Proc. Roy. Soc. (London) A283 (1965), 179. J. A. Turnbull and W. T. Eeles, 2nd Conf. on Ind. Carbon and Graphite, Soc. Chem. Ind., London, 1966, p. 173.

    Google Scholar 

  43. M. K. Halpin and G. M. Jenkins, 3rd Conf. on Ind. Carbon and Graphite, Soc. Chem. Ind., London, 1970, p. 53.

    Google Scholar 

  44. A. Hérold, Chapter this volume.

    Google Scholar 

  45. B. Hirsch, A. Howie, R. B. Nicholson, D. W. Pashley and M. J. Whelan, in Electron Microscopy of Thin Crystals, (Butterworths, London, 1965) ch. 6.

    Google Scholar 

  46. B. N. Brockhouse, S. Hautecler and H. Stiller, in Interaction of Radiation with Solids (Edited by Strumane et al. North-Holland (1963), p 580.

    Google Scholar 

  47. W. D. Ellenson, D. Semmingsen, D. Guérard, D. G. Onn and J. E. Fischer, Mater. Sci. Eng. 31 (1977), 137.

    CAS  Google Scholar 

  48. R. J. Nemanich, S. A. Solin and D. Guérard, Phys. Rev. B16 (1977), 2965.

    CAS  Google Scholar 

  49. S. A. Solin, Mater. Sci. Eng. 31 (1977), 153.

    CAS  Google Scholar 

  50. L. J. Brillson, E. Burstein, A. A. Maradudin and T. Stark, in the Physics of Semimetals and Narrow Gap Semiconductors, Dallas, Texas, 1960 (Edited by D. L. Carter and R. T. Bate ), Pergamon Press, New York (1971), p. 187.

    Google Scholar 

  51. L. J. Brillson, Ph.D. Thesis, Department of Physics, University of Pennsylvania, Philadelphia, PA, U.S.A. (1972) (unpublished).

    Google Scholar 

  52. F. Tuinstra and J. L. Koenig, J. Chem. Phys. 53 (1970), 1126.

    CAS  Google Scholar 

  53. R. A. Friedel and G. C. Carlson, J. Phys. C. 75 (1971), 1149.

    CAS  Google Scholar 

  54. S. A. Solin, R. J. Nemanich and G. Lucovsky, Mater. Sci. Eng. 31 (1977), 159.

    Google Scholar 

  55. R. Nicklow, N. Wakabayashi and H. G. Smith, Phys. Rev. B5 (1972), 4951.

    Google Scholar 

  56. R. W. G. Wyckoff, in Crystal Structures (Interscience Publishers, Inc., New York, 1948), second edition, volume I.

    Google Scholar 

  57. R. Juza and V. Wehle, Natw. 52 (1965), 560.

    CAS  Google Scholar 

  58. R. C. Asher, J. Inorg. Nucl. Chem. 10 (1959), 238.

    CAS  Google Scholar 

  59. W. Rüdorff, Z. Phys. Chem. B45 (1939), 42.

    Google Scholar 

  60. A. R. Ubbelohde, Proc. Roy. Soc. (London) A304 (1968), 25.

    CAS  Google Scholar 

  61. D. E. Nixon, G. S. Parry and A. R. Ubbelohde, Proc. Roy. Soc. (London) A291 (1966), 324.

    CAS  Google Scholar 

  62. W. Rüdorff and H. Schultz, Z. Anorg. Allg. Chem. 245 (1940), 12.

    Google Scholar 

  63. W. Metz and D. Hohlwein, Carbon 13 (1975), 84; 13 (1975), 87.

    CAS  Google Scholar 

  64. J. M. Thomas, G. R. Millward, N. C. Davies and E. L. L. Evans, J. Chem. Soc., Dalton Trans. 23 (1976), 2443.

    Google Scholar 

  65. J. Mélin and A. Hérold, C.R. Acad. Sci. 280 (1975), 641.

    Google Scholar 

  66. E. R. Falardeau, L. R. Hanlon and T. E. Thompson, Inorg. Chem. 17 (1978), 301.

    CAS  Google Scholar 

  67. W. Rüdorff, V. Sils, R. Zeller, Z. Anorg. Allg. Chem. 283 (1956), 299.

    Google Scholar 

  68. J. Maire and J. Mering, Proc. 3rd Carbon Conf, Buffalo (1957), Pergamon Press, New York 3 (1959), 337.

    Google Scholar 

  69. T. Sasa, Y. Takahashi and T. Mukaibo, Carbon 9 (1971), 407.

    CAS  Google Scholar 

  70. Y. Mizutani, Kyoto Daigaku Genski Enerugi Kenkyusho Iho 41 (1972), 61; 44 (1973), 57.

    CAS  Google Scholar 

  71. W. Rüdorff and W. F. Siecke, Chem. Ber. 91 (1958), 1348.

    Google Scholar 

  72. F. Beguin and R. Setton, Carbon 13 (1975), 293.

    CAS  Google Scholar 

  73. R. Setton, Mater. Sci. Eng. 31 (1977), 303.

    CAS  Google Scholar 

  74. J. J. Song, D. D. L. Chung, P. C. Eklund and M. S. Dresselhaus, Solid State Comm. 20 (1976), 1111.

    CAS  Google Scholar 

  75. J. E. Cahill and G. E. Leroi, J. Chem. Phys. 51 (1966), 4514.

    Google Scholar 

  76. P. C. Eklund, N. Kambe, G. Dresselhaus and M. S. Dresselhaus Phys. Rev. B18 (1978) 7069.

    CAS  Google Scholar 

  77. R. Swanson, Thesis, Stanford University (1969); available from University Microfilms, Ann Arbor, Michigan.

    Google Scholar 

  78. B. Bach, C.R. Acad. Sci. B273 (1971). 666.

    CAS  Google Scholar 

  79. B. Bach, E. L. L. Evans, J. M. Thomas and M. Barber, Chem. Phys. Letters 10 (1971), 547.

    CAS  Google Scholar 

  80. L. E. Schmutz, D. D. L. Chung, R. A. Wachnik, P. C. Eklund and M. S. Dresselhaus, Bull. Am. Phys. Soc. 22 (1977), 420.

    Google Scholar 

  81. G. R. Hennig, J. Chem. Phys. 43 (1965), 1201.

    CAS  Google Scholar 

  82. M. Zanini and J. E. Fischer, Mater. Sci. Eng. 31 (1977), 168.

    Google Scholar 

  83. J. E. Fischer, T. E. Thompson and F. L. Vogel, in Petroleum-Derived Carbons, ACS Symposium Series 21, (eds. M. L. Deviney and T. M. O’Grady ), American Chemical Society, Washington (1975), 418.

    Google Scholar 

  84. J. E. Fischer, T. E. Thompson, G. M. T. Foley, D. Guerard, M. Hoke and F. L. Lederman, Phys. Rev. Lett. 37 (1976), 769.

    CAS  Google Scholar 

  85. A. Avogadro, G. Bellodi, G. Borghesi, G. Samoggia and M. Villa, Il Nuovo Cimento B38 (1977), 418.

    Google Scholar 

  86. L. R. Hanlon, E. R. Falardeau and J. E. Fischer, Solid State Commun. 24 (1977) 377.

    CAS  Google Scholar 

  87. E. A. Taft and H. R. Philipp, Phys. Rev. A138 (1965), 197.

    CAS  Google Scholar 

  88. K. Siegbahn et. al., in ESCA: Atomic, Molecular and Solid State Structure Studied by Means of Electron Spectroscopy (Uppsala, 1967 ), Nova Acta Regiae Societatis Scientiarum Upsaliensis, Ser. IV, Vol. 20.

    Google Scholar 

  89. M. S. Dresselhaus and J. G. Mavroides, IBM J. Res. Develop. 8 (1964), 262.

    CAS  Google Scholar 

  90. P. R. Schroeder, M. S. Dresselhaus and A. Javan, Phys. Rev. Letters 20 (1968), 1292.

    CAS  Google Scholar 

  91. P. R. Schroeder, M. S. Dresselhaus and A. Javan, in The Physics of Semimetals and Narrow Gap Semiconductors (Edited by D. L. Carter and R. T. Bate ), Pergamon Press, New York (1971), p. 139.

    Google Scholar 

  92. W. W. Toy, M. S. Dresselhaus and G. Dresselhaus, Phys. Rev. B15 (1977), 4077.

    CAS  Google Scholar 

  93. J. W. McClure, Phys. Rev. 119 (1960), 606.

    CAS  Google Scholar 

  94. R. A. Wachnik, B.S. Thesis, Department of Physics, Massachusetts Institute of Technology, Cambridge, MA, U.S.A. (1977), (unpublished).

    Google Scholar 

  95. H. Venghaus, Phys. State. Sol. B81 (1977), 221.

    CAS  Google Scholar 

  96. H. R. Philipp, Phys. Rev. B16 (1977), 2896.

    Google Scholar 

  97. R. J. Nemanich, G. Lucovsky and S. A. Solin, Solid State Commun. 23 (1977), 117. A. P. P. Nicholson and D. J. Bacon, J. Phys. C: Solid State Phys. 10 (1977), 2295. J. A. Young and J. U. Koppel, J. Chem. Phys. 42 (1965), 357.

    CAS  Google Scholar 

  98. R. J. Nemanich and S. A. Solin, Solid State Commun. 23 (1977), 417.

    CAS  Google Scholar 

  99. P. C. Eklund and E. R. Falardeau (to be published).

    Google Scholar 

  100. G. Herzberg, in Spectra of Diatomic Molecules, D. Van Nostrand Company, Inc., Princeton, N.J. (1945).

    Google Scholar 

  101. J. R. Scott, Rev. Mod. Phys. 46 (1974), 83.

    CAS  Google Scholar 

  102. G. P. Carver, Phys. Rev. B2 (1970), 2284.

    Google Scholar 

  103. L. E. Campbell, G. L. Montet and G. J. Perlow, Phys. Rev. B15 (1977), 3318.

    CAS  Google Scholar 

  104. American Institute of Physics Handbook, 3rd ed. (Edited by D. E. Gray), McGraw Hill, New York (1972), p. 4–115.

    Google Scholar 

  105. U. Mizutani, T. Kondow and T. B. Massalski, Phys. Rev. B17 (1978), 3165.

    CAS  Google Scholar 

  106. T. Kondow, U. Mizutani and T. B. Massalski, Mater. Sci. Eng. 31 (1977), 267.

    CAS  Google Scholar 

  107. M. D. Chinn and S. C. Fain, Jr., J. Vac. Sci. Tech. 14 (1977), 314; Phys. Rev. Lett. 39 (1977), 146.

    CAS  Google Scholar 

  108. F. A. Putnam and T. Fort, Jr., J. Phys. Chem. 79 (1975), 459.

    CAS  Google Scholar 

  109. H. Schechter, J. G. Dash, M. Mor, R. Ingalls and S. Bukshpan, Phys. Rev. B14 (1976), 1876.

    Google Scholar 

  110. H. Taub, H. R. Danner, Y. P. Sharma, H. L. McMurry and R. M. Brugger, Phys. Rev. Lett. 39 (1977), 215.

    CAS  Google Scholar 

  111. M. B. Dynes, Mat. Res. Bull. 10 (1975), 287.

    Google Scholar 

  112. M. S. Whittingham and F. R. Gamble, Mat. Res. Bull. 10 (1975), 363.

    CAS  Google Scholar 

  113. W. B. Clark and P. M. Williams, Phil. Mag. 35 (1977), 883.

    CAS  Google Scholar 

  114. A. R. Beal and W. Y. Liang, Phil. Mag. 27 (1973), 1397.

    CAS  Google Scholar 

  115. R. E. Schwall, G. R. Stewart and T. H. Geballe, J. Low. Temp. Phys. 22 (1976), 557.

    CAS  Google Scholar 

  116. S. F. Meyer, R. E. Howard, G. R. Stewart, J. V. Acrivos and T. H. Gaballe, J. Chem. Phys. 62 (1975), 4411.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Electrical Engineering and Computer Science and Center for Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts, 02139, USA

    M. S. Dresselhaus

  2. Francis Bitter National Magnet Laboratory, Massachusetts Institute of Technology, Cambridge, Massachusetts, 02139, USA

    G. Dresselhaus

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  1. M. S. Dresselhaus
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  1. Laboratoire de Physique Appliquée, EPF, Lausanne, Switzerland

    F. Lévy

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Dresselhaus, M.S., Dresselhaus, G. (1979). Lattice Mode Structure of Graphite Intercalation Compounds. In: Lévy, F. (eds) Intercalated Layered Materials. Physics and Chemistry of Materials with Layered Structures, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9415-7_8

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