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Alkali Metal Intercalation Compounds of Transition Metal Chalcogenides: TX2, TX3 and TX4 Chalcogenides

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Intercalated Layered Materials

Part of the book series: Physics and Chemistry of Materials with Layered Structures ((PCMA,volume 6))

Abstract

The occurrence of alkali metal intercalated compounds from layered chalcogenides with two dimensional structures was reported for the first time in 1965 by Rüdorff [1]. Rapidly this field of research proved very fruitful. A first exhaustive study in the more general framework of ternary chalcogenides with alkali and transition metals has been given in this series (Vol. 2) by W. Bronger. These last few years, numerous new results were reported in the chemical field, at the same time as physical studies were expanding. Also the synthesis of pseudo one-dimensional chalcogenides leads to new prospects, these compounds being capable of intercalation.

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References

  1. W. Rüdorff, Chimia 19 (1965), 489.

    Google Scholar 

  2. J. Cousseau, L. Trichet, J. Rouxel, Bull. Soc. Chim. Fr. 3 (1973), 872.

    Google Scholar 

  3. M. Armand in Fast Ion Transport in Solids, W. Van Gool ed., North Holland (1973).

    Google Scholar 

  4. M. B. Dines, Mat. Res. Bull. 10 (1975), 287 and US Pat. 3 933 688.

    CAS  Google Scholar 

  5. D. Murphy, F. Di Salvo, G. Hull, J. Waszczak, Inorg. Chem. 15 (1976), 17.

    CAS  Google Scholar 

  6. R. B. Chianelli, M. B. Dines, Inorg. Chem. 14–10 (1975), 2417.

    Google Scholar 

  7. W. P. F. A. M. Omloo, F. Jellinek, J. Less. Comm. Met. 20, (1970), 121.

    CAS  Google Scholar 

  8. G. A. Wiegers, R. Van der Meer, H. Van Heiningen, H. J. Kloosterboer, A. J. A. Albernik, Mat. Res. Bull. 9 (1974), 1261.

    CAS  Google Scholar 

  9. B. Van Laar, H. M. Rietveld and D. J. W. Ijdo, J. Sol. State Chem. 3 (1971), 590.

    Google Scholar 

  10. G. V. Subba Rao, J. C. Tsang, Mat. Res. Bull. 9 (1974), 921.

    Google Scholar 

  11. D. W. Murphy, F. Di Salvo, G. Hull, J. V. Waszczak, S. Mayer, G. R. Stewart, S. Early, J. V. Acrivos, T. Geballe, J. Chem. Phys. 62 (1975), 967.

    CAS  Google Scholar 

  12. M. S. Whittingham, J. Electrochem. Soc. 123 (1976), 315 and Chem. Comm. J. Chem. Soc. (1974), 328.

    CAS  Google Scholar 

  13. M. Lazzari, G. Razzini, B. Scrosati, J. Power Sources 1 (1977), 57.

    Google Scholar 

  14. R. Schöllhorn, H. Meyer, Mat. Res. Bull. 9 (1974), 1237.

    Google Scholar 

  15. J. O. Besenhard, H. Meyer, R. Schöllhorn, Z. Naturforsch. 31b (1976), 907.

    Google Scholar 

  16. D. A. Winn, J. M. Shemilt, B. C. H. Steele, Mat. Res. Bull. 11 (1976), 559.

    CAS  Google Scholar 

  17. R. Schöllhorn, A. Lerf, J. Less. Comm. Metal 42 (1975), 89.

    Google Scholar 

  18. R. Schöllhorn, A. Weiss, Z. Natur forsch. 28b (1973), 71 1.

    Google Scholar 

  19. M. Danot, J. Rouxel, L. Trichet, unpublished work.

    Google Scholar 

  20. P. Molinie, C. Berthier, to be published.

    Google Scholar 

  21. M. Danot, A. Le Blanc, J. Rouxel, Bull. Soc. Chim. Fr. 8 (1969), 2670.

    Google Scholar 

  22. J. Rouxel, M. Danot, J. Bichon, Bull. Soc. Chim. Fr. 11 (1971), 3930.

    Google Scholar 

  23. J. Bichon, M. Danot, J. Rouxel, Compt. Rend. Acad. Sci.: 276 (1973), 1283.

    CAS  Google Scholar 

  24. A. Le Blanc, M. Danot, L. Trichet, J. Rouxel, Mat. Res. Bull. 9 (1974), 191.

    Google Scholar 

  25. J. Rouxel, J. Cousseau, L. Trichet, Compt. Rend. Acad. Sci. 273, (1971), 243.

    CAS  Google Scholar 

  26. B. Van Laar, D. J. W. Ijdo, J. Sol. State Chem. 3 (1971), 590.

    Google Scholar 

  27. M. S. Whittingham, F. Gamble Jr., Mat. Res. Bull. 10 (1975), 363.

    CAS  Google Scholar 

  28. H. E. Barz, A. S. Cooper, E. Corenzwit, M. Marezio, B. T. Matthias, P. H. Schmidt, Science 175 (1972), 884.

    CAS  Google Scholar 

  29. A. H. Thompson, F. R. Gamble and C. R. Symon, to be published.

    Google Scholar 

  30. R. Brec, G. Ouvrard and J. Rouxel, Rev. Chim. Min. 13 (1976), 348.

    CAS  Google Scholar 

  31. P. Palvadeau, P. Molinie, L. Guemas-Brisseau and J. Rouxel, to be published.

    Google Scholar 

  32. J. W. Boon and C. H. Mac Gillavry, Rec. Trav. Chim. Pays-Bas 61 (1942), 910.

    CAS  Google Scholar 

  33. M. Sergent and J. Prigent, Compt. Rend. Acad. Sci. 261 (1965), 5135.

    CAS  Google Scholar 

  34. P. F. Bongers, C. F. Van Brüggen, J. Koopstra, W. P. F. A. M. Omloo, G. A. Wiegers and F. Jellinek, J. Phys. Chem. Solids 29 (1968), 977.

    CAS  Google Scholar 

  35. R. B. Somoano, V. Hadek and A. Rembaum, J. Chem. Phys. 58 (1973), 697.

    CAS  Google Scholar 

  36. A. Le Blanc, Thesis, Nantes 1975.

    Google Scholar 

  37. R. Brec, J. Ritsma, G. Ouvrard and J. Rouxel, Inorg. chem. (in press).

    Google Scholar 

  38. A. Le Blanc and J. Rouxel, Compt. Rend. Acad. Acad. Sci. 279 (1974), 303.

    Google Scholar 

  39. R. B. Somoano, V. Hadek, A. Rembaum, S. Samson, J. A. Woollam, J. Chem. Phys. 62 (1975), 1068.

    CAS  Google Scholar 

  40. O. Berkooz and E. Hermon, Mat. Res. Bull. 5 (1970), 173.

    CAS  Google Scholar 

  41. F. Jellinek, Mat. Res. Bull. 6 (1971), 169.

    CAS  Google Scholar 

  42. G. V. Subba Rao, M. W. Shafer and L. J. Tao, Mat. Res. Bull. 8 (1973), 1231.

    Google Scholar 

  43. G. V. Subba Rao, M. W. Shafer and L. J. Tao, AIP Conf Proc. 10 (1973), 1173.

    Google Scholar 

  44. H. Sabrowsky and Chr. Platte, V Int. Conf. on Solid Compounds of Trans. Elements, Uppsala 1976.

    Google Scholar 

  45. A. E. Van Arkel and C. Crevecoeur, J. Less. Common Metals, 5 (1963), 177.

    CAS  Google Scholar 

  46. K. Koerts, Act. Cryst. 16 (1963), 432.

    CAS  Google Scholar 

  47. J. M. van den Berg and C. W. F. Kort, J. Less. Common Metals 13 (1967), 363.

    Google Scholar 

  48. H. Hahn and B. Harder, Z. Anorg. Allgem. Chem. 288 (1956), 257.

    CAS  Google Scholar 

  49. L. Trichet and J. Rouxel, Compt. Rend. Acad. Sci. 267 (1968), 1322;

    CAS  Google Scholar 

  50. N. Le Nagard, G. Collin and O. Gorochov, Mat. Res. Bull. 10 (1975), 1279;

    Google Scholar 

  51. C. Moreau, M. Spiesser and J. Rouxel, Compt. Rend. Acad. Sci. 280 (1975), 1203.

    CAS  Google Scholar 

  52. N. Le Nagard, G. Collin and O. Gorochov, Mat. Res. Bull. 10 (1975), 1287.

    Google Scholar 

  53. M. S. Whittingham, Belg. Pat. 819 672 (1973).

    Google Scholar 

  54. M. S. Whittingham, Science 192 (1976), 1126.

    CAS  Google Scholar 

  55. L. Trichet and J. Rouxel, Anvar CNRS Pat. 76 04598.

    Google Scholar 

  56. L. Trichet and J. Rouxel, Mat. Res. Bull. 12 (1977); 345.

    CAS  Google Scholar 

  57. C. Delmas, C. Fouassierand P. Hagenmuller, J. Sol. State. Chem. 13 (1975), 165.

    CAS  Google Scholar 

  58. J. Rouxel, J. Sol. State Chem. 17 (1976), 223.

    CAS  Google Scholar 

  59. R. Huisman, R. De Jonge, C. Haas and F. Jellinek, J. Solid State Chem. 3 56 (1971).

    CAS  Google Scholar 

  60. F. R. Gamble, J. Solid State Chem. 9 (1974), 358.

    CAS  Google Scholar 

  61. A. Madhukar, Solid State Comm. 16 (1975), 383.

    CAS  Google Scholar 

  62. L. Trichet, personal communication.

    Google Scholar 

  63. M. Danot and J. Rouxel, Compt. Rend. Acad. Sci. 271 (1970), 998.

    CAS  Google Scholar 

  64. B. G. Silbernagel, Solid State Comm. 17 (1975), 361.

    CAS  Google Scholar 

  65. B. G. Silbernagel and M. S. Whittingham, J. Chem. Phys. 64, (1976), 3670.

    CAS  Google Scholar 

  66. C. Berthier, L. Trichet and J. Rouxel, to be published.

    Google Scholar 

  67. B. G. Silbernagel and M. S. Whittingham, Mat. Res. Bull. 11 (1976), 29.

    CAS  Google Scholar 

  68. L. Trichet, Thesis Nantes 1973.

    Google Scholar 

  69. L. Trichet, D. Jerome and J. Rouxel, Compt. Rend. Acad. Sci. 280C (1975), 1025.

    CAS  Google Scholar 

  70. J. P. Boilot, L. Zuppiroli, G. Delplanque and D. Jerome, Phil. Mag. 32 (1975), 343.

    CAS  Google Scholar 

  71. G. Bonera, F. Borsa, M. L. Grippa and A. Rigamonti, Phys. Rev. 134 (1971), 52.

    Google Scholar 

  72. P. M. Williams in Physics and Chemistry of Materials with layer structures (Vol. 2 ), p. 51, (1976).

    Google Scholar 

  73. J. P. Boilot, Thesis Paris 1975.

    Google Scholar 

  74. R. Schollhorn and A. Lerf, Z. Naturforsch. 29b (1974), 804.

    Google Scholar 

  75. R. Schollhorn and W. Schmucker, Z. Naturfosch. 30b (1975), 975.

    Google Scholar 

  76. R. Schollhorn, E. Sick and A. Lerf, Mat. Res. Bull. 10 (1975), 1005.

    Google Scholar 

  77. A. Le Blanc, M. Danot and J. Rouxel, Bull. Soc. Chim. Fr. 1 (1969), 87.

    Google Scholar 

  78. F. R. Gamble, J. H. Osiecki, M. Cais, R. Pisharody, F. J. Di Salvo, and T. H. Geballe, Science 174 (1971), 493.

    CAS  Google Scholar 

  79. G. V. Subba Rao, M. W. Shafer and J. C. Tsang, J. Phys. Chem. 79-6 (1975), 553.

    Google Scholar 

  80. R. Schollhorn and A. Weiss, J. Less Common Metals 36 (1974), 229.

    Google Scholar 

  81. M. S. Whittingham, Mat. Res. Bull. 9 (1974), 1681.

    CAS  Google Scholar 

  82. L. Trichet and J. Rouxel, unpublished work.

    Google Scholar 

  83. R. Chianelli, J. C. Scanlon, M. S. Whittinghan and F. R. Gamble, Inorg. Chem. 14-7, (1975), 1691.

    Google Scholar 

  84. F. R. Gamble and B. Sibernagel, J. Chem. Phys. 63.6 (1975), 2544.

    Google Scholar 

  85. B. G. Silbernagel and F. R. Gamble, J. Chem. Phys. 65.5 (1976), 1914.

    Google Scholar 

  86. J. V. Acrivos, C. Delios, N. Y. Topse and J. R. Salem, J. Phys. Chem. 79-26 (1975) 3003.

    Google Scholar 

  87. S. F. Meyer, R. E. Howard, G. R. Stewart, J. V. Acrivos, T. H. Geballe, J. Chem. Phys. 62-11 (1975), 4411.

    Google Scholar 

  88. R. R. Chianelli, J. C. Scanlon, M. S. Whittingham and F. R. Gamble, Inorg. Chem. 14-7 (1965), 1691.

    Google Scholar 

  89. S. F. Meyer, J. V. Acrivos and T. H. Geballe, Proc. Nat. Acad. Sci. U.S.A. 72, 2 (1975), 464.

    Google Scholar 

  90. Handbook of Chemistry and Physics, Chemical Rubber Co., 45th edition (1965).

    Google Scholar 

  91. R. Schollhorn and A. Weiss, Z. Naturforsch. B27 (1972), 1273.

    Google Scholar 

  92. B. G. Silbernagel, M. B. Dines, F. R. Gamble, L. A. Gebhard and M. S. Whittingham, J. Chem. Phys. 65 (1976), 1906.

    CAS  Google Scholar 

  93. J. V. Acrivos and J. R. Salem, Phil. Mag. 39-3 (1974), 603.

    Google Scholar 

  94. R. B. Somoano and A. Rembaum, Phys. Rev. Lett. 27 (1971), 402.

    CAS  Google Scholar 

  95. G. V. Subba Rao, M. W. Shafer, S. Kawarazaki and A. M. Toxen, J. Solid State Chem. 9 (1974), 323.

    Google Scholar 

  96. J. C. Phillips, Phys. Rev. Letters, 28 (1972), 1196.

    CAS  Google Scholar 

  97. H. E. Barz, A. S. Cooper, E. Corenzwit, M. Marezzio, B. T. Matthias, P. H. Schmidt, Science 175 (1972), 884.

    CAS  Google Scholar 

  98. R. Schöllhorn, A. Lerf and F. Sernetz, Z. Natur forsch, 29b (1974), 810.

    Google Scholar 

  99. F. Sernetz, A. Lerf and R. Schöllhorn, Mat. Res. Bull. 9 (1974), 1597.

    CAS  Google Scholar 

  100. A. M. Hermann, R. Somoano, V. Hadek and A. Rembaum, Solid State Comm. 13 (1973), 1065.

    CAS  Google Scholar 

  101. S. F. Meyer, R. E. Howard, G. R. Stewart, J. V. Acrivos and T. H. Geballe, J. Chem. Phys. 62 (1975), 4411.

    CAS  Google Scholar 

  102. W. Krönert and V. Plieth, Z. Anorg. Allg. Chem. 336 (1965), 207.

    Google Scholar 

  103. F. K. McTaggart and A. D. Wadsley, Aust. J. Chem. 11 (1958), 445.

    CAS  Google Scholar 

  104. S. Furuseth, L. Brattas and A. Kjekshus, Acta Chem. Scand. A29 (1975), 623.

    Google Scholar 

  105. A. Meerschaut and J. Rouxel, J. Less. Common Metals 39 (1975), 197.

    CAS  Google Scholar 

  106. H Hahn and B. Harder, Z. Anorg. Allg. Chem. 288 (1956), 241;

    CAS  Google Scholar 

  107. H. Hahn and P. Ness, Z. Anorg. Allg. Chem. 302(1959), 136:

    CAS  Google Scholar 

  108. F. Jellinek, Ark. Kemi. 20 (1963), 447.

    CAS  Google Scholar 

  109. F. Kadijk, Thesis Groningen 1969.

    Google Scholar 

  110. E. Bjerkelund and A. Kjekshus, Z. Anorg. Allg. Chem. 328 (1964), 236.

    Google Scholar 

  111. K. Seite, E. Bjerkelund and A. Kjekshus, J. Less. Common Metals 11 (1966), 14.

    Google Scholar 

  112. E. Bjerkelund, J. H. Fermor and A. Kjekshus, Acta Chem. Scand. 20 (1966), 1836.

    CAS  Google Scholar 

  113. F. Jellinek, G. Brauer and H. Müller, Nature 185 (1960), 376.

    CAS  Google Scholar 

  114. H. Haraldsen, Acta Chem. Scand, 17 (1963), 1290.

    Google Scholar 

  115. Int. Tables for Cryst., Kynock Press (1962) vol. Ill, p. 281.

    Google Scholar 

  116. F. Jellinek, R. A. Pollack and M. W. Shafer, Mat. Res. Bull. 9 (1974), 845.

    CAS  Google Scholar 

  117. A. D. Yoffee, Chem. Soc. Rev. 5–1 (1976).

    Google Scholar 

  118. J. A. Wilson, F. J. Di Salvo, S. Mahajan, Adv. Phys. 24–2 (1975), 117.

    Google Scholar 

  119. P. M. Williams, This series, Vol. 2, p. 51.

    Google Scholar 

  120. P. Haen, P. Monceau, B. Tissier, G. Waysand, A. Meerschaut, P. Molinié and J. Rouxel, Proc. Low Temp. Conf. L. T. 14, 5 (1975), 445.

    CAS  Google Scholar 

  121. J. Chaussy, P. Haen, J. C. Lasjaunias, P. Monceau, G. Waysand, A. Waintal, A. Meerschaut, P. Molinié and J. Rouxel, Sol. State Comm. 20 (1976), 759.

    CAS  Google Scholar 

  122. H. G. Schuster in Lecture Notes in Physics, Vol. 34, One dimensional conductors, Springer, Berlin, 1975.

    Google Scholar 

  123. V. V. Walatka, M. M. Labes and J. H. Perlstein, Phys. Rev. Lett. 31 (1973), 1139.

    CAS  Google Scholar 

  124. F. J. Di Salvo, B. G. Bagley, J. M. Voorhoeve and J. V. Waszczak, J. Phys. Chem. Solids 34 (1973), 1357.

    Google Scholar 

  125. R. Delaplace, P. Molinié and D. Jerome, J. Phys. Lett. 37 (1976), L 13.

    Google Scholar 

  126. C. Berthier, P. Molinié and D. Jerome, Solid State Comm. 18 (1976), 1393.

    CAS  Google Scholar 

  127. P. Monceau, N. P. Ong, A. M. Portis, A. Meerschaut and J. Rouxel, Phys. Rev. Lett. 37-10 (1976), 602.

    Google Scholar 

  128. R. R. Chianelli and M. B. Dines, Inorg. Chem. 14–10 (1975), 2417.

    Google Scholar 

  129. D. W. Murphy and F. A. Trumbore, J. Electrochem. Soc. 123–7 (1976), 960 and 124–3 (1977), 325.

    Google Scholar 

  130. A. Meerschaut, Thesis Nantes 1977.

    Google Scholar 

  131. C. Perrin, A. Perrin and J. Prigent, Bull. Soc. Chim. Fr. 8 (1972), 3086.

    Google Scholar 

  132. F. Hulliger, Structure and Bonding 4 (1968), 125.

    Google Scholar 

  133. R. Allmann, I. Baumann, A. Kutogler, Naturwiss. 51, 11 (1964), 263.

    CAS  Google Scholar 

  134. K. Seite and A. Kjekshus, Acta Chem. Scand. 18 (1964), 690.

    Google Scholar 

  135. P. Molinié, Thesis Nantes 1977.

    Google Scholar 

  136. K. Seite, A. Kjekshus, Acta Chem. Scand. 19 (1965), 1002.

    CAS  Google Scholar 

  137. L. Guémas, A. Meerschaut, P. Palvadeau, Compt. Rend. Acad. Sci. 396 (1975), 197.

    Google Scholar 

  138. A. Meerschaut, P. Palvadeau and J. Rouxel, J. Solid State Chem. 20 (1977), 21.

    CAS  Google Scholar 

  139. L. Guémas-Brisseau, P. Palvadeau and J. Rouxel, to be published.

    Google Scholar 

  140. P. Molinié, P. Haen and J. Rouxel, to be published.

    Google Scholar 

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Rouxel, J. (1979). Alkali Metal Intercalation Compounds of Transition Metal Chalcogenides: TX2, TX3 and TX4 Chalcogenides. In: Lévy, F. (eds) Intercalated Layered Materials. Physics and Chemistry of Materials with Layered Structures, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9415-7_4

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