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On the Intercalation Reaction

  • Chapter
Intercalated Layered Materials

Part of the book series: Physics and Chemistry of Materials with Layered Structures ((PCMA,volume 6))

Abstract

The insertion of adducts (I) in between the layers of pseudo-two-dimensional (2D) solids is called intercalation and the purpose of this chapter is to review recent work which has led to a better understanding of the following selected topics:

  1. 1.1.1

    the chemical process of intercalation in transition element dichalcogenides TX2, i.e. the reaction:

    $$T{X_2}(c) + xI = {I_x}.T{X_2}(c)$$
    ((1))

    and

  2. 1.1.2

    the physicochemical properties of the complex formed in (1). The work will be concerned mostly with cases where both TX2 and the intercalated product in (1) are solids and the changes in the direct and reciprocal lattice will form the basis for the discussion of experimental observations. Typical changes in TaS2 phases are shown in Figure 1 and the notation used normally is described in Figure 2.

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Authors and Affiliations

  1. Cavendish Laboratory, Cambridge, England

    Mrs. J. V. Acrivos

  2. San José University, Ca, 95192, USA

    Mrs. J. V. Acrivos

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  1. Laboratoire de Physique Appliquée, EPF, Lausanne, Switzerland

    F. Lévy

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Acrivos, J.V. (1979). On the Intercalation Reaction. In: Lévy, F. (eds) Intercalated Layered Materials. Physics and Chemistry of Materials with Layered Structures, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9415-7_2

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