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Applications of EPR to Surface Chemistry : Study, Classification and Uses of Adsorbed Species

  • Conference paper
Magnetic Resonance in Colloid and Interface Science

Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 61))

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Abstract

After a brief survey of the important events in the field of EPR applied to the study of adsorbed species and of the adsorption processes, the general features of adsorbed species are outlined : energy, distinction between adsorbed and bulk species and between physically and chemically adsorbed species, types, origin and formation of adsorbed species. A classification of the hitherto known adsorbed species is proposed which is based on their relation to adsorption processes and thus on the type of surface to adsorbed species bond : class A (physisorption) and class B (chimisorption). The latter class is divided further into two subclasses : one corresponds to species observed by EPR directly after adsorption, the other to species observed only after a secondary process (reaction or subsequent adsorption). After examples showing what information the EPR technique can give on adsorbed species (identification, structure, surface to adsorbed species bond, mobility), a review is given on the uses of adsorbed species to investigate various properties of the solid onto which they are adsorbed.

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References

  1. Y.K. Zavoisky, J. Phys. USSR, 9, 245, 1945

    Google Scholar 

  2. D.E. O’Reilly, Adv. Catalysis, 12, 31, 1960

    Article  Google Scholar 

  3. V.B. Kazansky, G.B. Pariisky and V.V. Voedvosky, Kin.i Kat., 1, 539, 1960

    Google Scholar 

  4. V.B. Kazansky, G.B. Pariisky and V.V. Voedvosky, Discuss. Faraday Soc., 31, 203, 1961

    Article  Google Scholar 

  5. J.J. Rooney and R.C. Pink, Proc. Chem. Soc., 70, 1961

    Google Scholar 

  6. D.W. Brouwer, Chem. Ind., 177, 1961

    Google Scholar 

  7. V.B. Kazansky, O.V. Nikitina, G.B. Pariisky and V.F. Kiselev, Dokl. Akad. Nauk SSSR, 151, 369, 1963

    Google Scholar 

  8. R.J. Kokes, Proc. Int. Congr. Catal. 3rd, North Holland, Amsterdam, 1, 484, 1964

    Google Scholar 

  9. A.J. Tench and P.J. Holroyd, Chem. Comm., 471, 1968

    Google Scholar 

  10. J.H. Lunsford, Adv. Catalysis, 22, 265, 1972

    Article  CAS  Google Scholar 

  11. B.D. Flockhart, “Surface and Defect Properties of solids” (Special ist Periodical Report) The Chemical Society, 2, 69, 1973

    CAS  Google Scholar 

  12. M. Che, J. Védrine and C. Naccache, Bull. Soc. Chim. 3307, 1970

    Google Scholar 

  13. G.C. Bond “Principles of Catalysis”, Monographs for Teachers, The Chemical Society, London, 1972

    Google Scholar 

  14. J. Conard, This Congress, 1979

    Google Scholar 

  15. D.J.E. Ingram, “Free Radicals as studied by electron spin resonance” Butterworths, London, 1958

    Google Scholar 

  16. C. Naccache, M. Che and Y. Ben Taarit, Chem. Phys. Letters, 13, 109, 1972

    Article  CAS  Google Scholar 

  17. D. Oliver, M. Richard and M. Che, Chem. Phys. Letters, 60, 77, 1978

    Article  Google Scholar 

  18. M. Che, S. Coluccia and A. Zecchina, J. Chem. Soc., Faraday Trans I, 74, 1324, 1978

    Article  CAS  Google Scholar 

  19. M. Dufaux, M. Che and C. Naccache, J. Chim. Phys., 67, 527, 1970

    CAS  Google Scholar 

  20. M. Che, C. Naccache and B. Imelik, J. Catal., 24, 328, 1972

    Article  CAS  Google Scholar 

  21. Y. Ben Taarit and Mériaudeau, This congress, 1979

    Google Scholar 

  22. A.D. Walsh, J. Chem. Soc., 2266, 1953

    Google Scholar 

  23. J. H. Lunsford and J.P. Jayne, J. Phys. Chem. 69, 2182, 1965

    Article  CAS  Google Scholar 

  24. S.A. Marshall, A.R. Reinberg, R.A. Serway and J.A. Hodges, Mol. Phys., 8, 223, 1964

    Article  Google Scholar 

  25. R.A. Schoonheydt and J.H. Lunsford, J. Phys. Chem. 76, 323, 1972

    Article  CAS  Google Scholar 

  26. P.W. Atkins, A. Horsfield and M.C.R. Symons, J.Chem. Soc., 5220, 1964

    Google Scholar 

  27. N.B. Wong and J.H. Lunsford, J. Chem. Phys., 56, 2664, 1972

    Article  CAS  Google Scholar 

  28. P.W. Atkins, J.A. Brivati, N. Keen, M.C.R. Symons and P.A. Trevalion, J. Chem. Soc., 4785, 1962

    Google Scholar 

  29. J.H. Lunsford, J. Chem. Phys., 46, 4347, 1967

    Article  CAS  Google Scholar 

  30. P.W. Atkins and M.C.R. Symons, J. Chem. Soc., 4794, 1962

    Google Scholar 

  31. W. Kaänzig and M.H. Cohen, Phys. Rev. Letters, 3, 509, 1959

    Article  Google Scholar 

  32. M. Che, C. Naccache and B. Imelik, J. Chim. Phys., 68, 1301, 1968

    Google Scholar 

  33. P.H. Kasaï, J. Chem. Phys., 43, 3322, 1965

    Article  Google Scholar 

  34. R.D. Iyengar, M. Codell, J.S. Karra and J. Turkevich J. Amer. Chem. Soc., 88, 5055, 1966

    Article  CAS  Google Scholar 

  35. R.D. Iyengar and R. Kellerman, Z. Phys. Chem., 64, 345, 1969

    Article  CAS  Google Scholar 

  36. R.D. Iyengar and R. Kellerman, J. Colloid Int. Sc., 35, 424, 1971

    Article  CAS  Google Scholar 

  37. M. Che and C. Naccache, Chem. Phys. Letters, 8, 45, 1971

    Article  CAS  Google Scholar 

  38. J.R. Brailsford and J.R. Morton, J. Chem. Phys. 51, 4794, 1969

    Article  CAS  Google Scholar 

  39. N.B. Wong and J.H. Lunsford, J. Chem. Phys., 55, 3007, 1971

    Article  CAS  Google Scholar 

  40. Y. Ben Taarit and J.H. Lunsford, Chem. Phys. Letters, 19, 348, 1973

    Article  Google Scholar 

  41. A.J. Tench. J. Chem. Soc., Faraday Trans. I, 68, 1181, 1972

    Article  CAS  Google Scholar 

  42. M. Che and A. J. Tench, J. Chem. Phys., 64, 2370, 1976

    Article  CAS  Google Scholar 

  43. C.A. Coulson, Volume Commémoratif Victor Henri, Contributions à I’étude de la Structure moléculaire 1948, p. 15

    Google Scholar 

  44. P. Mériaudeau, J.C. Védrine, Y. Ben Taarit and C. Naccache, J. Chem. Soc., Faraday Trans II, 71, 736, 1975

    Article  Google Scholar 

  45. M. Che and A.J. Tench, Chem. Phys. Letters, 18, 199, 1973

    Article  CAS  Google Scholar 

  46. Y. Ben Taarit and J.H. Lunsford, J. Phys., Chem., 77, 780, 1973

    Article  CAS  Google Scholar 

  47. M. Che, C. Naccache and A.J. Tench, J. Chem. Soc., Faraday Trans I, 70, 263, 1974

    Article  CAS  Google Scholar 

  48. M. Che, B. Shelimov, J.F.J. Kibblewhite and A.J. Tench, Chem. Phys. Letters, 28, 387, 1974

    Article  CAS  Google Scholar 

  49. M. Che, M. Fournier and J.P. Launay, J. Chem. Phys. 71, 1954, 1979

    Article  CAS  Google Scholar 

  50. J.C. Védrine and C. Naccache, J. Phys. Chem., 77, 1606, 1973

    Article  Google Scholar 

  51. Y. Ben Taarit, J.C. Védrine, C. Naccache, Ph. de Montgolfier and P. Mériaudeau, J. Chem. Phys., 67, 2880, 1977

    Article  Google Scholar 

  52. J.H. Lunsford, Catal. Rev., 8, 135, 1973

    Article  CAS  Google Scholar 

  53. M.C.R. Symons, D.R. Brown and J.C. Védrine, Chem. Phys. Letters, 52, 133, 1977

    Article  CAS  Google Scholar 

  54. M. Che, J.C. Mc Ateer and A.J. Tench, Chem. Phys. Letters, 31, 145, 1975

    Article  CAS  Google Scholar 

  55. M. Dufaux, M. Che and C. Naccache, Comptes Rendus (Paris), 268 c, 2255, 1969

    Google Scholar 

  56. C. Naccache, M. Che and Y. Ben Taarit, Chem. Phys. Letters, 13, 109, 1972

    Article  CAS  Google Scholar 

  57. C.C. Chao and J.H. Lunsford, J. Phys. Chem., 76, 1546, 1972

    Article  CAS  Google Scholar 

  58. E.G. Derouane and J.C. Védrine, Ind. Chim. Belge, 38, 375, 1973

    CAS  Google Scholar 

  59. R.B. Clarkson and S. Mc Clellan, J. Phys. Chem., 82, 294, 1978

    Article  CAS  Google Scholar 

  60. R.B. Clarkson and R.G. Kooser, Surf. Sci., 74, 325, 1978

    Article  CAS  Google Scholar 

  61. T. Takaishi, A. Yusa, Y. Ogino and S. Ozawa, Japan J. Appl. Phys., suppl 2, 2, 279, 1974

    Google Scholar 

  62. Y. Ben Taarit and J.H. Lunsford, J. Phys. Chem., 77, 1365, 1973

    Article  Google Scholar 

  63. P. Mériaudeau, Y. Ben Taarit, J.C. Védrine and C. Naccache, J. Chem. Soc., Faraday Trans. II, 73, 76, 1977

    Article  Google Scholar 

  64. K. Toriyama and M. Iwasaki, J. Phys. Chem., 73, 2663, 1969

    Article  CAS  Google Scholar 

  65. K. Toriyama and M. Iwasaki, J. Phys. Chem., 73, 2919, 1969

    Article  CAS  Google Scholar 

  66. V.B. Golubev, Zhur, Fiz Khim., 39, 2606, 1965

    CAS  Google Scholar 

  67. J. Védrine, G. Dalmai and B. Imelik, J. Chim. Phys., 65, 1780, 1968

    Google Scholar 

  68. R.B. Clarkson and J. Turkevich, J. Coll. Interf. Sci., 38, 165, 1972

    Article  CAS  Google Scholar 

  69. B.P. Lemke and D. Haneman, Surf. Sci., 64, 771, 1977

    Article  CAS  Google Scholar 

  70. M. Che and C. Naccache, unpublished results

    Google Scholar 

  71. A.K. Kolosov, V.A. Shvets and V.B. Kazansky, Chem. Phys. Letters, 34, 360, 1975

    Article  CAS  Google Scholar 

  72. D. Olivier, M. Richard and M. Che, unpublished results

    Google Scholar 

  73. A.J. Tench and T. Lawson, Chem. Phys. Letters, 1, 459, 1970

    Article  Google Scholar 

  74. M. Che, A.J. Tench. S. Coluccia and A. Zecchina, J. Chem. Soc. Faraday, Trans I., 72, 1553, 1976

    Article  CAS  Google Scholar 

  75. O.V. Krylov, G.B. Pariiski and K.N. Spiridonov, J. Catal., 23, 301, 1971

    Article  CAS  Google Scholar 

  76. V.A. Khalif, B.V. Rozentuller, A.M. Frolov, E.L. Aptekar, K.N. Spiridonov and O.V. Krylov, Kin. i Katal., 19, 1231, 1978

    CAS  Google Scholar 

  77. J.H. Lunsford, J. Phys. Chem. 72, 4163, 1968, J. Catal., 14, 379, 1969

    Article  CAS  Google Scholar 

  78. M.I. Loktev and A.A. Slinkin, Russ. Chem. Rev., 45 807, 1976

    Article  Google Scholar 

  79. M. Che, J.F. Dutel, P. Gallezot and M. Primet, J. Phys. Chem., 80, 21, 1976

    Article  Google Scholar 

  80. P. Gallezot, Y. Ben Taarit and B. Imelik, J. Catal., 26, 481, 1972

    Article  CAS  Google Scholar 

  81. M. Che, B. Shelimov, J.F.J. Kibblewhite and A.J. Tench, Chem. Phys. Letters, 28, 387, 1974

    Article  CAS  Google Scholar 

  82. B.N. Shelimov and M. Che, J. Catal., 51, 143, 1978

    Article  CAS  Google Scholar 

  83. C. Naccache and M. Che, Catalysis, J.W. Hightower, Ed., North Holland Amsterdam, 1973, p. 1389

    Google Scholar 

  84. K.I. Aika and J.H. Lunsford, J. Phys. Chem., 81, 1393, 1977

    Article  CAS  Google Scholar 

  85. K.I. Aika and J.H. Lunsford, J. Phys. Chem., 82, 1794, 1978

    Article  CAS  Google Scholar 

  86. Z. Dudzik and Z.M. George, J. Catal., in the press

    Google Scholar 

  87. D. Olivier, C. Marachi and M. Che, J. Chem. Phys., in the press

    Google Scholar 

  88. D. Olivier, C. Marachi and M. Che, J. Chem. Phys., 71, 000, 1979, in the press

    Article  CAS  Google Scholar 

  89. N. Sistovaris, W.O. Riede and H. Sillescu, Ber. Buns. Phys. Chem., 79, 882, 1975

    CAS  Google Scholar 

  90. H. Hommel, L. Facchini, A.P. Legrand and J. Lecourtier, Eur. Polym. J., in the press

    Google Scholar 

  91. J.L. Garnett and A.T.T. Oei, Proceed.Int. Symp. on surface area determination, D.H. Everett and R.H. Ottewill ed., Butterworths, London, 1970, p. 177

    Google Scholar 

  92. Tseng and S. Chang, Nature, 248, 575, 1974

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Laboratoire de Chimie des Solides, ER 133, CNRS, Université P. et M. Curie, 4,Place Jussieu, 75230, Paris Cedex 05, France

    M. Che

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  1. M. Che
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Editor information

Editors and Affiliations

  1. Laboratoire de Chimie des Surfaces, Université Pierre et Marie Curie, Paris, France

    Jacques P. Fraissard

  2. Naval Research Laboratory, Washington, D.C., USA

    Henry A. Resing

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© 1980 D. Reidel Publishing Company

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Che, M. (1980). Applications of EPR to Surface Chemistry : Study, Classification and Uses of Adsorbed Species. In: Fraissard, J.P., Resing, H.A. (eds) Magnetic Resonance in Colloid and Interface Science. NATO Advanced Study Institutes Series, vol 61. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9079-1_6

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  • DOI: https://doi.org/10.1007/978-94-009-9079-1_6

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