Abstract
Zerovalent metal carbonyls have often been supported over various inorganic carriers (1 – 10) with the general purpose of obtaining well dispersed transition metal phases over inert or semi inert supports. Molybdenum hexacarbonyl has been the subject of several investigations (8, 9, 11, 12). In particular Mo(CO)6 has been sublimed into faujasite type zeolite with the purpose of obtaining small metal particles embedded within the zeolite cavities. IR, X Rays and thermogravimetric methods were used to investigate the intermediate and final species formed upon decomposition of the zerovalent compound. However although valuable information was obtained (9), neither methods could provide unambiguous evidence as to the oxidation and structural states of various intermediates formed at various stages of the decomposition. We felt that combined EPR and 13C NMR would yield supplementary informations which could not be achieved in previous studies.
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References
Derouane, E.G., B Nagy, J., and Védrine, J.C.: 1977, J. Catal. 46, pp. 434
Parkyns, N.D.: 1964, Proceeding 3rd International Congress Amsterdam, pp. 194.
Anderson, J.R,, and Mainwaring, D.E.: 1974, J. Catal. 35, pp. 162.
Anderson, J.R., Elmes, P.S., Howe, R.F., and Mainwaring, D.E.: 1977, J. Catal. 50, pp. 508.
Anderson, J.R., and Howe, R.F: 1977, Nature (London) 268, pp. 129.
Smith, G.C., Chosnachi, T.P., Dagupta, S.R., Iwatake, K., and Watters, K.L.: 1975, Inorg. Chem. 4, pp. 1419.
Robertson, J., and Webb, G.: 1974, Proc. Roy. Soc. Ser. A 341, pp. 383.
Coudurier, G., Gallezot, P., Praliaud, H., Primet, M., and Imelik, B.: 1976, C.R. Acad. Sci. 282 C, pp. 311.
Gallezot, P., Coudurier, G., Primet, M., and Imelik, B.: 1977, American Chemical Society Symposium Series n° 40, pp. 144.
B Nagy, J., Van Eenoo, M,, and Derouane, E.G.: 1979, J. Catal. 58, pp. 230.
Davie, E.S., Whan, D.A., and Kemball, C: 1972, J. Catal. 24, pp. 272.
Howe, R.F., Davidson, D.E., and Whan, D.A.: 1972, J.C.S Faraday Trans I 68, pp. 2266
Bonardet, J.L., and Fraissard, J.P.: 1975, J. Magn. Reson. 22, pp. 543–548.
Naccache, C., and Ben Taarit, Y.: 1973, J.C.S. Faraday Trans. I 69, pp. 1475.
Ben Taarit, Y.: 1979, Chem. Phys. Lett. 62, pp. 211.
Pople, J.A.: 1964, Mol. Phys. 7, pp, 310.
Todd, L.J., and Wilkinson, J.R.: 1974, J. Organometal. Chem. 77, pp. 1–25.
Johnson, B.F.G.: private communication.
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Taarit, Y.B., Wicker, G., Naccache, C. (1980). An NMR and EPR Investigation of the Interaction of Chromium and Molybdenum Hexacarbonyl with Faujasite Type Y Zeolite. In: Fraissard, J.P., Resing, H.A. (eds) Magnetic Resonance in Colloid and Interface Science. NATO Advanced Study Institutes Series, vol 61. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9079-1_44
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DOI: https://doi.org/10.1007/978-94-009-9079-1_44
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