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Magnetic Resonance in Colloid and Interface Science pp 461–466Cite as

Electron Acceptor and Donor Properties of Oxides, as Investigated by Electron Spin Resonance Spectroscopy

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Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 61))

Abstract

The formation of radicals on the surface of alkaline-earth oxides, Al2O3 and SiO2-Al2O3, has been studied by ESR. The following molecules have been used: nitrobenzene, perylene, anthracene, naphthalene and hexamethylbenzene. The concentration of electrondonor sites increases with increasing Lewis base-strength of the oxides. The concentration of electron-acceptor sites increases with increasing Lewis acid-strength.

The nature of electron donor-acceptor sites and the relation between these and Lewis base-acid sites is discussed.

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References

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Author information

Authors and Affiliations

  1. Centro di Studio del CNR su “Struttura ed Attività Catalitica di Sistemi di Ossidi” (SACSO), Istituto di Chimica Generale ed Inorganica, Università di Roma, Roma, Italy

    D. Cordischi, V. Indovina & M. Occhiuzzi

Authors
  1. D. Cordischi
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  2. V. Indovina
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  3. M. Occhiuzzi
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Editor information

Editors and Affiliations

  1. Laboratoire de Chimie des Surfaces, Université Pierre et Marie Curie, Paris, France

    Jacques P. Fraissard

  2. Naval Research Laboratory, Washington, D.C., USA

    Henry A. Resing

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© 1980 D. Reidel Publishing Company

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Cordischi, D., Indovina, V., Occhiuzzi, M. (1980). Electron Acceptor and Donor Properties of Oxides, as Investigated by Electron Spin Resonance Spectroscopy. In: Fraissard, J.P., Resing, H.A. (eds) Magnetic Resonance in Colloid and Interface Science. NATO Advanced Study Institutes Series, vol 61. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9079-1_37

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  • DOI: https://doi.org/10.1007/978-94-009-9079-1_37

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-9081-4

  • Online ISBN: 978-94-009-9079-1

  • eBook Packages: Springer Book Archive

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