Abstract
Mixed valence chemistry is illustrated by the presentation of the structures of diverse typical compounds. In a phenomenological description of mixed valence compounds the optical spectra of binuclear complexes are discussed in terms of the model proposed by Hush. Examples of systems showing a wide variation in the range of electronic coupling between the metallic centers are presented. The.results of a number of experimental studies of the representative pyrazine bridged ruthenium(II,III) dimer are summarized. Prussian Blue, Fe4[Fe(CN)6]3·xH2O, representing polynuclear crystalline compounds serves as a second characteristic example to demonstrate the close connection between spectroscopic and magnetic properties on one hand and the mixed valence interaction on the other hand.
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Ludi, A. (1980). Descriptive Chemistry of Mixed-Valence Compounds. In: Brown, D.B. (eds) Mixed-Valence Compounds. NATO Advanced Study Institutes Series, vol 58. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9076-0_2
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DOI: https://doi.org/10.1007/978-94-009-9076-0_2
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