Skip to main content

The Effects of Sulfate and Non-Sulfate Particles on Light Scattering at the Mauna Loa Observatory

  • Chapter
  • 122 Accesses

Abstract

The results of a 1 yr sampling program designed to quantify the effects of sulfate and non-sulfate particles on light scattering measurements routinely made at the Mauna Loa Observatory in Hawaii are described. Aerosol sampling with a cascade impactor was conducted at an altitude of 3400 m above sea level near the summit of a large, gently sloping volcano during nocturnal downslope flow, when particles are believed representative of clean, mid-tropospheric background conditions. A microchemical spot test using a transmission electron microscope was applied to quantitatively identify individual sulfuric acid, ammonium sulfate, and non-sulfate particles. Simultaneous measurements of integrated light scattering with a four-wavelength nephelometer were also made.

The results of the study indicate that significant variations in aerosol chemistry and morphology occur at Mauna Loa Observatory over an annual period. Episodes of high particle scattering caused by large non-sulfate particles, presumably soil dust, occur mainly in the spring and are generally associated with strong northwesterly large scale flow. Evidence has been gathered suggesting that dust storms over the Asian continent largely account for the springtime turbidity peak in Hawaii. During other times of the year, the effects of sulfate and non-sulfate particles on light scattering are approximately equal.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Bigg, E. K.: 1977, J. Appl. Meteor. 16, 262.

    Article  CAS  Google Scholar 

  • Bodhaine, B. A.: 1978, ‘The Mauna Loa Four Wavelength Nephelometer: Instrument Details and Three Years of Observations’, Air Resources Laboratories/GMCC, Boulder, Colorado, 39 pp.

    Google Scholar 

  • Bodhaine, B. A. and Pueschel, R. F.: 1972, J. Geophys. Res. 77, 5106.

    Article  CAS  Google Scholar 

  • Bodhaine, B. A., Harris, J. M., Herbert, G. A., and Komhyr, W. D.: 1980, J. Geophys. Res. 85, 1600.

    Article  Google Scholar 

  • Bodhaine, B. A., Mendonca, B. G., Harris, J. M., and Miller, J. M.: 1981, J. Geophys. Res. 86, 7395.

    Article  CAS  Google Scholar 

  • Butcher, S. S. and Charlson, R. J.: 1972, An Introduction to Air Chemistry, Academic Press, New York, 241 pp.

    Google Scholar 

  • Darzi, M. and Winchester, J. W.: 1981, J. Geophys. Res. (submitted).

    Google Scholar 

  • Dittenhoefer, A. C. and de Pena, R. G.: 1980, J. Geophys. Res. 85, 4499.

    Article  CAS  Google Scholar 

  • Duce, R. A., Unni, C. K., Ray, B. J., Prospero, J. M., and Merrill, J. T.: 1980, Science 209, 1522.

    Article  CAS  Google Scholar 

  • Friedlander, S. K.: 1977, Smoke, Dust and Haze, John Wiley and Sons, New York, 317 pp.

    Google Scholar 

  • Hanson, K. J. (ed.): 1977, Geophysical Monitoring for Climatic Change No. 5, Summary Report 1976, NOAA/ERL, Boulder, Colorado, 110 pp.

    Google Scholar 

  • Hansen, E. B., Caniparoli, D. G., and Charlson, R. J.: 1979, ‘Aerosol Light-Scattering Characteristics at Mauna Loa Observatory’, presented at the WMO Technical Conference on Regional and Global Observation of Atmospheric Pollution Relative to Climate, 20–24 August 1979, Boulder, Colorado.

    Google Scholar 

  • Heffter, J. L., Taylor, A. D., and Ferber, G. J.: 1975, ‘A Regional-Continental Scale Transport, Diffusion, and Deposition Model’. NOAA Tech. Memo. ERL ARL-50, Silver Spring, MD, 29 pp.

    Google Scholar 

  • Macdonald, G. A. and Katsura, T.: 1964, J. Petrol. 5, 82.

    CAS  Google Scholar 

  • Mamane, Y. and de Pena, R.: 1978, Atmos. Environ. 12, 69.

    Article  CAS  Google Scholar 

  • Mason, B.: 1966, Principles of Geochemistry, 3rd ed., Wiley, New York.

    Google Scholar 

  • Mendonca, B. G. and Pueschel, R. F.: 1973, J. App. Meteor. 12, 156.

    Article  Google Scholar 

  • Mendonca, B. G., Hanson, K. J., and De Luisi, J. J.: 1978, Science 202, 513.

    Article  CAS  Google Scholar 

  • Mendonca, B. G., De Luisi, J. J., Hanson, K. J., and Peterson, J. T.: 1979, ‘Signatures in Atmospheric Transmission Variations at Mauna Loa Observatory, Hawaii’, presented at the WMO Technical Conference on Regional and Global Observation of Atmospheric Pollution Relative to Climate, 20–24 August 1979, Boulder, Colorado.

    Google Scholar 

  • Miller, J. M.: 1981, ‘A Five-Year Climatology of Back Trajectories from the Mauna Loa Observatory, Hawaii’, Atmos. Environ. 15, 1553.

    Article  Google Scholar 

  • Pueschel, R. F., Bodhaine, B. A., and Mendonca, B. G.: 1973, J. Appl. Meteor. 12, 308.

    Article  CAS  Google Scholar 

  • Shaw, G. E., Reagan, J. A., and Herman, B. M.: 1973, J. Appl. Meteor. 12, 374.

    Article  Google Scholar 

  • Shaw, G. E.: 1980, J. Appl. Meteor. 19, 1254.

    Article  Google Scholar 

  • Simpson, H. J.: 1972, J. Geophys. Res. 77, 5266.

    Article  CAS  Google Scholar 

  • Woodward, A. P., Jensen, B., Leslie, A. C. D., Nelson, J. W., Winchester, J. W., Ferek, R. J., and Van Espen, P.: 1977, ‘Aerosol Characterization by Impactors and Streaker Sampling and PIXE Analysis’, Proceedings of Symposium. Recent Advances in Air Pollutant Analysis, American Institute of Chemical Engineers, New York.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

H. C. Martin

Rights and permissions

Reprints and permissions

Copyright information

© 1982 D. Reidel Publishing Company, Dordrecht, Holland

About this chapter

Cite this chapter

Dittenhoefer, A.C. (1982). The Effects of Sulfate and Non-Sulfate Particles on Light Scattering at the Mauna Loa Observatory. In: Martin, H.C. (eds) Long-Range Transport of Airborne Pollutants. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7966-6_8

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-7966-6_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-7968-0

  • Online ISBN: 978-94-009-7966-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics