Abstract
The prototype, cubic autocatalytic reaction (A + 2B → 3B) forms the basis of a simple homogeneous system displaying a rich variety of complex behaviour. Even under well-stirred, isothermal open conditions (the CSTR) we may find multistability, hysteresis, extinction and ignition. Allowing for the finite lifetime of the catalyst (B inert products) adds another dimension. The dependence of the stationary-states on residence-time now yields isolas and mushrooms. Sustained oscillations (stable limit cycles) are also possible. There are strong analogies between this simple system and the exothermic, first-order reaction in a CSTR.
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© 1984 D.Reidel Publishing Company
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Gray, P., Scott, S.K. (1984). Isothermal Autocatalysis in the CSTR: Exotic Stationary-State Patterns (Isolas and Mushrooms)and Sustained Oscillations. In: Nicolis, G., Baras, F. (eds) Chemical Instabilities. NATO ASI Series, vol 120. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7254-4_5
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DOI: https://doi.org/10.1007/978-94-009-7254-4_5
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