Abstract
Large scale motions have been observed at the interface between an aqueous solution of a long chain alkyltrimethyl ammonium halogenide and a nitrobenzene solution of picric acid in proportions far removed from the equilibrium partition state. These motions differ from the usual Marangoni effect because the desorption of the surface active material, required for sustained movements, depends on a chemical interfacial reaction. Such a reaction coupled to the transfer processes permits an instability to occur without any chemical reactions with complex kinetics.
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Dupeyrat, M., Nakache, E., Vignes-Adler, M. (1984). Chemically Driven Interfacial Instabilities. In: Nicolis, G., Baras, F. (eds) Chemical Instabilities. NATO ASI Series, vol 120. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7254-4_16
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DOI: https://doi.org/10.1007/978-94-009-7254-4_16
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