Abstract
For reproducible analyses and reliable control of polycyclic aromatic hydrocarbons (PAH) and related heterocyclic compounds, the availability of standardised analytical procedures is essential. When national or international regulations are issued or developed, standardised analytical methods are usually mandatory.
In the light of such standardisation requirements, the following aspects are reviewed and discussed:
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— sampling and sample treatment
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— analytical techniques (including screening methods)
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— priority list for PAH/POM analysis.
The capabilities of various analytical methods are reviewed, such as capillary gas chromatography, high pressure liquid chromatography, thin layer chromatography and low temperature luminescence spectrophotometry. A candidate list of high priority PAH/POM compounds, including some representative heterocyclic compounds, which is based on occurrence in environmental emissions, health effects and analytical considerations, is discussed.
Finally, some activities carried out in support of harmonisation and standardisation efforts in PAH/POM analysis are described:
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— preparation and characterisation of high purity compounds which is oriented on priority list for PAH/POM analysis;
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— systematic determination and collection of molecular spectra under standard conditions of a comprehensive range of PAH/POM compounds of environmental significance.
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References
Association of Official Analytical Chemists, Official Methods of Analysis of the AOAC, 12th edition, (1975).
ASTM Annual Book of Standards: Standard Methods of Test for Sampling Stacks for Particulate Matter, D2928-71, Part 23, Am. Soc. Testing Mat., (1973).
ASTM Annual Book of Standards, Part 31, Water, (1975).
British Standard Simplified Methods for Measurement of Grit and Dust Emissions (Metric Units), B.S. 3405: 1971.
P. Brookes, Mutation Research, 39, pp 257–284, (1977).
N.E. Bolton, C.L. Hunt, T.A. Lincoln and W.E. Porter, Occ. Health and Safety, March/April 1977, p 30.
W. Cautreels and K. Van Cauwenberghe, Water Air Soil Pollution, 6, p 103, (1976).
W. Cautreels and K. Van Cauwenberghe, Atmos. Environ., 12, p 1133, (1978).
B.N. Colby, R.G. Beimer, D.R. Rushwick and W.A. Telland, Anal. Chem., in press.
A.L. Colmsjö and C.E. Östman, Anal. Chem., 52, pp 2093–2095, (1980).
A. Dipple, Polynuclear Aromatic Carcinogens. In: “Chemical Carcinogens” (C.E. Searle, ed.) ACS Monograph 173. Am. Chem. Soc. Washington DC, p 245, (1976).
EEC Council Directive 75/440/EEC, O.J. L 194, 25 July, 1975.
EPA: Quality criteria for water, US Fed. Reg. 3 Dec. 1979, pp 69464-69 for Survey of Industrial Effluents for Priority Pollutants Sampling and Analysis Procedures (rev. April 1978).
EPA, EMSL, Method 625: Base/Neutrals, Acids and Pesticides, Cincinnati, Ohio, 1979.
Fed. Reg. 36, No. 247, 24878 (1977).
Fleischverordnung, 4/7/1978, Bundesgesetzblatt I. S.1003.
H.V. Gelboin and P.O.P Ts’o in “Polycyclic Hydrocarbons and Cancer”, Acad. Press, New York, p 110, (1978).
J.A. Glaser, D.L. Foerst, G.D. McKee, S.A. Quave and W.L. Budde, Environmental Scientific Technology, 15, pp 1426–1435, (1981).
C. Golden and E. Sawicki, International J. Environ. Anal. Chem., 4, pp 9–23, (1975).
W.H. Griest, L.B. Yeatts Jr. and J.E. Caton, Anal. Chem. 52, pp 199–201, (1980).
G. Grimmer, A. Hildebrandt, and M. Böhnke, Erdöl, Kohle, Erdgas, Petrochem., 25, pp 442–531, (1972).
G. Grimmer, A. Hildebrandt and H. Böhnke, Zentralbl. Bakterrol. Hyg. Abt. I (Orig. B), 158, pp 35–49, (1973).
G. Grimmer and H. Böhnke, J. Assoc. Off. Anal. Chem., 58, pp 725–733, (1975).
G. Grimmer and H Böhnke, Chromatographia, 9, pp 30–40, (1976).
G. Grimmer, H. Böhnke and A. Glaser, Zbl. Bakt. Hyg., I. Abt. Orig. B 164, p 218, (1977).
G. Grimmer, H. Böhnke and A. Glaser, Erdöl, Kohle, Erdgas und Petrochem., 30, pp 411–417, (1977).
G. Grimmer and P. Voigtsberger, Erdöl und Kohle, Erdgas Petrochem. ver. mit Brennstoffehem. 33, p 226, (1980).
G. Grimmer, J. Jacob, K.W. Naujack, and G. Dettbarn, Fres. Z. Anal. Chem., 309, pp 13–19, (1981).
G. Grimmer, G. Dettbarn and D. Schneider, Z. Wasser Abwasser Forsch 14, Nr. 3, pp 100–106, (1981).
G. Grimmer, J. Jacob, and K.W. Naujack, Fres. Z. Anal. Chem., 306, pp 347–355, (1981).
G. Grimmer, K.W. Naujack and D. Schneider, Fres. Z. Anal. Chem., 311, pp 475–484, (1982).
G. Grimmer, OECD workshop on PAH in air, Paris, October 1981.
P. Hanus, H. Guerrero, R. Biehl and T. Kenner, J. Assoc. Off. Anal. Chem., 62, No. 1, pp 29–35, (1979).
J. Howard, J. Assoc. Off. Anal. Chem., 61, pp 122–129, (1968).
ISO Draft International Standard DIS 78/II (1974) Geneva.
IARC/WHO: Environmental Carcinogens — “Selected Methods of Analysis”, Vol. 3, IARC Publications, No. 29, Lyon, (1979).
IARC: Monograph of carcinogenic risk of the chemical to man, Vol. 3 “Certain polycyclic aromatic hydrocarbons and heterocyclic compounds”, International Agency for Research on Cancer, Lyon, (1973).
O. Janssen, Erdöl, Kohle, Erdgas, 28, pp 624–638, (1975).
L. Joe, Jr., L. Roseboro and T. Fazio, J. Assoc. Off. Anal. Chem., 64, pp 641–646, (1981).
J. Josephson, Environ. Sci. Technology, 15, pp 1408–1412, (1981).
G.A. Junk and C.S. Ford, Chemosphere 9, pp 187–230, (1980).
W. Karcher, A. Nelen, R. Depaus, J. van Eijk, P. Glaude, and J. Jacob in “Polycyclic Aromatic Hydrocarbons Chemical Analysis and Biological Fate” (M. Cooke and A.J. Dennis, eds.) Battelle-Press, Columbus, Ohio, p 317, (1981).
W. Karcher, R.J. Fordham, A. Nelen, R. Depaus, J. Dubois and P. Glaude in “Polynuclear Aromatic Hydrocarbons, Chemical Analysis and Biological Fate” (M. Cooke and A.J. Dennis, eds.) Battelle-Press. Columbus, Ohio, (1982).
W. Karcher, J. Jacob, and L. Haemers, EUR-report 6967, (1980).
W. Karcher, J. Jacob, and R. Fordham, EUR-report 7175 (1981), and EUR-report 7812 (1982).
A.M. Krstulovic, D.M. Rosic and P.R. Brown, Anal. Chem., 48, p 1348, (1976).
R.C. Lao, R.S. Thomas, H. Oja, and L. Dubois, Anal. Chem., 45, p 908, (1973).
C.J. Least, G.F. Johnson and H. M Solomon, Clin. Chem., 22, p 765, (1976).
M.L. Lee, M. Novotny and K.D. Bartle, Anal. Chem., 48, p 1566, (1976).
M.L. Lee, M. Novotny, and K.D. Bartle, “Analytical Chemistry of Polycyclic Aromatic Compounds” Academic Press, New York, p.448, (1981).
W.E. May, J. Brown-Thomas, L.R. Hilpert and S.E. Wide in “Polynuclear Aromatic Hydrocarbons, Chemical Analysis and Biological Fate” (M. Cooke and A.J. Dennis eds.) Battelle Press, Columbus, Ohio, pp 1–16, (1981).
W.E. May, J.M. Brown, S.N. Chester, F. Guenther, L.R. Hilpert, H.S. Hertz and S.A. Wise in ‘Polynuclear Aromatic Hydrocarbons, Chemistry and Biology’, Carcinogenesis and Mutagenesis (P.W. Jones and P. Leber eds.) Ann Arbor Science, pp 411-418, (1979).
F.W. McLafferty, Science, 214, pp 280–287, (1981).
NIOSH Manual of Analytical Methods, HEW Publications, NIOSH, Washington DC, pp 77-157, (1977).
T. Ramdahl, K. Kreseth and G. Becher, J. High Resolution Chromatogr. and Chrom. Comm., 5, pp 19–26, (1982).
D. Rondia, Int. J. Air Water Pollution, 9, pp 113–121, (1965).
E. Sawicki, R.C. Carey, A.E. Dooley, J.B. Giscland, J.L. Monkman, R.E. Neligan and L.A. Ripperton, Health Laboratory Science, 7, p 60, (1970).
I. Schmeltz and D. Hoffmann, Chem. Review, 77, p 295, (1977).
L.M. Shabad, A. Khesina, G.A. Smirnow, N.E. Styopina, W. Prietsch, N. Yaskulla and M. Narmann, Gig. Sanit., 10, pp 50–53, (1976).
M.E. Snook, R.F. Stevenson, H.C. Higman, R.I. Arrendale and O.T. Chortyk, Beitr. Tabakforsch., 8, p 250, (1976).
T.W. Stanley, J.E. Meeker and M.J. Morgan, Environ. Sci. Technol., 1, p 927, (1967).
U. Stenberg, OECD Workshop on PAH, Paris, October 1981.
P.E. Strup, R.D. Giammar, T.R. Stanford and P.W. Jones in “Polynuclear Aromatic Hydrocarbons: Chemistry, Metabolism and Carcinogenesis” (R.I. Freudenthal and P.W. Jones, eds.), Raven Press, New York, p 241, (1976).
K. Tintel, J. Lugtenburg and J. Cornelisse, J. Chem. Soc., Chem. Communications, pp 185-186, (1982).
Umweltbundesamt (ed.): Berichte 1/79. Luftqualitätskriterien für ausgewählte polyzyklische aromatische Kohlenwasserstoffe. Erich Schmidt Verlag, Berlin.
US-clearing House Fed. Science Technol. Inf. PB rep. No. 200266 (G.P. Gross) (1971).
US Fed. Register, Dept. of Labor OSHA, 22 October 1976.
Verordnung über Zulassung von Zusatzstoffen für die Herstellung von Kaugummi, 20/9/1972, Bundesgesetzblatt I, S.1825.
WHO: Working group on Air Standarisation of Sampling and Analytical Procedure for estimation of PNA in the Environment, WHO, Geneva, (1969).
WHO International Standard for drinking water, 3rd edition, WHO, Geneva, (1971).
WHO: Selected Methods of Measuring Air Pollutants, WHO Offset Publication No. 24 (1970).
N. Wilburn, IARC Lyon, Private Communication.
Y. Yang, A.P. D’Silva and V.A. Fassel, Anal. Chem., 53, pp 894–899, (1981).
E. Bayer, K. Albert, M. Nieder, E. Grom, G. Wolff and M. Rindlisbacher, Anal. Chem., 54, pp 1747–1750, (1982).
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Karcher, W. (1983). Standardisation Aspects in PAH/POM Analysis. In: Rondia, D., Cooke, M., Haroz, R.K. (eds) Mobile Source Emissions Including Policyclic Organic Species. NATO ASI Series, vol 112. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7197-4_10
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