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Group V Atom NMR Spectroscopy Other than Nitrogen

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The Multinuclear Approach to NMR Spectroscopy

Part of the book series: NATO ASI Series ((ASIC,volume 103))

Abstract

Primary dependence of nuclear shielding on oxidation state observed throughout the earlier Periodic Groups is not evident in Group V. Symmetry considerations related to the lower oxidation state lone pair do, however, affect the spectroscopies of the quadrupolar 75As and 121Sb. Reversal effects in 75As shielding upon methyl substitution are remarked. The precision of the pairwise additive model for 121Sb shieldings is used to assign cis isomers in the SbClnBr6−n − system.

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Author information

Authors and Affiliations

  1. Faculty of Graduate Studies, The University of Western Ontario, London, Canada

    R. Garth Kidd

Authors
  1. R. Garth Kidd
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Northwestern University, Evanston, Illinois, USA

    Joseph B. Lambert

  2. Department of Chemistry, University of Stirling, Stirling, Scotland

    Frank G. Riddell

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© 1983 D. Reidel Publishing Company

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Kidd, R.G. (1983). Group V Atom NMR Spectroscopy Other than Nitrogen. In: Lambert, J.B., Riddell, F.G. (eds) The Multinuclear Approach to NMR Spectroscopy. NATO ASI Series, vol 103. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7130-1_18

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  • DOI: https://doi.org/10.1007/978-94-009-7130-1_18

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-7132-5

  • Online ISBN: 978-94-009-7130-1

  • eBook Packages: Springer Book Archive

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