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On the Structure of Ion-Exchange Resins

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Mass Transfer and Kinetics of Ion Exchange

Part of the book series: NATO ASI Series ((NSSE,volume 71))

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Abstract

The ideal case of an ion-exchange resin is that of a homogeneous isotropically-swelling gel with a regular distribution of charged functional groups throughout the particle. For convenience, the particle geometry should be spherical, since this requires only one parameter for its definition, and of course each particle should have the same radius. The charged groups should each have a single counterion, and the Donnan membrane effect should permit virtually no invasion of external electrolyte. When considering the exchange of ions in such a system, both the original counterion and the ion for which it exchanges should be of the same size, hydration, and valency, and should have identical diffusion coefficients both in the external solution, and inside the homogeneous gel phase. Again for convenience we should wish the resin to show no preference for one ion rather than the other.

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Author information

Authors and Affiliations

  1. formerly Senior Research Scientist Duolite International, Inc., USA

    John R. Millar

Authors
  1. John R. Millar
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Editor information

Editors and Affiliations

  1. University of Bari, Italy

    Lorenzo Liberti (Senior Researcher at the Water Research Institute of the National Research Council of Italy Associate Professor of Industrial Chemistry at the Faculty of Engineering) (Senior Researcher at the Water Research Institute of the National Research Council of Italy Associate Professor of Industrial Chemistry at the Faculty of Engineering)

  2. Pennsylvania State University, University Park, PA, 16802, USA

    Friedrich G. Helfferich (Professor of Chemical Engineering) (Professor of Chemical Engineering)

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© 1983 Martinus Nijhoff Publishers, The Hague

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Millar, J.R. (1983). On the Structure of Ion-Exchange Resins. In: Liberti, L., Helfferich, F.G. (eds) Mass Transfer and Kinetics of Ion Exchange. NATO ASI Series, vol 71. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6899-8_2

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  • DOI: https://doi.org/10.1007/978-94-009-6899-8_2

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-6901-8

  • Online ISBN: 978-94-009-6899-8

  • eBook Packages: Springer Book Archive

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