Abstract
We previously reported on a semiconductor to metal transition induced upon intercalation in the system LixZrSe2. Considering recent 77Se NMR data, which give evidence of a large interaction between ions and conduction electrons and provide a tool to study short range order of the intercalated ions, we give a new description of this system, taking into account previous 77Se NMR X-rays, EPR and magnetic susceptibility measurements on powder samples. Discrepancy with results of transport measurements by other authors on single crystals intercalated in the same way, as the non observation of PLD/CDW, are also discussed.
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Berthier, C., Chabre, Y., Segransan, P., Deniard, P., Trichet, L., Rouxel, J. (1984). Ion-Electron Interaction and Intercalation Induced Semiconductor to Metal Transition in the Intercalated Dichalcogenide LixZrSe2 . In: Acrivos, J.V., Mott, N.F., Yoffe, A.D. (eds) Physics and Chemistry of Electrons and Ions in Condensed Matter. NATO ASI Series, vol 130. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6440-2_43
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DOI: https://doi.org/10.1007/978-94-009-6440-2_43
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