Abstract
This paper discusses some of the physical and chemical phenomena encountered during intercalation of the layered transition metal dichalcogenides. For convenience three classes of intercalate complexes are distinguished; 1) those formed with nitrogen containing organic molecules, and ammonia and hydrazine, 2) complexes with alkali and alkali earth metals, and 3) complexes with the ā3dā transition metals. Intercalation can cause profound changes in the electronic properties of the host lattice, and these can be understood in terms of charge transfer and increased interlayer separation. The phenomena discussed include optical properties, transport properties, superconductivity, phase changes, staging, magnetic properties, metal insulator transitions, Anderson localisation, and fast ion conduction. Some possible practical applications are also mentioned.
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Yoffe, A.D. (1984). Electronic Properties of Intercalate Complexes of Layer Type Transition Metal Dichalcogenides. In: Acrivos, J.V., Mott, N.F., Yoffe, A.D. (eds) Physics and Chemistry of Electrons and Ions in Condensed Matter. NATO ASI Series, vol 130. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6440-2_37
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DOI: https://doi.org/10.1007/978-94-009-6440-2_37
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