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Micellization

  • Chapter
Surfactant Systems

Abstract

In Chapter 1 the characteristic property of amphiphiles in accumulating at air-water or oil-water interfaces was discussed in terms of the entropy gain caused by disruption of organized water structure and the removal of mobility constraints as the hydrophobic region was removed from an aqueous environment. An alternative to the crowding of the interface as the surfactant concentration is increased is provided by the formation of small aggregates or micelles in the bulk of the solution. The hydrophobic moieties compose the core of the micelle, being shielded from the surrounding solvent by the shell of ionic head groups. There is much experimental evidence to suggest that the mobility of hydrocarbon chains in the micellar interior resembles that in a liquid hydrocarbon. Hence the process of micellization does indeed represent a method by which the hydrocarbon chains may regain their mobility.

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  1. Department of Pharmacy, University of Manchester, UK

    D. Attwood

  2. Department of Pharmacy, University of Strathclyde, UK

    A. T. Florence

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Attwood, D., Florence, A.T. (1983). Micellization. In: Surfactant Systems. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5775-6_3

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