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Spectroscopic and Chemical Investigations of PVC Structure

  • Chapter
Degradation and Stabilisation of PVC

Abstract

The substantial progress achieved during the past two decades in elucidating the molecular structure of PVC owes much to four spectroscopic techniques. At the outset, infrared spectroscopy proved valuable for the characterisation of the configurational and conformational chain isomers present and, more recently, 1H- and 13C-NMR spectroscopy have provided the means for quantitative measurements of tacticity. As there are increasing indications that a knowledge of the configurational and conformational states of PVC chains are important for an understanding of the propagation stage of the degradation process,1–4 the availability of such information is very useful.

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  1. The British Petroleum Company plc, Sunbury-on-Thames, Middlesex, UK

    W. F. Maddams

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  1. Department of Chemistry, University College, Cardiff, Wales, UK

    E. D. Owen

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Maddams, W.F. (1984). Spectroscopic and Chemical Investigations of PVC Structure. In: Owen, E.D. (eds) Degradation and Stabilisation of PVC. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5618-6_4

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