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Models of the Electrical Double Layer

An Overview of the Present Situation

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Trends in Interfacial Electrochemistry

Part of the book series: NATO ASI Series ((ASIC,volume 179))

Abstract

Although attempts to model the electrical double layer are more than a century old there is still no satisfactory explanation for the variety of phenomena observed. In the last few years, as a result of advances in experimental techniques as well as the development of theoretical interest in interphases, there has been an attempt to construct a model of this region based more firmly on molecular concepts. The present paper surveys some of the progress made in this direction towards the solution of seven problems which arise in the consideration of the electrical double layer.

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References

  1. G. Gouy, J. Phys. Chim., 9 (1910) 457.

    CAS  Google Scholar 

  2. D.L. Chapman, Phil. Mag., 25 (1913) 475

    Google Scholar 

  3. P. Debye and E. Mückel, Physikal Z., 24 (1923) 185.

    CAS  Google Scholar 

  4. D.C. Grahame, Chem. Relviews, 41 (1947) 441

    Article  CAS  Google Scholar 

  5. V. Freiser, Z. Elektrochem., 56 (1952) 822

    Google Scholar 

  6. M.J. Sparnaay, Rec. Trav. Chim., 77 (1958) 382

    Google Scholar 

  7. A.L. Loeb — J. Colloid Sci., 6 (1951) 75

    Article  CAS  Google Scholar 

  8. R. Parsons and S. Trasatti, Trans. Faraday Soc., 65 (1969) 3314.

    Article  CAS  Google Scholar 

  9. G.M. Torrie and J.P. Valleau, J. Chem. Phys., 73 (1980) 5807.

    Article  CAS  Google Scholar 

  10. H.D. Hurwitz, A. Sanfeld and A. Steinchen-Sanfeld, Electrochim. Acta, 9 (1964) 929.

    Article  CAS  Google Scholar 

  11. G. Gouy, Ann. Phys., (9) 9 (1917) 129

    Google Scholar 

  12. O. Stern, Z. Elektrochem., 30 (1924) 508

    CAS  Google Scholar 

  13. D. Henderson, L. Blum and M. Lozada-Cassou, J. Electroanal. Chem., 150 (1983) 291.

    Article  CAS  Google Scholar 

  14. D.C. Grahame, J. Electrochem. Soc., 98 (1951) 343

    Article  CAS  Google Scholar 

  15. N.F. Mott, R. Parsons and R.J. Watts-Tobin, Phil. Mag., 7 (1962) 483.

    Article  CAS  Google Scholar 

  16. G. Gouy, Ann. Chem. Phys., (7) 29 (1903) 161.

    Google Scholar 

  17. Z.A. Iofa and A.N. Frumkin, Zhur. Fiz. Khim., 18 (1944) 268.

    CAS  Google Scholar 

  18. D.C. Grahame and R. Parsons, J. Amer. Chem. Soc., 83 (1961) 1291

    Article  CAS  Google Scholar 

  19. R. Parsons and F.G.R. Zobel, J. Electroanal. Chem., 9 (1965) 333.

    Article  CAS  Google Scholar 

  20. J.A. Harrison, J.E.B. Randies and D.J. Schffrin, J. Electroanal. Chem., 25 (1970) 197.

    Article  CAS  Google Scholar 

  21. J.E.B. Randies, Advances in Electrochemistry and Electrochemical Engineering Vol. 3 1963 Ed. P. Delahay and C.W. Tobias, Wiley, New York. p1.

    Google Scholar 

  22. H.H. Girault and D.J. Schiffrin, J. Electroanal. Chem. 150 (1983) 43.

    Article  CAS  Google Scholar 

  23. O.K. Rice, J. Phys. Chem., 30 (1926) 1501.

    Article  CAS  Google Scholar 

  24. R. Parsons, Modern Aspects of Electrochemistry Vol. 1 (1954) Ed. J.O M. Bockris and B.E. Conway, Butterworths, London, p. 103.

    Google Scholar 

  25. N.D. Lang and W. Kohn, Phys. Rev., B 1 (1970) 4555, B 3 (1971) 1215.

    Google Scholar 

  26. J.P. Badiali, M.L. Rosinberg and J. Goodisman, J. Electroanal. Chem., 143 (1983); 150 (1983 25.

    Google Scholar 

  27. A. Kornsyshev, W. Schmickler and M. Vorotyntsev, Phys. Rev. B 25 (1982) 5244.

    Google Scholar 

  28. W. Schmickler, J. Electroanal. Chem., 150 (1983) 19.

    Article  CAS  Google Scholar 

  29. W. Schmickler and D. Henderson, J. Chem, Physics, 80 (1984) 3381.

    Article  CAS  Google Scholar 

  30. J.P.Badiali, M.L.Rosinberg, F. Vericat and L. Blum, J. Electroanal. Chem., 158 (1983) 253.

    Article  CAS  Google Scholar 

  31. J. Lyklema, Trans. Faraday Soc., 59 (1963) 418.

    Article  CAS  Google Scholar 

  32. D.C, Grahame, J. Amer. Chem. Soc., 79 (1957) 2093.

    Article  CAS  Google Scholar 

  33. R.J. Watts-Tobin, Phil. Mag., 6 (1961) 133.

    Article  CAS  Google Scholar 

  34. R. Parsons, Electrochimica Acta, 21 (1976) 681.

    Article  CAS  Google Scholar 

  35. W.R. Fawcett, Israel J. Chesmistry 18 (1979) 3.

    CAS  Google Scholar 

  36. I.L. Cooper and J.A. Harrison, J. Electroanal. Chem., 66 (1975) 85.

    Article  CAS  Google Scholar 

  37. R. Parsons and R.M. Reeves, J. Electroanal. Chem. 123 (1981) 141.

    Article  CAS  Google Scholar 

  38. R. Parsons, R.M. Revees and P.N. Taylor, J. Electroanal. Chem., 50 (1974) 149.

    Article  CAS  Google Scholar 

  39. R. Guidelli, J. Electroanal. Chem., 110 (1980) 205

    Article  CAS  Google Scholar 

  40. A. Hamelin, J. Electroanal. Chem., 138 (1982) 395.

    Article  CAS  Google Scholar 

  41. G. Valette, J. Electroanal. Chem., 122 (1981) 285.

    CAS  Google Scholar 

  42. D.C. Grahame, J. Amer. Chem. Soc., 76 (1954) 4815

    Article  Google Scholar 

  43. D.J. Schiffrin, Trans. Faraday Soc., 67 (1971) 3318.

    Article  CAS  Google Scholar 

  44. G. Valette, J. Electroanal. Chem., 138 (1982) 37.

    Article  CAS  Google Scholar 

  45. R. Parsons and A. Stockton, J. Electroanal. Chem., 25 (1970) App 10.

    Google Scholar 

  46. W.R. Fawcett, J. Electroanal. Chem., 39 (1972) 474.

    Article  CAS  Google Scholar 

  47. A.N. Frumkin, Z. Physikal. Chem., 116 (1925) 46.

    Google Scholar 

  48. D.M. Mohilner, J. Physical Chem., 81 (1977) 244 and Private Communication.

    Article  CAS  Google Scholar 

  49. M.V. Sangaranarayanan and S.K. Rangarajan, Can. J. Chem., 59 (1981) 2072); J. Electroanal. Chem., 176 (1984) 1, 29, 45, 65, 99, 119.

    Article  CAS  Google Scholar 

  50. B.E. Conway, J.G, Matheson and H.P. Dkar, J. Phys. Chem., 78 (1974) 1226.

    Article  CAS  Google Scholar 

  51. J.O’M. Bockris, M.A.V. Devanathan and K. Müller, Proc. Roy. Soc., A 274 (1963) 55.

    Google Scholar 

  52. R. Parsons, J. Electroanal. Chem., 109 (1980) 369.

    Article  CAS  Google Scholar 

  53. L.M. Baugh and R. Parsons, J. Electroanal. Chem., 41 (1973) 311; Croat. Chim. Acta, 45 (1973) 127.

    Article  CAS  Google Scholar 

  54. J. Lipkowski, C. Hinnen, C. Nguyen Van Huong, R. Parsons and J. Chevalet, J. Electroanal. Chem., 143 (1983) 375.

    Article  CAS  Google Scholar 

  55. R. Parsons and J.T, Reilly; J. Electroanal. Chem., 24 (1970) App 23.

    Google Scholar 

  56. R. Peat and S. Shannon, J. Electroanal. Chem., 159 (1983) 229.

    Article  CAS  Google Scholar 

  57. W. Lorenz and G. Salié, Z. Physikal Chem., 218 (1961).259.

    CAS  Google Scholar 

  58. G.C. Barker, Pure Appl. Chem., 15 (1967) 239.

    Article  CAS  Google Scholar 

  59. K.J. Vetter and J.W. Schultze, Ber. Bungsenge, 76 (1972) 920, 927.

    CAS  Google Scholar 

  60. D.M. Kolb, Advances in Electrochemisty and Electrochemical Engineering Ed. H. Gerischer and C.W. Tobias, Vol II (1978) Wiley, New York p. 125.

    Google Scholar 

  61. J.W. Schultze and F.D. Koppitz, Electrochim. Acta, 21 (1976) 327, 337.

    Article  CAS  Google Scholar 

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© 1986 D. Reidel Publishing Company, Dordrecht, Holland

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Parsons, R. (1986). Models of the Electrical Double Layer. In: Silva, A.F. (eds) Trends in Interfacial Electrochemistry. NATO ASI Series, vol 179. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4694-1_14

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  • DOI: https://doi.org/10.1007/978-94-009-4694-1_14

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8587-8

  • Online ISBN: 978-94-009-4694-1

  • eBook Packages: Springer Book Archive

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