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A Model for Fluids in Metamorphosed Ultramafic Rocks: IV. Metasomatic Veins in Metaharzburgites of Cima di Gagnone, Valle Verzasca, Switzerland

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Book cover Chemical Transport in Metasomatic Processes

Part of the book series: NATO ASI Series ((ASIC,volume 218))

Abstract

Most of the over one-hundred known metaperidotite lenses of the high grade metamorphic part of the Central Alps show metasomatic features like concentric zoning and composite veining. These indicate that an important hydrothermal event took place during an early stage of the uplift which followed the pressure peak of the regional metamorphism, at approximately 580–650 deg C and 4–6 kbar. Some of the most conspicuous veins occur in the Cima di Gagnone region in the North-Eastern Verzasca Valley in Switzerland. They are usually no longer than 2 to 5 meters and vary in width from 1 to 50 centimeters. Geometrically two types can be distinguished: The first type starts in the mafic marginal (“black wall”) zone of a lens or in mafic layers cross-cutting a lens. The second one has a tensioncrack shape and begins and ends anywhere in the ultramafic host rock. The veins are usually symmetrically zoned, composed of a central zone with several replacement zones on both sides. Based on their dominant mineral phases, 4 vein types can be distinguished: (A) Mg-amphibole dominated, (B) tremolite- chlorite dominated, (C) chlorite- talc dominated, and (D) talc- carbonate dominated veins. The veins are interpreted to represent the second stage of a hydrothermal metamorphism during which rapid deformation led to brittle behaviour of the ultramafic host rock. Fluid compositions deduced from mineral data with the aid of activity- activity-X( CO2) — diagrams indicate locally steep gradients in CO2, SiO2, iron, calcium and aluminium. A tentative interpretation of the changing mineral compositions as a function of the distance from the vein center indicates a diffusion-dominated mass transfer mechanism. In contrast to more acid rocks, aluminium seems to be easily transported in the high pH- and low fO2-conditions of the fluids present in these ultramafic rocks.

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References

  • Berman, R.G., Engi, M. and Brown, T.H. (1985):Optimisation of standard state properties and activity models for minerals: methodology and application to an eleven component system. 1st Codata symposium, Chem. Thermodyn.Thermophys.Properties,Databases, 165–173.

    Google Scholar 

  • Bowers, T.S. and Helgeson, H.C. (1983): Calculation of the thermodynamic and geochemical consequences of non-ideal mixing in the system H2O-CO2-NaCl on phase relations in geological systems. Metamorphic equilibria at high pressures and temperatures. Amer.Mineralogist 68, 1059–1075.

    Google Scholar 

  • Bowers, T.S., Jackson, K.J. and Helgeson, H.C. (1984): Equilibrium activity diagrams for coexisting minerals and aqueous solutions at pressures and temperatures to 5kb and 600 deg C. Springer, Berlin, 397p.

    Google Scholar 

  • Brady, J.B. (1975a): Reference frames and diffusion coefficients. Amer.J.Sci. 275, 954.

    Article  Google Scholar 

  • Brady, J.B. (1975b): Chemical components and diffusion. Amer.J.Sci. 275, 1073–1088.

    Article  Google Scholar 

  • Brady, J.B. (1977): Metasomatic zones in metamorphic rocks.Geochim. Cosmochim.Acta 41, 113–125.

    Article  Google Scholar 

  • Brady, J.B. (1983): Intergranular diffusion in metamorphic rocks. Amer.J.Sci.283A, 181–200.

    Google Scholar 

  • Carlswell, D.A., Curtis, C.C. and Kanaris-Sotiriou, R. (1974): Vein metasomatism in peridotite at Kalskaret near Tafjord, South Norway. J. Petrol. 15,383–390.

    Google Scholar 

  • Chidester, H. (1962): Petrology and geochemistry of selected talc-bearing rocks in North-Central Vermont. U.S.Geol.Surv.Prof.Paper 345, 207p.

    Google Scholar 

  • Chou, I. and Eugster, H.P. (1977): Solubility of magnetite in supercritical chloride solutions. Amer.J.Sci. 277, 1296–1314.

    Article  Google Scholar 

  • Curtis, C.D. and Brown P.E. (1969): The metasomatic development in the zoned ultrabasic bodies in Unst, Shetland. Contr.Mineral.Petrol. 24, 275–292.

    Article  Google Scholar 

  • Curtis, C.D. and Brown P.E. (1971): Trace element behavior in the zoned metasomatic bodies of Unst, Shetland. Contr.Mineral.Petrol. 31, 87–93.

    Article  Google Scholar 

  • Day, H.W., Chernosky, J.V. and Kumin, H.J. (1985): Equilibria in the system MgO-SiO2-H2O: a thermodynamic analysis. Amer.Mineralogist 70, 237–248.

    Google Scholar 

  • Delany, J.M. and Helgeson, H.C. (1978): Calculation of the thermodynamic consequences of dehydration in subducting oceanic crust to 100 kb and > 800° C. Amer.J.Sci. 279, 638–686.

    Article  Google Scholar 

  • Eckstrand, O.R. (1975). The Dumont Serpentinite: A model for control of nickeliferous opaque mineral assemblages by alteration reactions in ultramafic rocks. Econ. Geol. 70, 183–201.

    Article  Google Scholar 

  • Ernst, W.G. (1976): Petrologic phase equilibria. W.H. Feeman, San Francisco.

    Google Scholar 

  • Eugster, H.P. (1977): Compositions and thermodynamics of metamorphic solutions, 183–202, in D.G. Fraser (ed.), Thermodynamics in geology. Reidel, Dordrecht-Holland, 410 p.

    Google Scholar 

  • Evans, B.W. (1977): Metamorphism of alpine peridotite and serpentinite. Ann.Rev.Earth Planet.Sci.5, 397–447.

    Article  Google Scholar 

  • Evans, B.W. and Trommsdorff, V. (1974): Stability of enstatite + talc and CO2-metasomatism of metaperidotite, Val d’Efra, Lepontine Alps. Amer.J.Sci., 274 274–296.

    Article  Google Scholar 

  • Evans, B.W., Trommsdorff, V. and Richter, W. (1979): Petrology of an eclogite-metarodingite suite at Cima di Gagnone, Ticino, Switzerland. Amer.Mineralogist 64,15–31.

    Google Scholar 

  • Evans, B.W., Trommsdorff, V. and Goles, G. (1981): Geochemistry of high grade eclogites and metarodingites from the Central Alps. Contr.Mineral.Petrol. 77, 301–311.

    Article  Google Scholar 

  • Evans, B.W. and Trommsdorff, V. (1983): Fluorine hydroxyl titanian clinohumite in alpine recrystallized garnetperidotite: compositional controls and petrologic significance. Amer.Jour.Sci.283A, 355–369.

    Google Scholar 

  • Fisher, G.W. (1977): Nonequilibrium thermodynamics in metamorphism, ‘318–403, in Fraser, D.G. (ed.): Thermodynamics in geology. Reidel, Dordrecht, Holland.

    Google Scholar 

  • Fletcher, R.C. and Hofmann, A. (1974): Simple models of diffusion and combined diffusion-infiltration metasomatism, 243–259, in: Hofmann, A. et al., ed., Geochemical transport and kinetics, Carnegie Inst. Wash.Publ. 634, 353p.

    Google Scholar 

  • Flowers, G.C. (1979): Correction of Holloway’s (1977) adaption of the modified Redlich-Kwong equation of state for the calculation of the fugacities of molecular species in supercritical fluids of geologic interest. Contr.Mineral.Petrol. 69, 315–318.

    Article  Google Scholar 

  • Fowler, M.B., Williams, H.R. and Windley, B.F. (1981): The metasomatic developement of zoned ultramafic balls from Fiskenasset, Est Greenland. Min.Mag. 44, 171–177.

    Article  Google Scholar 

  • Frantz, J.D. and Mao, H.K. (1976): Bimetasomatism resulting from intergranular diffusion: I. A theoretical model for monomineralic reaction zone sequences. Amer.J.Sci. 276, 817–840.

    Article  Google Scholar 

  • Frantz, J.D. and Mao, H.K. (1979): Bimetasomatism resulting from intergranular diffusion: II. Prediction of multimineralic zone sequences. Amer. J. Sci. 279, 302–323.

    Article  Google Scholar 

  • Frisch, C. and Helgeson, H.C. (1984): Metasomatic phase relations in dolomites of the Adamello Alps. Amer.J.Sci.284, 121–185.

    Article  Google Scholar 

  • Frost, R. (1975): Contact metamorphism of serpentinite, chloritic black wall and rodingite at Paddy-Go-Easy Pass, Central Cascades, Washington. Jour.Petrol. 16, 272–313.

    Google Scholar 

  • Garrels, R. and Mckenzie, F. (1971): Evolution of sedimentary rocks. W.Norton Co., New York, 397p.

    Google Scholar 

  • Gubser, R. and Sommerauer J. (1976,ms): The MICROP-system. Ausgewählte Programme zur Korrektur, statistischen Verarbeitung und Plotdarstellung von Messdaten aus der Elektronen-Mikrosonde. Program library, Inst. Krist. Petrogr. ETH-Zürich.

    Google Scholar 

  • Harpum, J.R. (1957): Soapstone bodies produced by magnesium metasomatism in south-west Tanganyika. Second meet., East-Centr. and South. Regional Comm. Geol., Tananarive, 183–192.

    Google Scholar 

  • Heinrich, C. (1982): Kyanite-eclogite to amphibolite facies evolution of hydrous mafic and pelitic rocks, Adula Nappe, Central Alps. Contrib.Mineral.Petrol.81, 30–38.

    Article  Google Scholar 

  • Heinrich, C. (1983): Die regionale Hochdruckmetamorphose der Aduladecke, Zentralalpen, Schweiz. Ph.D.thesis no. 7282, ETH-Zurich, 193p.

    Google Scholar 

  • Helgeson, H.C. (1970): A chemical and thermodynamic model of ore deposition in hydrothermal systems. Min.Soc.Amer.Spec.Pap. 3, 155–186.

    Google Scholar 

  • Helgeson, H.C. (1979): Mass transfer among minerals and hydrothermal solutions, 586–610, in: Barnes, H.L. (ed.): Geochemistry of hydrothermal ore deposits, 2nd ed., Wiley, New York.

    Google Scholar 

  • Helgeson, H.C. (1982): Prediction of the thermodynamic properties of electrolytes at high temperatures, 133–177,in Rickard, D. and Wickman, F. (eds.), Chemistry and geochemistry of solutions at high temperatures and pressures, Physics and chemistry of the earth, 13 and 14.

    Google Scholar 

  • Helgeson, H.C. and Kirkham, D.H. (1974): Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and tempratures: I.Summary of the thermodynamic/electrostatic properties of the solute: Amer.J.Sci. 274, 1089–1198.

    Article  Google Scholar 

  • Helgeson, H.C. and Kirkham, D.H. (1976): III. Equation of state for aqueous species at infinite dilution. Amer.J.Sci.276,97–240.

    Article  Google Scholar 

  • Helgeson, H.C., Delany, J.M., Nesbitt, H.W. and Bird, D.K. (1978): Summary and critique of thermodynamic properties of rock-forming minerals. Amer.J. Sci. 278A, 229p.

    Google Scholar 

  • Hewitt, D.A. (1978): A redetermination of the fayalite-magnetite-quartz equilibrium between 650 and 850° C. Amer.J.Sci.278, 715–724.

    Article  Google Scholar 

  • Hofmann, A. (1972) Chromatographic theory of infiltration metasomatism and its application to feldpars. Amer.J.Sci. 272, 69–90.

    Article  Google Scholar 

  • Hurford, A.J. (1986): Cooling and uplift patterns in the Lepontine Alps, South Central Switzerland, and an age of vertical movement on the insubric fault line. Contrib.Mineral.Petrol. (in press).

    Google Scholar 

  • Jahns, R.H. (1967): Serpentinites in the Roxbury district, Vermont. In Wyllie, P. (ed.): Ultramafic and related rocks, Wiley, New York, 464p.

    Google Scholar 

  • Johannes, W. (1975): Zur Synthese und thermischen Stabilität von Antigorit. Fortschr.Mineral., 53, 36.

    Google Scholar 

  • Koons, P.O. (1981): A study of natural and experimental metasomatic assemblages in an ultramafic-quartzo-feldspatic metasomatic system from the Haast schist, South Island, New Zealand. Contr. Mineral. Petrol.78, 189–195.

    Article  Google Scholar 

  • Lichtner, P.C. (1985): Continuum model for simultaneous chemical reactions and mass transport in hydrothermal systems. Geochim.Cosmochim.Acta 49, 779–800.

    Article  Google Scholar 

  • Lichtner, P.C., Oelkers, E.H. and Helgeson, H.C. (1985): Comparison of exact and numerical finite difference calculations to the moving boundary problem resulting from aqueous diffusion coupled to precipitation/ dissolution of a stationary solid phase: J.Geophys.Res. (in press).

    Google Scholar 

  • Lichtner, P. C., Oelkers, E.H. and Helgeson, H.C. (1986): Interdiffusion with multiple precipitation/dissolution reactions: transient model and the steady state limit. Geochim.Cosmochim.Acta 50, 1951–1966.

    Article  Google Scholar 

  • Matthews, D.W. (1967): Zoned ultramafic bodies in the Lewisian of the Moine nappe in Skye. Scott.J.Geol.3, 17–33.

    Article  Google Scholar 

  • Naldrett, A.J. (1966): Talc-carbonate alteration of some serpentinized ultramafic rocks south of Timmins, Ontario. J.Petrol. 7, 489–99.

    Google Scholar 

  • Nissen, H.U., Wessicken, R., Woensdregt, C.F: and Pfeifer, H.R. (1980): Disordered intermediates between jimthompsonite and anthophyllite from the Swiss Alps. Proceedings from “Developments of electron microscopy and analysis (EMAG 1979)”, Brighton. Inst. Phys. Conf. Ser.no. 52, 99–100.

    Google Scholar 

  • Ohnmacht, W. (1974): Petrogenesis of carbonateorthopyroxenites (Sagvandites) and related rocks from Troms, Nothern Norway. J.Petrol. 15, 303–323.

    Google Scholar 

  • Oterdoom. W.H. (1978): Tremolite-and diopside-bearing serpentine assemblages in the CaO-MagO-SiO2-H2O multisystem. Schweiz. Mineral. Petrogr. Mitt. 58, 127–137.

    Google Scholar 

  • Pfeifer, H.R. (1977): A model for fluids in metamorphic ultramafic rocks: I. Observations at surface and subsurface conditions (high pH spring waters). Schweiz.Mineral.Petrogr.Mitt.57, 361–396.

    Google Scholar 

  • Pfeifer, H.R. (1978): Hydrothermal Alpine metamorphism in metaperidotite rocks of the Cima Lunga zone, Valle Verzasca, Switzerland. Schweiz.Mineral.Petrogr.Mitt. 58,400–405.

    Google Scholar 

  • Pfeifer, H.R. (1979, ms): Fluid-Gesteins-Interaktion in metamorphen Ultramafifiten der Zentralalpen. Ph.D.thesis no.6379, ETH-Zurich, 200p.

    Google Scholar 

  • Pfeifer, H.R. (1981): A mudel for fluids in metamorphosed ultramafic rocks, III. Mass transfer under amphibolite facies conditions in olivine-enstatite rocks of the Central Alps, Switzerland. Bull.Mineral. 104, 834–847.

    Google Scholar 

  • Pfeifer, H.R. et al. (in prep.): A model for metamorphic ultramafic rocks rocks: II. Fluid composition and mass transfer in serpentinites of the Central Alps.

    Google Scholar 

  • Philipps, A.H. and Hess, H.H. (1936): Metamorphic differentiation at contacts between serpentinites and siliceous country rocks. Amer.Mineral. 21, 333–362.

    Google Scholar 

  • Read, H.H: (1934): On zoned associations of antigorite, talc, actinolite, chlorite and biotite in Unst, Shetland Islands. Min.Mag. 23, 519–540.

    Article  Google Scholar 

  • Sanford, R.F. (1982): Growth of ultramafic reaction zones in greenschist to amphibolite facies metamorphism. Amer.J.Sci.282, 543–616.

    Article  Google Scholar 

  • Sato, M. (1972): Intrinsic oxygen fugacities of iron-bearing oxides and silicate minerals under low pressure. Geol. Soc.Am.Mem. 131, 289–307.

    Google Scholar 

  • Sharp, M.R. (1980): Metasomatic zonation of an ultramafic lens at Ikàtoq, near Faeringehavn, southern West Greenland. Grønlands Geol.Unders.135, 32p.

    Google Scholar 

  • Slaugther, J., Kerrick, D.M. and Wall, V.J. (1975): Experimental and thermodynamic study of equilibria in the system CaO-MgO-SiO2-H2O-CO2. Amer.J.Sci.275, 143–162.

    Article  Google Scholar 

  • Sommerauer, J. (1977,ms): COMIC-FD, Steuer-und Datenverarbeitungsprogramm zur Benützung der Elektronen-Mikrosonde SEMQ, 40p. Program library, Inst. Krist.Petrogr. ETH-Zürich.

    Google Scholar 

  • Spencer, K.J. and Lindsley, D.H. (1981): A solution model for coexisting iron-titanium oxides. Amer.Mineralogist 66, 1189–1201.

    Google Scholar 

  • Tempkin, M. (1945): Mixtures of fused salts as ionic solutions. Acta physicochimica U.R.S.S. 20, 411–420.

    Google Scholar 

  • Trommsdorff, V. (1972): Change in T-X during metamorphism of siliceous dolomitic rocks of the Central Alps. Schweiz.Mineral.Petrogr. Mitt.52, 567–571.

    Google Scholar 

  • Trommsdorff, V. and Evans, B. (1974): Alpine metamorphism of peridotitic rocks. Schweiz.Mineral.Petrogr.Mitt. 54, 333–354.

    Google Scholar 

  • Veblen, D.R., Buseck, P.R. and Burham, C.W. (1977): Asbestiform chain silicates: new minerals and structural groups. Science 198, 359–365.

    Article  Google Scholar 

  • Walther, J.V. and Helgeson, H.C., (1977): Calculation of the thermodynamic properties of aqueous silica and the solubility of quartz and its polymorphs at high pressures and temperatures.Amer.J.Sci. 277, 1315–1351.

    Article  Google Scholar 

  • Walther, J.V. and Helgeson, H.C. (1980): Description and interpretation of metasomatic phase relations at high pressures and temperatures: I. Equilibrium activities of ionic species in non-ideal mixtures of CO2 and H2O. Amer.J.Sci. 280, 575–606.

    Article  Google Scholar 

  • Walther, J.V. (1983): Description and interpretation of metasomatic phase relations at high pressures and temperatures: II. Metasomatic reaction between quartz and dolomite at Campolungo, Switzerland. Amer.J.Sci.283A, 459–485.

    Google Scholar 

  • Wear, K.J., Stephens, J.R. and Eugster, H.P. (1976): Diffusion metasomatism and mineral reaction zones: general principles and application to feldspar alteration. Amer.J.Sci.276, 767–816.

    Article  Google Scholar 

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Pfeifer, HR. (1987). A Model for Fluids in Metamorphosed Ultramafic Rocks: IV. Metasomatic Veins in Metaharzburgites of Cima di Gagnone, Valle Verzasca, Switzerland. In: Helgeson, H.C. (eds) Chemical Transport in Metasomatic Processes. NATO ASI Series, vol 218. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4013-0_22

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