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The Unavoidable Importance of Electrostatic Effects in the Structures of Weakly Bonded Complexes

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Structure and Dynamics of Weakly Bound Molecular Complexes

Part of the book series: NATO ASI Series ((ASIC,volume 212))

Abstract

The electrical interaction between static and polarized charge distributions of molecules is very important in determining the approach orientations of monomers making up hydrogen bonded complexes. A detailed analysis of those interactions is presented. The orientati onal angles describing the structures of complexes can be predicted by searching the surface of the electrical interaction energy, and a large number of binary complexes and several larger complexes have been studied in this way. The model appears to be generally successful.

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois, 61801, USA

    Clifford E. Dykstra & Shi-yi Liu

Authors
  1. Clifford E. Dykstra
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  2. Shi-yi Liu
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Editor information

Editors and Affiliations

  1. Molecular Spectroscopy Division, National Bureau of Standards, Gaithersburg, Maryland, USA

    Alfons Weber

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© 1987 D. Reidel Publishing Company

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Dykstra, C.E., Liu, Sy. (1987). The Unavoidable Importance of Electrostatic Effects in the Structures of Weakly Bonded Complexes. In: Weber, A. (eds) Structure and Dynamics of Weakly Bound Molecular Complexes. NATO ASI Series, vol 212. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3969-1_23

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  • DOI: https://doi.org/10.1007/978-94-009-3969-1_23

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8261-7

  • Online ISBN: 978-94-009-3969-1

  • eBook Packages: Springer Book Archive

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