Skip to main content

Physical and Chemical Factors Controlling Gaseous Deposition of SO2 to Snow

  • Chapter
Seasonal Snowcovers: Physics, Chemistry, Hydrology

Part of the book series: NATO ASI Series ((ASIC,volume 211))

Abstract

Dry deposition of SO2 to snow was studied under well-controlled laboratory conditions and described using a diffusion and aqueous-phase reaction model. The amount of sulfur uptake depended strongly on the liquid-water content of the snow, the time scale considered, the SO2 concentration and the S(IV) to S(VI) oxidation rate. The average deposition velocity in 48 experiments of 6–12 hr duration each was 0.06 cm s-1, with lower values for subzero snow (0.02–0.05 cm s-1) and higher values for snow at 0°C (> 0.07 cm s-1). Average penetration of sulfur into the snowpack was 4–7 cm.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Bales, R.C., M.P. Valdez and G.A. Dawson, Gaseous deposition to snow: II, physical-chemical model for SO2 deposition, submitted to J. Geophys. Res., 1986.

    Google Scholar 

  • Cadle, S.H., J.M. Dasch, and P.A. Mulawa, Atmospheric concentrations and the deposition velocity to snow of nitric acid, sulfur dioxide and various particulate species, Atmos. Environ., 19, 1819–1827, 1985.

    Article  Google Scholar 

  • Huebert, B.J., Measurements of the dry-deposition flux of nitric acid vapor to grasslands and forest, in Precipitation Scavenging, Dry Deposition and Resuspension, vol. 2, edited by H.R. Pruppacher, R.G. Semonin, and W.G.N. Slinn, pp. 785–794, Elsevier North-Holland, New York, 1983.

    Google Scholar 

  • Huebert, B.J., and C.H. Robert, The dry deposition of nitric acid to grass, J. Geophys. Res., 90, 2085–2090, 1985.

    Article  Google Scholar 

  • Nenow, D., Surface Premelting, Prog. Crystal Growt and Character, 9, 185–225, 1984.

    Article  Google Scholar 

  • Ocampo, J. and J. Klinger, Adsorption of N2 and CO2 on ice, J. Colloid. Interface Sci., 86, 377–383, 1982.

    Article  Google Scholar 

  • Pierson, W.R., W.W. Brachaczek, R.A. Gorse, Jr., S.M. Japar, and G.M. Norbeck, On the acidity of dew, J. Geophys. Res., 91, 4083–4096, 1986.

    Article  Google Scholar 

  • Sommerfeld, R.A., and D. Lamb, Preliminary measurements of SO2 adsorbed on ice, Geophys. Res. Lett., 13., 349–351, 1986.

    Article  Google Scholar 

  • Valdez, M.P., R.C. Bales, D.A. Stanley, G.A. Dawson, Gaseous deposition to snow: I, Experimental study of SO2 and NO2 deposition, submitted to J. Geophys. Res., 1986.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1987 D. Reidel Publishing Company

About this chapter

Cite this chapter

Bales, R.C., Valdez, M.P., Dawson, G.A., Stanley, D.A. (1987). Physical and Chemical Factors Controlling Gaseous Deposition of SO2 to Snow. In: Jones, H.G., Orville-Thomas, W.J. (eds) Seasonal Snowcovers: Physics, Chemistry, Hydrology. NATO ASI Series, vol 211. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3947-9_17

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-3947-9_17

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8251-8

  • Online ISBN: 978-94-009-3947-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics