Summary
The use of kinetic sub-models in the simulation of the physico-chemical behaviour of atmospheric pollutants is a widely accepted approach. These sub-models are generated primarily in laboratory kinetic studies in order to reduce the complexity of the overall reacting system. For the particular case of the degradation of hydrocarbons, it will be shown that one not only needs the concentration profiles of the stable species formed, but also that the qualitative and quantitative determination of the reactive intermediates such as atoms or radicals is required for the validation of the proposed kinetic model.
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© 1987 ECSC, EEC, EAEC, Brussels and Luxembourg
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Vinckier, C., Peeters, J. (1987). A Comparison of Models for the Oxidation of Acetylene at 300 K. In: Angeletti, G., Restelli, G. (eds) Physico-Chemical Behaviour of Atmospheric Pollutants. Air Pollution Research Report. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3841-0_24
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DOI: https://doi.org/10.1007/978-94-009-3841-0_24
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