Abstract
The chemistry of transition metals incorporated in ionomers based on perfluoroethylene sulfonic acid (Nafion, PFSA) and polystyrene sulfonic acid (SPS or PSSA) materials is explored. Their formation, dehydration and reactions with gaseous molecules are illustrated by spectroscopic studies of metal-gas product moieties and reactive intermediates, such as metal carbonyls and hydrides, and by the formation of dispersed metal particles in the ionomers. The use of metal-containing ionomers as catalysts is illustrated by the role of Rh, Ru and Pt - containing ionomers in the CO oxidation reaction.
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© 1987 D. Reidel Publishing Company, Dordrecht, Holland
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Risen, W.M. (1987). Chemistry in Ionomers. In: Pineri, M., Eisenberg, A. (eds) Structure and Properties of Ionomers. NATO ASI Series, vol 198. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3829-8_7
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DOI: https://doi.org/10.1007/978-94-009-3829-8_7
Publisher Name: Springer, Dordrecht
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