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Structure/Reactivity and Thermochemistry of Ions pp 97–164Cite as

Kinetic Energy Dependence of Ion-Molecule Reactions: From Triatomics to Transition Metals

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Part of the book series: NATO ASI Series ((ASIC,volume 193))

Abstract

The kinetic energy dependence of a variety of ion-molecule reactions are examined using guided ion beam mass spectrometry. This experimental technique is shown to provide unprecedented detail in reaction excitation functions over an extremely wide kinetic energy range. Fundamental triatomic systems (A+ + H2, HD, D2 where A = 0, N, C, Si, Ne, Ar, Kr, and Xe) are examined with an eye on understanding the details of variations in the reaction excitation functions. These include the effects of thermochemistry, electronic degeneracy, adiabatic versus diabatic potential energy surfaces, and spin-orbit coupling. This insight is then applied to the reactions of hydrogen with atomic transition metal ions in specific electronic states. Several diabatic “rules” of reactivity become evident from these studies. These rules are further examined in more complex systems, the reactions of atomic metal ions with alkanes. Finally, studies of metal dimer and cluster ions are discussed with an emphasis on the effects of internal excitation.

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  1. Chemistry Department, University of California, Berkeley, CA, 94720, USA

    P. B. Armentrout

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  1. Center for Chemical Physics, National Bureau of Standards, Gaithersburg, Maryland, USA

    Pierre Ausloos  & Sharon G. Lias  & 

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© 1987 D. Reidel Publishing Company, Dordrecht, Holland

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Armentrout, P.B. (1987). Kinetic Energy Dependence of Ion-Molecule Reactions: From Triatomics to Transition Metals. In: Ausloos, P., Lias, S.G. (eds) Structure/Reactivity and Thermochemistry of Ions. NATO ASI Series, vol 193. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3787-1_6

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