Abstract
Only a few anions can be produced efficiently and exclusively in the gas phase by electron impact, so indirect methods, usually involving gas phase ion-molecule chemistry must be employed. In this paper we summarize some of the methods which have been used in the flowing afterglow (FA) and ion cyclotron resonance (ICR) spectrometer for producing anions, particularly carbanions, for subsequent investigation of their chemical reactions.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
J. E. Bartmess and R. T. Mclver, Jr. in Gas Phase Ion Chemistry; M. T. Bowers, ed.; Academic Press, New York, 1979; Vol. 2, Chapter 11.
R. N. McDonald, A. K. Chowdhury and P. L. Schell, J.Am.Chem.Soc. 106 6095(1984).
R. R. Squires, V. M. Bierbaum, J. J. Grabowski and C. H. DePuy, J.Am.Chem.Soc., 105, 5185(1983).
C. H. DePuy, V. M. Bierbaum, G. K. King and R. H. Shapiro, J.Am.Chem.Soc. 100, 2921(1978).
C. H. DePuy, V. M. Bierbaum, L. A. Flippin, J. J. Grabowski, G. K. King, R. J. Schmitt and S. A. Sullivan, J.Am.Chem.Soc. 102, 5012(1980).
C. H. DePuy, V. M. Bierbaum, R. Damrauer and J. A. Soderquist, J.Am.Chem.Soc. 107 3385(1985).
D. B. Jacobson and B. S. Freiser, J.Am.Chem.Soc. 107 7399(1985).
V. M. Bierbaum, J. J. Grabowski and C. H. DePuy, J.Phys.Chem. 88 1389(1984).
V. M. Bierbaum, C. H. DePuy and R. H. Shapiro, J.Am.Chem.Soc. 99 5800(1977).
S. R. Kass, J. Filley, J. M. Van Doren and C. H. DePuy, J.Am.Chem.Soc. 108 2849(1986).
S. R. Kass and C. H. DePuy, J.Org.Chem. 50 2874(1985).
K. Takashima and J. M. Riveros, J.Am.Chem.Soc. 100 6128(1978).
D. W. Fahey, H. Bohringer, F. C. Fehsenfeld and E. E. Ferguson, J.Chem.Phys. 76 1799(1982).
C. H. DePuy and V. M. Bierbaum, J.Am.Chem.Soc. 103 5034(1981).
S. W. Froelicher, B. S. Freiser and R. R. Squires, J.Am.Chem.Soc. 108 2853(1986).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 D. Reidel Publishing Company, Dordrecht, Holland
About this chapter
Cite this chapter
DePuy, C.H., Bierbaum, V.M. (1987). Formation of Anions in the Gas Phase. In: Ausloos, P., Lias, S.G. (eds) Structure/Reactivity and Thermochemistry of Ions. NATO ASI Series, vol 193. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3787-1_14
Download citation
DOI: https://doi.org/10.1007/978-94-009-3787-1_14
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8185-6
Online ISBN: 978-94-009-3787-1
eBook Packages: Springer Book Archive