Abstract
The basic optical phenomena responsible for the transparency of heavy metal fluoride glasses are examined in terms of theory and experiment. The preparation and properties of the most widely used zirconium tetrafluoride-based compositions are emphasized, and their optical behavior contrasted with that observed in silicate glasses and other vitreous fluorides. The topics addressed include ultraviolet and infrared absorption, light scattering, refractive index, and the effects of ionizing radiation. The role of impurities such as metallic oxides, hydroxyl species, and carbon dioxide, and the merits and disadvantages of various reactive atmosphere treatments are discussed.
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References
Miyashita, T. and Manabe, T., IEEE J. Quantum Electron. QE-18, 1432 (1982).
Drexhage, M.G., pp. 151–243 in “Treatise on Materials Science Science and Technology Vol. 26: Glass IV” (Academic Press, NY, 1985).
Tran, D.C., Sigel, G.H., and Bendow, B., J. Lightwave Tech. LT-2, 566 (1984).
Tokiwa, H. Mimura, Y., Shinbori, O. and Nakai, T., J. Lightwave Tech. LT-3, 569 (1985).
Tokiwa, H., Mimura, Y., Shinbori, O. and Nakai, T., J. Lightwave Tech. LT-3, 574 (1985).
Ohsawa, K. and Shibata, T., J. Lightwave Tech. LT-2, 602 (1984).
SpecTran Corp., Sturbridge, MA, USA; Le Verre Fluore, St. Erblon, France; Furukawa Electric Co. Ltd., Tokyo, Japan.
Lucas, J., Tregoat, D., El-Houari, A. and Fonteneau, G., Proc. SPIE 484, 36 (1984).
Drexhage, M.G. El-Bayoumi, O., Moynihan, C.T., Bruce, A.J., Chung, K.H., Gavin, D.L. and Loretz, T., J. Am. Ceram. Soc. 65, C168 (1982).
Drexhage, M.G., Mater. Sci. Forum 5, 1 (1985).
Suscavage, M.J., Hutta, J.J., Drexhage, M.G., Perrazo, N., Mossadegh, R. and Moynihan, C.T., Mater. Sci. Forum 5, 35 (1985).
Drexhage, M.G., Hutta, J.J., Suscavage, M.J., Mossadegh, R. and Moynihan, C.T., Mater. Sci. Forum 6, 509 (1985).
Moore, M.W., Carter, S.F., France, P.W. and Williams, J.R., Mater. Sci. Forum 6, 525 (1985).
see Tran, D.C., “Light Scattering in Halide Glass Fibers”, this volume.
Schroeder, J., Tsoukala, V., Staller, C., Bruce, A.J., Moynihan, C.T., Hutta, J.J., Suscavage, M.J. and Drexhage, M.G., Electron. Lett. 20, 860 (1984).
Schroeder, J., Fox-Bilmont, M., Pazol, B., Tsoukala, V., Drexhage, M.G. and El-Bayoumi, O., Proc. SPIE 484, 61 (1984).
Schroeder, J., Floudas, J.A., Stiller, M.A. and Drexhage, M.G., Mater. Sci. Forum. 6, 577 (1985).
Schroeder, J., Tsoukala, V., Bruce, A.J., Staller, C.O., Hutta, J.J., Suscavage, M.J. and Drexhage, M.G., Mater. Sci. Forum 6 561 (1985).
Nakai, T., Mimura, Y., Tokiwa, H. and Shinbori, O., J. Lightwave Tech. LT-4, 87 (1986).
Cotter, D., J. Opt. Commun. 4, 10 (1983).
Dumbaugh, W.H. and Morgan, D.W., J. Non-Cryst. Solids 38–39, 211 (1980).
Izumitani, T. and Hirota, S., Mater. Sci. Forum. 6, 645, (1985).
Hirota, S., Izumitani, T. and Onaka, R., J. Non-Cryst. Solids 72, 39 (1985).
Sigel, G.H., pp. 5–89 in “Glass I: Interaction With Electromagnetic Radiation” (Academic Press, NY, 1977).
Pinnow, D.A., Rich, T.C., Ostermayer, F.W., and DiDomenico, M., Appl. Phys. Lett. 22, 527 (1973).
see Poignant, H., “The Role of Impurities in Halide Glass” and Reisfeld, R., “Optical Properties of Rare Earth and Transition Metal Ions in Fluoride Glasses”, this volume.
Ohishi, Y., Mitachi, S. and Takahashi, S., Mater. Res. Bull. 19, 673 (1984).
France, P.W., Carter, S.F., Williams, J. and Beales, K.J., Electron. Lett. 20, 607 (1984).
Maze, G., Cardin, V. and Poulain, M., J. Lightwave Tech. LT-2, 596 (1984).
Robinson, M., Pastor, R.C., Turk, R.R., Devor, D.P., Braunstein, M. and Braunstein, R., Mater. Res. Bull. 15, 735 (1980).
Tran, D.C. and Fisher, C., US Patent 4,539,032.
Brown, R.N. and Hutta, J.J., Appl. Opt. 24, 4500 (1986).
Mitachi, S. and Miyashita, T., Appl. Opt. 24, 2419 (1983).
Sun, K.H., Glass Tech. 20, 36 (1979).
Rosiewicz, A. and Gannon, J.R., Electron. Lett. 17, 184 (1981).
Cases, R., Alcala, R. and Tran, D.C., Mater. Sci. Forum 6, 755 (1985).
Yeh, D.C., Sibley, W.A., Suscavage, M.J. and Drexhage, M.G., “Radiation Effects and Optical Transitions in Ytterbium-Doped Fluoride Glass” submitted to J. Appl. Phys.
Tanimura, K., Sibley, W.A., Suscavage, M.J. and Drexhage, M.G., J. Appl. Phys. 58, 4544 (1985).
Cases, R., Griscom, D.L. and Tran, D.C., J. Non-Cryst. Solids 72, 51 (1985).
Friebele, E.J. and Tran, D.C., J. Non-Cryst. Solids 72, 221 (1985).
Griscom, D.L. and Tran, D.C., J. Non-Cryst. Solids 72, 159 (1985).
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© 1987 Martinus Nijhoff Publishers, Dordrecht
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Drexhage, M.G. (1987). Optical Properties of Fluoride Glasses. In: Almeida, R.M. (eds) Halide Glasses for Infrared Fiberoptics. NATO ASI Series, vol 123. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3561-7_14
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DOI: https://doi.org/10.1007/978-94-009-3561-7_14
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