Reactions of Organometallic Compounds with Surfaces of Supported and Unsupported Metals

Part of the NATO ASI Series book series (ASIC, volume 231)


Interactions of organometallic compounds with metal surfaces can be used to produce metal films and coatings as well as to modify the properties of metal catalysts for hydrocarbon conversion. The literature is reviewed, and results are evaluated characterizing the interaction of metal carbonyl clusters with surfaces of supported metals under mild conditions. The reactions lead to the preparation of highly dispersed bimetallic particles, which have homogeneous compositions and nonadditive properties in CO hydrogenation and hydrocarbon conversion.


Bimetallic Catalyst Organometallic Compound Metal Carbonyl Palladium Particle Bimetallic Particle 
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  1. 1.
    Yu.I. Yermakov, B.N. Kuznetsov, and V.A. Zakharov, Catalysis by Supported Complexes. Studies in Surface Science and Catalysis, v. 8, Elsevier (1981).Google Scholar
  2. 2.
    J.H. Sinfelt, Adv. Catal. 23, 91 (1973).CrossRefGoogle Scholar
  3. 3.
    V. I. Zaikovskii, V. I. Kovalchuk, Yu. A. Ryndin, L. M. Plyasova, B. N. Kuznetsov, and Yu. I. Yermakov, React. Kinet. Catal. Lett. 14, 99 (1980).CrossRefGoogle Scholar
  4. V.L. Kuznetsov, A.F. Danilyuk, I.S. Kolosova, and Yu. I. Yermakov, React. Kinet. Catal. Lett. 21, 249 (1982).CrossRefGoogle Scholar
  5. 4.
    J. Margitfalvi, M. Hegedus, S. Gobolos, E. Kern-Talas, P. Szedlacsek, S. Szabo, and F. Nagy, Proc. 8th Intern. Congr. Catal. 4, 903 (1984).Google Scholar
  6. 5.
    J. Margitfalvi, E. Kern-Talas, S. Gobolos, and M. Hegedus, The 9th North American Meeting of the Catalysis Society, P-24, Houston (1985).Google Scholar
  7. 6.
    J. Margitfalvi, E. Kern-Talas, and S. Gobolos, The 12th International Conference on Organometallic Chemistry, p. 518, Vienna (1985).Google Scholar
  8. 7.
    J. Margitfalvi, M. Hegedus, P. Szedlacsek, and F. Nagy, Appl. Catal. 15, 69 (1985).CrossRefGoogle Scholar
  9. 7a.
    Ch. Travers, J.P. Bournonville, and G. Martino, Proc. 8th Intern. Congr. Catal. 4, 891, (1984).Google Scholar
  10. 8.
    G.J. Antos, U.S. Patents 4,159,939;4,175,031;4,183,805;4,197,188;4,206,040;4,206,041;4,212,769;4,193,863;4,23,897;4,290,921;4,292,207;4,298,504;4,353,815.Google Scholar
  11. 9.
    G.J. Antos, U.S. Patent 4,174,298.Google Scholar
  12. 10.
    G.J. Antos, U.S. Patents 4,175,056;4,210,561;4,358,399.Google Scholar
  13. 11.
    Yu.A. Ryndin, L.V. Gorodova, O.V. Tyunina, A.A. Davydov, and Yu.I. Yermakov, React. Kinet. Catal. Lett. 26, 79 (1984).CrossRefGoogle Scholar
  14. 12.
    D.I. Kochubey, M.A. Kozlov, L.V. Gorodova, Yu.A. Ryndin, and Yu.I. Yermakov, React. Kinet. Catal. Lett. 26, 91 (1984).CrossRefGoogle Scholar
  15. 13.
    Yu.A. Ryndin, L.V. Gorodova, V.I. Zaikovskii, and Yu.I. Yermakov, React. Kinet. Catal. Lett. 26, 103 (1984).CrossRefGoogle Scholar
  16. 14.
    Yu.A. Ryndin, L.V. Gorodova, D.I. Kochubey, M.A. Kozlov, and A.A. Davydov, The 1st Italian-Soviet Seminar on Catalysis, p. 165, Messina (1984).Google Scholar
  17. 15.
    Vapor Deposition, (Eds. C.F. Powell, J.H. Oxly, and J.M. Blocher, Jr.) John Wiley and Sons, Inc. (1968).Google Scholar
  18. 16.
    Deposition of Films and Coatings by Decomposition of Organometallic Compounds, (Ed. G.A. Rasuvaev), Nauka, Moscow (1981).Google Scholar
  19. 17.
    V.G. Syrkin, Gas-Phase Metallization through Carbonyls, Metallurgiya, Moscow (1985).Google Scholar
  20. 18.
    Yu.I. Yermakov, Catal. Rev.-Sci. Eng. 12, 92 (1976).Google Scholar
  21. 19.
    V.L. Kuznetsov, A.T. Bell, and Yu.I. Yermakov, J. Catal. 65, 374 (1980).CrossRefGoogle Scholar
  22. 20.
    M.I. Bruce and F.G.A. Stone, Angew. Chem., Int. Ed. Engl. 7, 427 (1968).CrossRefGoogle Scholar
  23. 21.
    Yu.A. Ryndin, R.F. Hicks, A.T. Bell, and Yu.I. Yermakov, J. Catal. 70, 287 (1981).CrossRefGoogle Scholar
  24. 22.
    V. Ponec, Catal. Rev.-Sci. Eng. 11, 41 (1975).CrossRefGoogle Scholar
  25. 23.
    W.M.H. Sachtler and R.A. Van Santen, Adv. Catal. 26, 69 (1977).CrossRefGoogle Scholar
  26. 24.
    Y. Kobori, H. Yamasaki, Sh. Naito, T. Onishi, and K. Tamaru, J. Chem. Soc., Faraday Trans. 178, 1474 (1982).Google Scholar
  27. 25.
    G. Broden, T.N. Rhodin, and G. Brucner, Surf. Sci. 59, 593 (1976).CrossRefGoogle Scholar

Copyright information

© Kluwer Academic Publishers 1988

Authors and Affiliations

  1. 1.Institute of CatalysisNovosibirskUSSR

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