Abstract
In this contribution it is shown that solid state 13C NMR is a powerful technique for the identification and study of cyclodextrin inclusion compounds. From the unique splitting pattern of the host lattice spectrum, Cd compounds can be identified, and under favourable conditions information about the stoichiometry and the asymmetric unit of the crystal can be obtained. It is also shown that spherical agglomeration techniques can be used to produce Cd inclusion compounds in a particularly convenient form.
NRCC No: 28804
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References
J, Szejtli, Cyclodextrins and their inclusion Compounds, Akadémiai Kiado, Budapest 1982.
W. Saenger, Angew. Chemie Int. Ed. 19, 344 (1980)
S. Nagatomo, Chemical Economy and Engineering Review 17, 28 (1985)
I.E. Puddington and B.D. Sparks, Minerals Sci. Eng., 7, 282 (1975)
A.F. Sirianni, C.E. Capes and I.E. Puddington, Canad. J. Chem. Eng. 47, 166 (1969)
C.A. Fyfe, Solid State NMR for Chemists, CFC Press, Guelph 1984.
see, for example J.P. Behr and J.M Lehn, J. Am. Chem. Soc. 98, 1743 (1976)
Y. Inoue, T. Okuda and R. Chûjô, Carbohydrate Res. 141, 179 (1985).
J.A. Ripmeester, J. Inclusion Phen 4, 129, (1986)
M.J. Gidley and S.M. Bociek, J. Chem. Soc. Chem. Comm. 1986, 1223
R.P. Veregin, C.A. Fyfe, R.H. Marchessault and M.G. Taylor. Carbohydrate Res. 160, 41 (1987).
J.A. Ripmeester, J. Inclusion Phen. 6, 31 (1988).
H. Saito, G. Izumi, S. Mamizuka, S. Suzuki and R. Tabeta, J. Chem. Soc. Chem. Comm. 1982, 1386
P.C. Manor and W. Saenger, J. Am. Chem. Soc. 96, 3630 (1974)
J.A. Ripmeester, unpublished results
Y. Inoue, T. Okuda, F.H. Kuan and R. Chûjô, Carbohydrate, Res. 129, 9 (1984)
Y. Inoue, F.-H. Kuan and R. Chûjô, Carbohydrate Res. 159, 1 (1987)
W.P. Rothwell and J.S. Waugh, J. Chem. Phys. 74, 2721 (1981)
S.J. Opella and M.H. Frey, J. Am. Chem. Soc. 101, 5854 (1979)
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© 1988 Kluwer Academic Publishers
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Ripmeester, J.A., Majid, A. (1988). Preparation and 13C NMR Identification of Solid Cyclodextrin Inclusion Compounds. In: Huber, O., Szejtli, J. (eds) Proceedings of the Fourth International Symposium on Cyclodextrins. Advances in Inclusion Science, vol 5. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2637-0_26
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DOI: https://doi.org/10.1007/978-94-009-2637-0_26
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-7690-6
Online ISBN: 978-94-009-2637-0
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