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Modified Cyclodextrins; Substitution at O3 and Complexation of Metals

  • Conference paper
Proceedings of the Fourth International Symposium on Cyclodextrins

Part of the book series: Advances in Inclusion Science ((AIS,volume 5))

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Abstract

Chemical modification of 2,6-O-Dimethyl-β-Cyclodextrin leads to 3-O-Allyl,2-6-O-Dimethyl-β-Cyclodextrin, I; 3-O-Epoxypropyl,2,6-O-Dimethyl-β-Cyclodextrin, II; and 3-0-(1-Dimethylamino-2-Hydroxypropyl),2,6-Dimethyl-β-Cyclodextrin, III. The stereochemistry of these compounds was studied using the SYBYL Molecular Graphics program and by 500 MHz NMR which showed the 2-O-Methyl protons in II to be highly sensitive to solvent effects. Reaction of I with RhCl3 leads to a compound proposed as cyclodextrin dimer containing Rh coordinated to olefinic groups.

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Author information

Authors and Affiliations

  1. E.R. 180 du C.N.R.S., Universite Paris-SUD, Centre Pharmaceutique, 92290, Chatenay-Malabry, France

    A. W. Coleman & G. Tsoucaris

  2. U.A. 496 du C.N.R.S., Universite Paris-SUD, Centre Pharmaceutique, 92290, Chatenay-Malabry, France

    H. Galons, H. Parrot & M. Miocque

Authors
  1. A. W. Coleman
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  2. G. Tsoucaris
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  3. H. Galons
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  4. H. Parrot
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  5. M. Miocque
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Editor information

Editors and Affiliations

  1. Consortium für Elektrochemische Industrie GmbH, Munich, Germany

    O. Huber

  2. CHINOIN Pharmaceutical-Chemical Works, Budapest, Hungary

    J. Szejtli

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© 1988 Kluwer Academic Publishers

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Coleman, A.W., Tsoucaris, G., Galons, H., Parrot, H., Miocque, M. (1988). Modified Cyclodextrins; Substitution at O3 and Complexation of Metals. In: Huber, O., Szejtli, J. (eds) Proceedings of the Fourth International Symposium on Cyclodextrins. Advances in Inclusion Science, vol 5. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2637-0_24

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  • DOI: https://doi.org/10.1007/978-94-009-2637-0_24

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7690-6

  • Online ISBN: 978-94-009-2637-0

  • eBook Packages: Springer Book Archive

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