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Hydridocarbene Complexes of Platinum(II) Derived from Electrophilic Cleavage of C-F Bonds in Hydridotrifluoromethyl Compounds by Proton Acids

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Advances in Metal Carbene Chemistry

Part of the book series: NATO ASI Series ((ASIC,volume 269))

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Abstract

A low-temperature structural investigation of trans-PtH(CF3)-(PPh3)2 (1) shows a lengthening of C-F bonds compared to fluorocarbon compounds. It is observed that the C-F bond in 1 readily reacts with HBF4 in the presence of protic nucleophiles such as alcohols and thiols to give carbene complexes. The intermediacy of an hydridodifluorocarbene species has been confirmed by low-temperature NMR spectroscopy.The X-ray structure of an hydridocarbene complex of Pt(II) is also reported.

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References

  1. D.L. Reger and M.D. Dukes, J. Organomet. Chem., 153, 67 (1978).

    Article  CAS  Google Scholar 

  2. G.R. Clark, S.V. Hoskins and W.R. Roper, J. Organomet. Chem., 234,C9 (1982).

    Article  CAS  Google Scholar 

  3. T.G. Richmond, A.M. Crespi and D. F. Shriver, Organometallics,3, 314 (1984).

    Article  CAS  Google Scholar 

  4. T.G. Richmond and D.F. Shriver, Organometallics, 2, 1061 (1983)

    Article  CAS  Google Scholar 

  5. T.G. Richmond and D.F. Shriver, Organometallics, 3, 305 (1984).

    Article  CAS  Google Scholar 

  6. M.B. Hall and R.F. Fenske, Inorg. Chem., 11, 768 (1972).

    Article  CAS  Google Scholar 

  7. R.A. Michelin, R. Ros and U. Belluco,Inorg. Chim. Acta, 24, L33 (1977)

    Article  CAS  Google Scholar 

  8. R.A. Michelin and R.Ros, J.C.S., Dalton Trans., submitted.

    Google Scholar 

  9. R.A. Michelin, G. Facchin and R. Ros, J. Organomet.Chem.,279,C25 (1985).

    Article  CAS  Google Scholar 

  10. E.M. Badley, K.W. Muir and G.A. Sim, J.C.S., Dalton Trans., 1930 (1976)

    Google Scholar 

  11. L. Manojlovic-Muir and K.W. Muir, J.C.S.,Dalton Trans., 2427 (1974).

    Google Scholar 

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Author information

Authors and Affiliations

  1. Institute of Industrial Chemistry and Organometallic Research Center CNR, University of Padua, Via Marzolo 9, 35131, Padua, Italy

    R. A. Michelin & G. Guadalupi

  2. ICTR CNR, Corso Stati Uniti 4, 35100, Padua, Italy

    F. Benetollo

  3. Istituto Chimica Farmaceutica, University of Milan, 20131, Milan, Italy

    G. Bombieri

Authors
  1. R. A. Michelin
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  2. G. Guadalupi
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  3. F. Benetollo
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  4. G. Bombieri
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Editor information

Editors and Affiliations

  1. Institute for Inorganic Chemistry, University of Würzburg, Würzburg, Germany

    U. Schubert

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© 1989 Kluwer Academic Publishers

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Michelin, R.A., Guadalupi, G., Benetollo, F., Bombieri, G. (1989). Hydridocarbene Complexes of Platinum(II) Derived from Electrophilic Cleavage of C-F Bonds in Hydridotrifluoromethyl Compounds by Proton Acids. In: Schubert, U. (eds) Advances in Metal Carbene Chemistry. NATO ASI Series, vol 269. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2317-1_8

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  • DOI: https://doi.org/10.1007/978-94-009-2317-1_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7541-1

  • Online ISBN: 978-94-009-2317-1

  • eBook Packages: Springer Book Archive

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