Abstract
Aziridine reacts spontaneously in THF at room temperature or below with the coordinated RNC ligand in some neutral and cationic isocyanide complexes of Pd(II) and Pt(II) to yield 5-membered cyclic diaminocarbene complexes, respectively. Reactions between thiirane and Pd(II) isocyanide complexes yield the corresponding cyclic amino-thiocarbene derivatives. In the presence of NaCl, oxirane is observed to react in 2-chloroethanol with some Pt(II) isocyanide complexes to form the corresponding 5-membered cyclic aminooxy carbene complexes. Also hydrido-alkyl-carbene derivatives were prepared by reaction of azetidine with some hydrido-alkyl-isocyanide compounds.These latter complexes react with triphenylphosphine eliminating H-Rx derived from Pt-Rx cleavage by NH.
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© 1989 Kluwer Academic Publishers
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Bertani, R., Mozzon, M., Zanotto, L., Michelin, R.A. (1989). Synthesis of Cyclic and Acyclic Carbene Complexes Derived from Isocyanide Ligands in Complexes of Palladium(II) and Platinum(II). In: Schubert, U. (eds) Advances in Metal Carbene Chemistry. NATO ASI Series, vol 269. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2317-1_7
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DOI: https://doi.org/10.1007/978-94-009-2317-1_7
Publisher Name: Springer, Dordrecht
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