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The Coordination and Redox Chemistry of Vanadium in Aqueous Solution

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Vanadium in Biological Systems

Abstract

With the recent discoveries of the first two naturally occurring vanadium-containing enzymes, the bromoperoxidase and nitrogenase, the coordination chemistry and reactivity of vanadium is receiving renewed attention. One of the most intriguing features of vanadium is the number of stable oxidation states in which vanadium is known and the relative ease of interconversion between many of these states. Vanadium complexes in the oxidation states, - 3, - 1, 0, 1 +, 2 +, 3 +, 4 + and 5 + have been well characterized, although, only the 2 + through 5 + states are well known in aqueous solution and the 3 + through 5 + are the oxidation states in which vanadium is found in biological systems.

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  1. Department of Chemistry, University of California, Santa Barbara, CA, 93106, USA

    Alison Butler

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  1. Alison Butler
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  1. Department of Chemistry, University of New Hampshire, USA

    N. Dennis Chasteen

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© 1990 Kluwer Academic Publishers

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Butler, A. (1990). The Coordination and Redox Chemistry of Vanadium in Aqueous Solution. In: Chasteen, N.D. (eds) Vanadium in Biological Systems. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2023-1_2

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  • DOI: https://doi.org/10.1007/978-94-009-2023-1_2

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