Skip to main content

Tributyltin Concentration in Waters of the Chesapeake Bay

  • Chapter
Organotin

Abstract

Tributyltin (TBT) has been analyzed in unfiltered water samples from the Chesapeake Bay (USA) from 1984 to 1989. Areas with large numbers of recreational vessels and one area with a high density of commercial and naval craft were targeted because of the likely input of TBT from these sources. The latter area also contained several large ship repair facilities that could contribute the antifouling agent. The range of TBT concentrations found at any one station was large with highest levels associated with times of peak usage. Concentrations in excess of 100 ng l-1 were common in some areas. The state and federal restrictions on TBT use appear to have partially achieved their desired effect of reducing water concentrations. While only one data set is extensive enough to show statistically significant downward trends, all sets visually indicate a decrease. A model that fits the most extensive data set indicates an 8–30% per year decrease in water TBT concentration for stations near boating activities.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 429.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 549.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 549.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Batiuk, R. 1987. Survey of Tributyltin and Dibutyl-tin Concentrations at Selected Harbors in Chesapeake Bay. Final Report prepared for US Environmental Protection Agency. Chesapeake Bay Liaison Office, Annapolis, Maryland.

    Google Scholar 

  • Evans, D.A. and R.J. Huggett. 1991. Statistical modeling of intensive TBT monitoring data in two tidal creeks of the Chesapeake Bay. Mar. Environ. Res., 32, 169–186.

    Article  Google Scholar 

  • Hall, L.W., Jr, M.J. Lenkevich, W.S. Hall, A.E. Pinkney and S.J. Bushong. 1987. Evaluation of butyltin compounds in Maryland waters of Chesapeake Bay. Mar. Pollut. Bull., 18, 78–83.

    Article  CAS  Google Scholar 

  • Hall, L.W., Jr, S.J. Bushong, W.F. Johnson and W.S. Hall. 1988. Spatial and temporal distribution of butyltin compounds in a northern Chesapeake Bay marina and river system. Environ. Monit. Assess., 10, 229–244.

    Article  CAS  Google Scholar 

  • Hall, L.W., Jr, M.A. Unger, S.J. Bushong and M.C. Ziegenfuss. 1989. Butyltin Monitoring in a Northern Chesapeake Bay Marina and River System in 1988: An Assessment of Tributyltin Legislation. Final Report prepared for Johns Hopkins University, prepared by Applied Physics Laboratory, Shady Side, Maryland.

    Google Scholar 

  • Huggett, R.J., M.A. Unger, P.F. Seligman and A.O Valkirs. 1992. The marine biocide tributyltin: assessing and managing environmental risks. Environ. Sci. Technol., 26, 232–237.

    Article  CAS  Google Scholar 

  • Naval Sea System Command. 1986. US Navy Experience on Research and Development of Antifouling Hull Paints Containing Tributyltin Compounds. Presentation to the Department of Agriculture and Consumer Affairs, Commonwealth of Virginia, Richmond, Virginia (5 Nov.).

    Google Scholar 

  • Seligman, P.F., C.M. Adema, P.M. Stang, A.O. Valkirs and J.G. Grovhoug. 1987. Monitoring and prediction of tributyltin in the Elizabeth River and Hampton Roads, Virginia. In: Proceedings of the Oceans ’87 International Organotin Symposium, Vol. 3, Halifax, Nova Scotia, 28 September-1 October 1987, pp. 1357–1363.

    Google Scholar 

  • Seligman, P.F., J.G. Grovhoug, A.O. Valkirs, P.M. Stang, R. Fransham, M.O. Stallard, B. Davidson and R.F. Lee. 1989. Distribution and fate of tributyltin in the United States marine environment. Appl. Organometal. Chem., 3, 31–47.

    Article  CAS  Google Scholar 

  • Stallard, M.O., S.Y. Cola and C.A. Dooley. 1989. Optimization of butyltin measurements for sea water, tissue, and marine sediment samples. Appl. Organomet. Chem., 3, 105–114.

    Article  CAS  Google Scholar 

  • Unger, M. A., W.G. Madntyre, J. Greaves and R.J. Huggett. 1986. G.C. determination of butyltins in natural waters by flame photometric detection of hexyl derivatives with mass spectrometric confirmation. Chemosphere, 15, 461–470.

    Article  CAS  Google Scholar 

  • Valkirs, A.O., B. Davidson, L.L. Kear and R.L. Fransham. 1991. Long-term monitoring of tributyltin in San Diego Bay, California. Mar. Environ. Res., 32, 151–167.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1996 Chapman & Hall

About this chapter

Cite this chapter

Huggett, R.J., Evan, D.A., MacIntyre, W.G., Unger, M.A., Seligman, P.F., Hall, L.W. (1996). Tributyltin Concentration in Waters of the Chesapeake Bay. In: Champ, M.A., Seligman, P.F. (eds) Organotin. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1507-7_24

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-1507-7_24

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-412-58240-0

  • Online ISBN: 978-94-009-1507-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics